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《Journal of Anhui Agricultural Sciences》 2008-22
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Synthesis,Characterization and Fluorescence Property of 2,2,2-amine Tri Acetyl-benzylamine and its Rare Earth complex

GAO Ji-hong et al (Academic Journal Center,Ningxia University,Yinchuan,Ningxia 750021)  
[Objective] The aim was to study the composition,coordination status and fluorescence property of rare earth complex with tripod type.[Method] The composition and fluorescence property of 2,2,2-amine tri acetyl-benzylamine(L) with ligand of tripod type were studied through Molar conductivity,infrared spectrum,NMR,elemental analysis,thermal analysis,and DTA-TG analysis.[Result] The composition of the rare earth complex of 2,2,2-amine tri acetyl-benzylamine was Re(NO3)3·L·4H2O(Re=La3+,Sm3+,Y3+,Tb3+,Ce3+,Eu3+),and 2∶1 electrolyte in DMF,in which NO3-coordinated with metal ion in the form of single tooth.Each rare earth complex emerged 2-3 exothermic peak at 248-635 ℃,corresponding to each level of oxidative decomposition course for complex.The complex Tb(NO3)3·L·4H2O had characteristics of condyloma line shape of fluorescence of Tb3+;in the methanol solution with concentration of 1×10-4 mol/L,fluorescence intensity of complex was the strongest.[Conclusion] The polarity of solvent was getting larger,the sensitization of 2,2,2-amine tri acetyl-benzylamine to Tb3+ was more intense and fluorescence intensity of complex was stronger.
【Fund】: 宁夏自然科学基金资助项目(NZ0507);; 宁夏大学科学研究基金资助项目
【CateGory Index】: O627.3
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【Citations】
Chinese Journal Full-text Database 5 Hits
1 Zhang Hongjie,Hong Guangyan,Li Deqian,Niu Chunji,Ni Jiazuan;Advances in Chemistry of Rare Earth in China[J];Chemistry;2001-06
2 Gao Ji-hong1,2,Yang Tian-lin1,Wu Gen-liang1(1.Key Laboratory of Energy Resources and Chemical Engineering,Ningxia University,Yinchuan 750021,China;2.Academic Journal Center,Ninxia University,Yinchuan 750021,China);Preparation of Amide-Type Tripodal Ligand from Nitrilotriacetic Acid[J];Journal of Ningxia University(Natural Science Edition);2007-01
3 XUE Gang-Lin, YANG Yi-Xin, LI Heng-Xin, HE Shui-Yang, LI Jun (Department of Chemistry, Northwest University, Xi' an 710069);Synthesis, Crystal Structure and Thermal Decomposition of [Ce(NO_3)_5H_2O]·(C_3N_2H_5)_2[J];Chinese Journal of Inorganic Chemistry;2001-03
4 Tai Xishi, Tang Yu, Liu Weisheng, Tan Minyu* (College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China);Synthesis, Characterization and Luminescent Properties of Complexes of Rare Earth Nitrates with Tris 2-etamine[J];Journal of The Chinese Rare Earth Society;2003-03
5 Liu Ling~1,Xu Zheng~(1*),Lou Zhidong~1,Zhang Fujun~1,Sun Bo~2,Pei Juan~2(1.Institute of(Optoelectronics) Technology, Beijing Jiaotong University,Beijing 100044,China;2.Department of Materials Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China);Luminescent Mechanism for Tb(o-BBA)_3(phen)[J];Journal of The Chinese Rare Earth Society;2005-06
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 WANG Dao, YE Qing, XIA Ding-guo, Bater, ZHOU Ke-bin, FU Jin-hong ( College of Environment and Energy Engineering, Beijing Polytechnic University, Beijing 100022, China );Research on Oxidation Activity of Ln2O3/γ-MnO2 Serial Catalyst[J];Journal of Beijing Polytechnic University;2002-02
