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《Journal of Anhui Normal University(Natural Science)》 2001-03
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ELECTROCHEMICAL SYNTHESIS OF METAL ALKOXIDES USING SACRIFICING ANODE

ZHOU Xing-fu, HAN Ai-jie, CHU Dao-bao, GU Jia-shan (Institute of Organic Chemistry, Anhui Normal University, Wuhu 241000, China)LIN Chang-jian, LIN Hua-shui, TAN Jian-guang(Depterment of Material Science, Xiamen University, Xiamen 361005, China)  
Metal alkoxides were directly prepared using pure metal as sacrificing anode in absolute alcohol. Metal alkoxides were characterized by FTIR spectra and element analysis. The effects of temperature,conductive additives,trace water on product yield were also investigated. The results showed that the direct electrochemical preparation of metal alkoxides had high current efficiency and electrolysis yield. These metal alkoxides have high purity and can be directly used as precursor of nanometer oxides prepared by Sol-gel method. The experiments showed that controlling temperature under 50-60℃, selecting R 4NBr as conductive additives and preventing titanium anode from being passiviated can improve product yield. Using alloy as anode may be recommended as a technique for the synthesis of alkoxides, this process can run in sufficiently high current efficiency and high reaction activity.
【Fund】: 安徽省教育厅科研基金 ( 99JL0 0 75 ) ;; 安徽省自然科学基金 ( 0 0 0 46112 )
【CateGory Index】: O627
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 ;The Summary of Nanocrystalline Materials[J];Materials Review;1997-02
2 TIAN Ming-Yuan; SHI Er-Wei; ZHONG Wei-Zhuo; PANG Wen-Qin; GUO Jing-Kun Key Laboratory of Inoryanic Synthesis and Preparotion Chemistry, Jilin University Changchun 130023 China)(Shanghai Institute of Ceramics, Chinese Academy of Sciences Shanghai 200050 Ch;Nano Ceramics and Nano Ceramic Powders[J];JOURNAL OF INORGANIC MATERIALS;1998-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Shi Liping, He Chunxia, Gu Hongyan, Ji Changying (Agricultural Engineering College,Nanjing Agicultural University, Nanjing 210032, China);STUDY ON THE FRICTION AND WEAR BEHAVIORS OF PTFE/NANO-Al2O3 COMPOSITES[J];Engineering Plastics Application;2003-09
2 Zhou Guojun Gan Weiping(CentralSouthUniversity,theMaterialDepartment,Changsha410083);Preparation of Bulk Nanocrystalline Materials and the Study on its Properties[J];Anhui Chemical Industry;2002-03
3 Li Yan Su Yi (Anhui Institute of Architecture, Hefei, 230022);PREPARAION AND SURFACE MODIFICATION OF Z rO 2 NANOMETER-SIZED POWDER[J];JOURNAL OF ANHUI INSTITUTE OF ARCHITECTURE;1999-02
4 SHEN Guang xia, CHU Dao bao,\ ZHOU Xing fu,\ GU Jia shan (College of Chemistry and Material Science, Anhui Normal University, Wuhu, Anhui, 241000, China);ELECTROCATALYTIC STUDIES AND APPLICATION OF THE TiO_2 MODIFIED ELECTRODES IN THE ORGANIC ELECTROSYNTHESIS[J];Journal of Anhui Normal University(Natural Science);2001-01
5 RUAN Ji-feng LI Chun-xi WANG Zi-hao(College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Preparation and photocatalytic performance of ultrafine titanium dioxide powder[J];Journal of Beijing University of Chemical Technology;2002-03
6 WANG Nian-rong~1 LIU Xiao-lin~1 YAN Tao~1 ZHOU Rong~1 CHEN Jian-feng~(1,2)(1.Key Lab for Nanomaterials,Ministry of Education;2.Research Center of the Ministry of Education for High Gravity Engineering and Technology,Beijing University of Chemical Technology,Beijing 100029,China);Synthesis of nano-sized magnesium titanate powders by chemical-reactive precipitation[J];Journal of Beijing University of Chemical Technology;2005-06
