Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Safety and Environment》 2005-04
Add to Favorite Get Latest Update

In situ IR study on adsorption and oxidation of toluene on supported Cu catalyst

LIU Ya-ning1, HUANG Hai-tao2, LI Xin-jun1, SUN Shi-cai1, ZHAO Dai-qing1(1 Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China; 2 Environment Science and Engineering Institute, Guangdong University of Technology, Guangzhou 510090, China)  
The present paper intends to introduce the authors' study of the adsorption of toluene on pure support alumina and supported copper catalyst through in situ infrared spectroscopic analysis respectively. For this purpose, we have studied the function of the pure support and active element as well as the process of adsorption and oxidation of toluene on catalyst on the condition of rich and lean oxygen case by case. Our research results indicate that the adsorption of toluene on catalyst Cu/γ-Al_2O_3 is very weak. And, therefore, the middle-way product of oxidation of toluene - benzoic acid - can form so strong adsorption on the surface of the catalyst Cu/γ-Al_2O_3 that the deep oxidation of benzoic acid may turn to be the rate-controlling factor of toluene's deep oxidation .It can also be found that copper oxide may act as the key active element in the catalyst Cu/γ-Al_2O_3.
【Fund】: 国家自然科学基金项目“脉冲电晕净化有机污染物的研究”(20376081)
【CateGory Index】: X701
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【Citations】
Chinese Journal Full-text Database 5 Hits
1 WANG Hai, DU Ying chun, CHEN Shu (Research Center for Chemical Engineering, Beijing Institute of Clothing Technology, Beijing 100029);Study on Alkylation of Benzene with Ethylene over βZeolite Catalyst by in situ IR[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);2000-03
2 He Xiaolong (Maoming Ethylene C. O. , maoming,525000);The Applying Process of Catalytic Combustion in Controlling Discharge of Waste Gas[J];Guangdong Chemical Industry;2000-05
3 LUO Lai tao GUO Jian jun GU Zhong hua (Department of Chemistry,Nangchang University,Nangchang,330047);THE INFLUENCE OF TRANSLATION METALS ON Pt Rh Pd/Al_2O_3 CATALYST PERFORMANCE FOR PURIFICATION[J];Environmental Chemistry;2004-04
4 Zheng Biaolian; He Xiaolong; Yan Xingguo; Wang Zhongquan(Dept.of Chem.);An Approach to the Activity Role in Deep Oxidation of Aromatic Hydrocarbons over Copper-Manganite[J];JOURNAL OF XIAMEN UNIVERSITY(NATURAL SCIENCE);1994-06
5 Hu Yanping; Jin Hengfang(Inner Mongolia Polytechnical University,Hohhot 010062);Water-Gas-Shift Reaction(WGSR)on Cerium Oxide by Fourifr-Transform Infrared Spectroscopy[J];CHINESE RARE EARTHS;1995-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 JIANG Tao,LI Duo-song,ZHANG Kai (College of Environment and Spatial informatics,China University of Mining and Technology,Xuzhou 221008,China);Catalytic Combustion of Toluene on La_(0.8)Sr_(0.2)MnO_3 Perovskite Catalyst[J];Urban Environment & Urban Ecology;2008-03
2 ZHU Ling1,WANG Xue-zhong2(1.Department of Environmental Engineering,Beijing Institute of Petrochemical Technology,Beijing 102617,China;2.Chinese Research Academy of Environmental Sciences,Beijing 100012,China);The Influence of Reaction Atmosphere on Soot Combustion in Ce_(0.5)Zr_(0.5)O_2 Solid Solution[J];Vehicle Engine;2008-03
3 LIU Ya-ning1,HUANG Hai-tao2,SUN Shi-cai1(1.Guangzhou Institute of Energy Conservation,Chinese Academy of Sciences,Guangzhou 510640;2.Guangdong University of Technology,Guangzhou 510006);Mechanism of Deep Oxidation of Toluene on Copper-based Catalyst[J];Environmental Science & Technology;2006-03