2 ZHANG Wei ping,CAO Wen kai,HE Shui yang (Dept.Chem.,Northwest Univ.,Xi'an 710069,Shaanxi,China);Synthesis and characterization of three new complexes of rare earth nitrate with imidazole[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2002-02
3 ZHANG Wei ping,HE Shui yang,ZHAO Xu dong (Dept. Chem.,Northwest Univ.,Xi'an 710069,Shaanxi,China);Synthesis and properties of complexes of rare earth nitrate with imidazole[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2002-03
4 SUN Jia yue, XIAO Ang, DU Hai yan, LIU Jie (College of Chemical and Environmental Engineering,Beijing Technology and Business University, Beijing 100037,China);SUMMARY OF STUDY AND APPLICATION OF RARE EARTH PHOSPHOR MATERIAL[J];Journal of Beijing Institute of Light Indusry;2002-04
5 SUN Jiayue, XIAO Ang, XIA Zhiguo, DU Haiyan(College of Chemical and Environmental Engineering,Beijing Technology and Business University,Beijing 100037,China);SUMMARY OF DEVELOPMENT AND APPLICATION OF THEPHOSPHOR FOR CATHODE RAY TUBES[J];Journal of Beijing Technology and Business University (Natural Science Edition);2003-04
6 WANG You1,WANG Zheng-de1,2,YUAN Wan-shun2,SUN De-yin2,LI Bao-wei1(1.Material and Metallurgy School,Inner Mongolia University of Science and Technology,Baotou 014010,China;2.Biochemical and Chemical Engineering School,Inner Mongolia University of Science and Technology,Baotou 014010,China);The heterogeneous preparation and characterization of dysprosium sulfides[J];Journal of Inner Mongolia University of Science and Technology;2007-01
7 Chen De,Zhang Dashun,Li Lin, Ma Baoqing 1,Jin Tianzhu 1 (Department of biology, Changde Teachers University,Changde Hunan, 415000) (1 State Key Laboratary of Rare Earth Material Chemistry and Applications ,Peking University,Beijing,100871);SYNTHESIS AND CRYSTAL STRUCTURE OF A NOVEL TETRANUCLEAR YTTRIUM COMPLEX WITH PROLINE LIGANDS AT HIGH pH VALUE[J];JOURNAL OF CHANGDE TEACHERS UNIVERSITY;2000-02
8 JI Dechun, LI Xiaonian, FU Guanping, LIU Huazhang (Zhejiang Province Key Laboratory of Heterogeneous Catalysis, Institute of Catalysis, Zhejiang University of Technology, Hangzhou 310014, China);Regular Effect of Rare Earth Oxide on Fe_(1-x)O Catalyst for Ammonia Synthesis[J];CHINESE JOURNAL OF CATALYSIS;2000-03
9 NIU Xin-shu,LIU Shan-hu,LI Hua,CHEN Jian-jun(Key Laboratory for Environmental Pollution Control of College of Chemistry & Environmental Science,Henan Normal University,Xinxiang 453007,China);Effect of Ce~(4+) Ions on Formation Process of Alumina Anodized Coating[J];Materials Protection;2007-08
10 ;Research Progress of Inorganic/organic Hybrid Optical Composites[J];Materials Review;1998-02
China Proceedings of conference Full-text Database 3 Hits
1 ;Effect And Influence Of Rare-earth On Ornamental Ti-Alloy Anodic Oxidation[A];[C];2009
2 Li Caihang Zhang tong (Institute of Chemical Engineering,Inner Mongolia Polytechnic University,Hohhot 010062);A Study on Phase Equilibrium and Complex of New Anticancer Drug FTRF with Lanthanum Chloride at 60℃[A];[C];2000