7 LI Hong (LiaoCheng University,Institute of Material Science and Technology,Liaocheng 252059);Nanocrystalline Ceramics and Its Applications[J];Shandong Ceramics;2004-03
8 LIU Sheng-lin, SUN Dong-bai, FAN Zi-shuan, YU Hong-ying, MENG Hui-min,WANG Xu-dong (School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China).;Current Status and Progress of Thermally Sprayed Nanostructured Coatings[J];Materials Protection;2006-09
9 Mihal Barladeanu Institute of Aviation Metallurgy,Bucharest-1,ROMANIA 71529;Current Status of Precipitation Research and Its Applications[J];Materials Review;2000-02
10 Deng Jianguo (Institute of Chemicals Materials CAEP,Chengdu 610003);Progress of Research Polymer/Polymer Nanocomposites[J];Materials Review;2000-03
China Proceedings of conference Full-text Database 5 Hits
1 YIN,Li-Feng LI,Cong-Ju FU,Ji-Quan College of Material Engineering,Beijing Institute of Clothing Technology,Beijing Key Laboratory;Nanoscale Metal Oxide Fiber Prepared by Electrospinning[A];[C];2007
2 CHEN Gai-rong;ZHANG Ying-gui Department of Chemistry and Chemical Engineering, Pingyuan University, Xinxiang, 453003, China;Preparation and Characterization of Nanocrystals MgO[A];[C];2001
3 ZHAO Ting-kai, LIU Yong-ning, ZHU Jie-wu (State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, 710049);A summary on nanomaterials[A];[C];2004
4 Yang Ming~(1,2),Tian Qin~1,Wang Xiaosai~1(1.College of Materials Science and Metallurgy Engineering, Guizhou University,Guiyang 550003,China;2.Key Laboratory for Mechanical Behavior and Microstructure of Materials,Guizhou Province,Guiyang 550003,China);Research of Iron-Based Ceramic Composite Prepared by SHS Method[A];[C];2008
5 Liu Jim Xu Cheng-hai (Northeastern University, Shenyang 110004, China);Present Situation and Progress in Nanosized Powder Preparation by Vacuum Freeze-Drying Method[A];Chinese association of Refrigeration[C];2002
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 <author>NG Guang-jian,YAO Wang,CHEN Guang-hua,LI Ying,YAN Hong (Key Laboratory of Advanced Functional Materials of China Ministry of Education, College of Material Science and Engineering,Beijing University of Technology,Beijing 100022,China; College of Life Science and Bioengineering,Beijing Univemity of Technology,Beijing 100022,China);<title>eparation of TiO_2 Nano-powder by Hydrolyzing Titanate Controlled by Surfactant[J];Journal of Beijing Polytechnic University;2004-03
2 Wang Yan; Su Chunhui; DuanMu Qingduo;Preparation and Catalysis Mechanism of Aluminium Isoporopy1[J];Journal of Changchun Institute of Optics and Fine Mechanics;1994-02
3 ;The Summary of Nanocrystalline Materials[J];Materials Review;1997-02
4 WANG Zichao; KARATO Shun-ichro(Institute of Geology, SSB) (University of Minnesota, USA)(Correspondent:Associate Professor,Institute of Geology,SSB,Beijing 100029);STRENGTH AND RHEOLOGY OF Y_3Al_5O_12 SINGLE CRYSTAL AT HIGH TEMPERATURE[J];CHINESE JOURNAL OF MATERIAL RESEARCH;1996-04
5 Xu Jianmei Zhang De( Faculty of Meterial Science and Chemical Engineering,China University of Geosiences,Wuhan,430074 );TECHNIQUE ADVANCE AND CURRENT APPLICATION SITUATION OF SOL GEL[J];GEOLOGICAL SCIENCE AND TECHNOLOGY INFORMATION;1999-04
