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《Journal of Anhui Agricultural Sciences》 2008-22
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Synthesis,Characterization and Fluorescence Property of 2,2,2-amine Tri Acetyl-benzylamine and its Rare Earth complex

GAO Ji-hong et al (Academic Journal Center,Ningxia University,Yinchuan,Ningxia 750021)  
[Objective] The aim was to study the composition,coordination status and fluorescence property of rare earth complex with tripod type.[Method] The composition and fluorescence property of 2,2,2-amine tri acetyl-benzylamine(L) with ligand of tripod type were studied through Molar conductivity,infrared spectrum,NMR,elemental analysis,thermal analysis,and DTA-TG analysis.[Result] The composition of the rare earth complex of 2,2,2-amine tri acetyl-benzylamine was Re(NO3)3·L·4H2O(Re=La3+,Sm3+,Y3+,Tb3+,Ce3+,Eu3+),and 2∶1 electrolyte in DMF,in which NO3-coordinated with metal ion in the form of single tooth.Each rare earth complex emerged 2-3 exothermic peak at 248-635 ℃,corresponding to each level of oxidative decomposition course for complex.The complex Tb(NO3)3·L·4H2O had characteristics of condyloma line shape of fluorescence of Tb3+;in the methanol solution with concentration of 1×10-4 mol/L,fluorescence intensity of complex was the strongest.[Conclusion] The polarity of solvent was getting larger,the sensitization of 2,2,2-amine tri acetyl-benzylamine to Tb3+ was more intense and fluorescence intensity of complex was stronger.
【Fund】: 宁夏自然科学基金资助项目(NZ0507);; 宁夏大学科学研究基金资助项目
【CateGory Index】: O627.3
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