3 ZHAO Hai-jun~1,ZHANG Gui-ying~2,XIN Zhen-jiang~1,WANG Bao-gui~2,ZHANG Hui~2 (1.Zhejiang Medical College,Hangzhou 310053.China;2.Deptartment of Nutrition and Food Hygiene,School of Public Health,Jinlin University,Changchun 130021,China);Effect of cerium nitrate on the reproductive capacity of male mice[A];[C];2009
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Song Qingmei Huang Jinfei Wu Maojun(Institute of Material Science, Fudan University) Chen Jiyao(Physics Department, Fudan University);STUDY ON SYNTHESIS AND LUMINESCENCE PROPERTY OF EUROPIUM-ACTIVATED STRONTIUM ALUMINATE[J];Chinese Journal of Luminescence;1991-02
2 Chi Lisheng(Fujian Institute of Research on the Structure of Matter, The Chinese Acadeny of Sciences, Fuzhou 350002)Su Qiang(Changchun Institute of Applied Chemistry, The Chinese Academy of Sciences, Changchun 130022);SYNTHESIS AND LUMINESCENCE PROPERTIES OF RVNb_2O_9(R=Y,Gd,La):Eu~(3+)(or Dy~(3+))[J];Chinese Journal of Luminescence;1994-01
3 Tan Qinde Guo Wei, He Ming'an, Gao Shengli and Liu Yilun (Department of Chemistry, Northwestern University,Xi'an);The Investigation of Preparation for Light Rare Earth Nitrates and Their Hydrates[J];Chemical Research In Chinese Universities;1986-12
4 TAI Xi Shi, TAN Min Yu *, LIU Wei Sheng (College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China);Synthesis and Spectral Properties of the Complexes of Lanthanide Nitrates with 1,1,1-Tri-[1′-(2′-oxa-5′-oxo-6′-aza 6′-bisphenyl)hexyl] Propane[J];Chemical Research In Chinese Universities;2001-02
5 CUI Yi;WANG De-Jun;WANG Bao-Hui;LI Tie-Jin(Department of Chemistry,Jilin University,Changchun,130023) DONG Xiang-TIng;HONG Guang-Yan(Institute of Applied Chemistry,Academia Sinica,Changchun);A Study of the Spectrum Properties and the Photovoltage Response of Nanocrystalline Nd_2O_3[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1995-02
6 CHENG Yi (Department of Chemistry, Nanjing University, Nanjing, 210093) LIN Hua Kuan (Department of Chemistry, Nankai University, Tianjin, 300071) WANG Kui  (Department of Bioinorganic Chemistry, Beijing Medical University, Beijing, 100083);Studies on Kinetics of Reaction Between Tb 3+ and Human Oxyhemoglobin by Stopped flow Fluorometry[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-06
7 Ma Jianfang Ni Jiazuan (Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022);The Structures of Rare Earth Carboxylates[J];PROGRESS IN CHEMISTRY;1996-04
8 REN Yu-Fang(Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Academia Sinica, Changchun, 130022);The Effect of Some Factors on the Electric Properties of Rare Earth Complex Oxide[J];Acta Chimica Sinica;1995-11
9 YANG Bin-Sheng(Institute of Moleculur Science, Shanxi University, Taiyuan, 030006)Wesley R.Harris( Department of Chemistry, University of Missouri-St. Louis , St. Louis , MO 63121);UV Difference Spectra Study on the Binding of Europium Ion with Apotransferrin[J];Acta Chimica Sinica;1999-05
10 FAN Zhi\ WEN Xin\ ZHOU Wei Hong\ LIU Xiao Lan\ MIAO Fang Ming (Institute of Chemical Crystallography, Tianjin Normal University, Tianjing\ 300074);STUDY ON SYNTHESIS, CRYSTAL STRUCTURE AND QUANTUM CHEMISTRY OF THE COMPLEX OF TRIS(2 BENZIMIDAZYLMETHYL) AMINE WITH COPPER (Ⅱ)[J];CHINESE JOURNAL OF INORGANIC CHEMISTRY;1999-05
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