6 ZHANG Ming, YAN Chang hao, LI You rong (Yangzhou University, Yangzhou 225002, China) Nakakita Satoshi, Inoue Shinich, Okamoto Hiroshi (Aichi Institute of Technology, Japan);PREPARATION AND MECHANICAL PERFORMANCE OF ALUMINIUM-CONTAINING PSBR COMPOSITE ELASTOMER[J];Polymeric Materials Science & Cngineering;2001-02
7 Zeng Qingbing, Li Xiaodong, Lu Yi(Department of Material Engineering and Applied Chemistry, National University of Defence Technology);PRINCIPLE AND APPLICATIONS OF SOL-GEL METHOD TO CERAMIC MATERIALS[J];POLYMERIC MATERIALS SCIENCE & CNGINEERING;1998-02
8 ZHANG Fang, QIN Xiao-mei, XIU Zhi-meng, YOU Jian, SUN Xu-dong (School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China; Liaoning Analyzing and Testing Center, Shenyang 110015, China );Synthesis of YAG micrometer powders by co-melting yttrium nitrate and aluminum nitrate[J];Journal of Functional Materials;2002-01
9 Luo Wuwen Glass Research Inst., China Building Materials Academy;Basic Precursors for Sol-Gel Method-Metal Alkoxides[J];Bulletin of the Chinese Ceramic Society;1993-04
10 Chen Yongxi Zhou Lijuan  Li Yingxia Lei Jiaheng (Wuhan University of Technology,Wuhan 430070; Department of Materials,College of Zibo,Zibo 250091)$$$$;Study on Synthesis of Yttrium Alkoxide with Yttrium Chloride and Sodium Isopropoxide[J];Bulletin of Thechinese Ceramic Society;2002-01
【Secondary Citations】
Chinese Journal Full-text Database 8 Hits
1 ZHENG Xinhua;ZHONG Jiaxiang;LIU Hongtao;QIAO Lei(Beijing Instilute of Technology)(Correspondent:ZHENG Xinhua,Associate Professor,Department of Mecharical Engineering,Beding institute of Technology,Be1Jing 100081);EFFECTS OF Y-PSZ ON DENSIFICATION AND PROPERTIES OF SINTERED NANO-ALUMINA[J];CHINESE JOURNAL OF MATERIAL RESEARCH;1996-03
2 Jiang Dongliang Guo Jingkun (Shanghai Institute of Ceramics,Academia Sinica);MULTIPHASE CERAMICS[J];Journal of The Chinese Ceramic Society;1991-03
3 Xu Yueping Guo Jingkun Huang Xiaoxian (Shanghai Institute of Ceramics, Academia Sinica);A RESEARCH ON SINTERING KINETICS OF ULTRAFINE ZrO_2-Y_2O_3 POWDER[J];Journal of The Chinese Ceramic Society;1992-01
4 Xu Dichun Hao Xiaochun Zhu Xuanhui (Materials Science and Engineering Department, Tianjin University);AGGLOMERATION CONTROL IN THE PREPARATION OF ULTRAFINE ZrO_2 (Y_2O_3) POWDER BY MEANS OF WET-CHEMICAL PROCESS[J];Journal of The Chinese Ceramic Society;1992-01
5 Shi Erwei Luan Huaishun Qiu Haibo Wang Aiming Zhong Weizhuo Feng Chude Guo Jinqkun (Shanghai Institute of Ceramies,Academia Sinica,Shanghai,201800);Physical and Chemical Circumstance for Hydrothermal Processing Ultrafine Zirconia Powder[J];Journal of Synthetic Crystals;1993-01
6 Guo Xin Sun Yaoqing Cui Kun (Huazhong University of Science and Technology,430074);Sintering Process of Ultrafine Zirconia Powder and Related Phenomena[J];Journal of Inorganic Materials;1993-02
7 Gao Lian;Qian Haichao(The State Key Laboratory of High Performance Ceramics and Superfine Microstructure,Chinese Academy of Sciences Shanghai 200050);Preparation of Ultrafine Zirconia Powder by Emulsion Method[J];JOURNAL OF INORGANIC MATERIALS;1994-02
8 Qiu Haibo;Gao Lian;Feng Chude;Guo Jingkun;Yan Dongsheng (State Key Laboratory on High Performance Ceramics and Superfine Microstructure Studies,Shanghai Institute of Ceramics, Chinese Academy of Sciences Shanghai 200050);Preparation of Nanoscale Zirconia Powder by Heterogeneous Aseotropic Distillation Processing[J];JOURNAL OF INORGANIC MATERIALS;1994-03
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