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《Engineering Plastics Application》 2009-01
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SYNTHESS OF FLOW MODFER PSAM/ZrP AND TS EFFECT ON PROPERTES OF PC

Su Zhuo,Chen Dan,Su Shengpei(College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,China)  
Oligomeric(styrene/acrylamide) copolymer(PSAM) was synthesized through free-radical polymerization,and flow modifier PSAM/ZrP was prepared by melt blending with PSAM and zirconium phosphate[Zr(HPO4)2·H2O,for short ZrP].Then PC/PSAM/ZrP and PC/ZrP composites were prepared by melt blending.The composites were characterized by FTIR,MFR and GPC,and the mechanical properties of composites were investigated.The results showed that PSAM/ZrP and ZrP could improve the flow property of the composites obviously and the modification effect of PSAM/ZrP was better.When the content of ZrP wasn't more than 3 phr,PSAM/ZrP didn't evoke the relative molecular mass and relative molecular mass distribution of PC changing.When the mass content of ZrP increased,the tensile elastic modulus and the bend elastic modulus of composites increased all along,the tensile strength and the bend strength of compositess also increased,the impact strength of the composites decreased gradually.But when the content of ZrP was 1 phr,PC/PSAM/ZrP composite had better comprehensive properties.
【Fund】: 2007年湖南省自然科学基金资助项目(07JJ5073)
【CateGory Index】: TQ323.41
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