4 He Xiaolong (Maoming Ethylene C. O. , maoming,525000);The Applying Process of Catalytic Combustion in Controlling Discharge of Waste Gas[J];Guangdong Chemical Industry;2000-05
5 Chen Dingsheng,Cen Chaoping,Lan Ruhui(South China Institute of Environmental Sciences,Ministry of Environmental Protection,Guangzhou 510655,China);Experiment Study on Distillation Absorbent of Waste Engine Oil[J];Guangdong Chemical Industry;2008-10
6 Cai Heshan,Li Xiaoxia,Xu Song(Department of Resource and Environment,Foshan University,Foshan 528000,China);Purification technology for removing volatile organic compounds[J];Journal of Chemical Industry & Engineering;2008-03
7 He Yi, Wang Hua, Li Guang-ming, Zhao Xiu-hua, Zhao Jian-fu;Catalytic Combustion Technology for Organic Waste Gases[J];Jiang Su Environmental Science and Technology;2004-01
8 FENG Yi ,SU Fang-yun, YAO Ya-ping (Petro China Lanzhou Lubricanting Oil R&D Institute, Lanzhou 730060, Gansu, China ; Technology Center of Lanzhou Petrochemical Company, Lanzhou 730060, Gansu, China);Dynamic Research on Saponification of High Carbon Alkylphenol[J];Fine Chemicals;2005-S1
9 ZHAO Yong-cai,ZHENG Zhong(Environment Protection Science Research & Design Institute of Ningbo,Ningbo 315012,China);Catalytic Combustion Technology for Volatile Organic Compounds(VOCs) and its Application[J];Insulating Materials;2007-05
10 Zhang Erhua,Qiu Gang(Institute of Environmental and Chemical Technology,HanShan Normal University,Chaozhou 521041,China);A Simple Method for Preparation of Nano-Pd Colloid[J];Science & Technology Information;2007-33
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 YU Yunbo, HE Hong *(Research Center for Eco Environmental Sciences, The Chinese Academy of Sciences, Beijing 100085, China);Mechanistic Study of Lean NO_x Reduction with Propene over Ag/Al_2O_3 by in Situ DRIFTS[J];Chinese Journal of Catalysis;2003-05
2 KE Rui~1,LI Junhua~(2*),HAO Jiming~2,FU Lixin~2,CHEN Qiang~1,ZHAO Daqing~1(1 Department of Mechanical Engineering,Tsinghua University,Beijing 100084,China;2 Department of Environmental Science and Engineering,Tsinghua University,Beijing 100084,China);In Situ DRIFTS Study on Non-thermal Plasma-Assisted NO_x Reduction by Propene over Ag/Al_2O_3 Catalyst[J];Chinese Journal of Catalysis;2005-11
3 WU Qiang, GAO Hongwei, HE Hong~*(State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, The Chinese Academy of Sciences, Beijing 100085, China);Study of SO_2 Effect on the Selective Catalytic Reduction of NO_x with Propene over Ag/Al_2O_3 by in Situ DRIFTS[J];Chinese Journal of Catalysis;2006-05
4 WU Qiang, YU Yunbo, HE Hong(State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences,The Chinese Academy of Sciences, Beijing 100085, China);Mechanistic Study of Selective Catalytic Reduction of NO_x with C_2H_5OH and CH_3OCH_3 over Ag/Al_2O_3 by in Situ DRIFTS[J];Chinese Journal of Catalysis;2006-11
5 Jin Yan Jiang Xueyin Sang Wenbin Wang Linjun Zhang Zhilin Xu Shaohong (School of Materials Science and Engineering, Shanghai University, Shanghai 201800);SYNTHESIS AND CHARACTERIZATION OF NANOMETRE SIZED ZnS∶Mn IN CHITOSAN[J];CHINESE JOURNAL OF LUMINESCENCE;1997-03
6 LI Chuihua LI Dan SHI Qihong (Science Center Shantou University Shantou 515063) ZHU Qiming ( Chemistry Department Qinghua University Beijing 100084);Preparation and Characterization of New CuCl/H Catalysts[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1999-02
7 ZHANG Ping 1, 2, WANG Le-fu1 and XU Jian-chang1 1.Department of Environmental Science,Guangzhou University,Guangzhou 510630,China 2.Department of Chemical Engineering, South China University of Technology,Guangzhou 510630, China;In situ Diffuse Reflectance FTIR Sectroscopy Study of the Selective Catalytic Reduction Reaction of NO over Ag/SAPO-34 Catalysis[J];Spectroscopy and Spectral Analysis;2003-01
