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Synthesis and Characterization of Fe(Ⅲ)Complex with a New Nitrogen-Oxygen Donors Macrocyclic Schiff Base Ligand

Xu Zhiqiang Ni Shisheng Xu Jide ( Department of Chemistry ) Tian Yupeng (Department of Chemistry, Fuyang Teachers College)  
A new Fe(Ⅲ)chloride complex containing a 17-membered triaza dioxa macrocyclic schiff base ligand(L),[FeLCI]Cl_2·2.5H_2O has been prepared by template condensation of 1,7-bis(2'-formylphenyl)-4-benzyl-1,7-dioxa-4- azaheptane (DH) with phenylene diamine (o-).The complex was character- ized by IR,UV,fluoresence spectrum,conductivity masurement,thermal and elemental analysis.
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