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《Journal of Anhui Normal University(Natural Science)》 2003-03
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SYNTHESIS AND CHARACTERIZATION OF TRI-COPOLYMER POLY(ETHYLENE OXIDE)MACROMONOMER、ACRYLAMIDE AND METHYL METHACRYLATE

SUN Lilin,FENG Song,LI Qinghai,SHEN Liangjun (College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China)  
Sodium sulfadiazine, which adopted as anion initiator for EO's ring-opening polymerization, has successfully initiated EO's polymerization.A new kind of PEOs macromonomer was synthesized with methacrylic chloride as end capping reagent. On the base of which, copolymerization of PEO macromonomer with acrylamide(AM)and methy1 methacrylate using AIBN as initiator was sequentially explored, the product of PAM-PMMA-PEO copolymer was obtained. After purified, macromonomer and copolymer were characterized with IR,1H-NMR, VPO andGPC Instrument.The anticipated structure on products was convinced. Simultaneously the corresponding conditions of polymerization were studied.
【CateGory Index】: O631.1
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