8 YANG Cheng, DONG Qing-nian, REN Jie, SUN Yu-hanState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;In-Situ IR Study of Adsorption and Decomposition of Methanol on γAl_2O_3, CeO_2 and Their Supported Pd Catalysts[J];Spectroscopy and Spectral Analysis;2004-07
9 Gao Naiyun 1 ,Li Fusheng 2 ,Yuasa Akira 3 ,Le Linsheng 4 ,Zhou Yun 5 (1.State Key Laboratory of Pollution Control and Resource Reuse,Tongji U niversity,Shanghai200092,Chin a;2.Department of Civil Engineering,G ifu University,1-1Yanagido,Gifu501-1193,Japan;3.Center for Rive r Basin Environment Research,Gifu University,1-1Yanagido,Gifu501-11 93,Japan;4.Shanghai Municipal Waterworks Shi bei Co.,Ltd,Shanghai200 082,China;5.Shanghai Municipal Waterworks Pudong Co.,Ltd,Shanghai20 0127,China);Research progress in the removal of trichloroethylene from water[J];Industrial Water Treatment;2003-09
10 Gao Lian and Xie Yongheng (Research Institute of Chemical Machinery under Ministry of Chemical Industry, Lanzhou 730060);Technologies for VOC Pollution Control[J];Environmental Protection of Chemical Industry;1998-06
【Secondary Citations】
Chinese Journal Full-text Database 9 Hits
1 Shu Jun, Wu Shan-liang and Wang Ren (East China Institute of Chemical Technology, Shanghai);MECHANISM OF CATALYTIC OXIDATION OF TOLUENE ON Cu-Mn-0 CATALYSTS[J];Chinese Journal of Catalysis;1989-03
2 ZHU Haiyang, SHEN Mingmin, LIU Tiandong, WEI Shuting, HU Yuhai, DONG Lin *, CHEN Yi (Laboratory of Mesoscopic Material Science, Department of Chemistry, Nanjing University, Nanjing 210093, Jiangsu, China);Surface Interaction between Copper Oxide and CeO_2-γ-Al_2O_3 Mixed Oxide Support[J];Chinese Journal of Catalysis;2002-04
3 Meng Ming, Lin Peiyan, Fu Yilu (Department of Chemical Physics, University of Science and Technology of China, Hefei 230026);THE EFFECT OF NOBLE METALS ON Co/ γ Al 2O 3 AND CHARACTERIZATION OF ITS STRUCTURE Ⅰ. Activity and XRD, XPS Characterization of Co M/ γ Al 2O 3 Catalysts[J];CHINESE JOURNAL OF CATAL YSIS;1996-03
4 MENG Ming LIN Peiyan FU Yilu (Department of Chemical Physics University of Science and Technology of China Hefei 230026);A Study of Pulse Adsorption and Temperature Programmed Heating on Co Pt(Pd,Rh)/γ Al 2O 3 Catalysts[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1997-05
5 Zhang Suqing Du Shaobin(Department of Chemistry, Yunnan Normal University, Kunming, 650092)Wang Jin(Department of Chemistry, Hangzhou University, Hangzhou, 3100028);STUDY OF CATALYTSTS FOR DEEP OXIDATION OF NITROGEN-CONTAINING ORGANIC WASTE WATER[J];Environmental Chemistry;1993-01
6 Yang Hanpei, Qiu Fali (Chengdu Institute of Organic Chemistry, Academia Sinica);Studies on Mixed Oxide Catalysts for Automobile Exhaust Control[J];Environmental Science;1992-02
7 DU Ying chun,YANG Li ying and ZHANG Ji rui (Research Center of Chemical Engineering,Beijing Institute of Clothing Technology,Beijing 100029);Alkylation of Benzene with Ethylene over Zeolite Catalyst FX 02[J];PETROCHEMICAL TECHNOLOGY;1999-04
8 Zheng Biaolian; He Xiaolong; Yan Xingguo; Wang Zhongquan(Dept.of Chem.);An Approach to the Activity Role in Deep Oxidation of Aromatic Hydrocarbons over Copper-Manganite[J];JOURNAL OF XIAMEN UNIVERSITY(NATURAL SCIENCE);1994-06
9 Yang Chunsheng, Chen Jianhua (Department of Materials, Yancheng Institute of Technology, Yancheng 224003, China);Application of Ceria and Lanthana in Catalyst for Cleansing Exhaust Gas of Car[J];Journal of The Chinese Rare Earth Society;2003-02
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved