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Photoelectric property of polyaniline doped with organic sulphonic acid

FENG Wei,WEI Wei,WU Hong-cai (School of Electronic and Information Engineering,Xi'an Jiaotong University,Xi'an 710049,China)$$$$  
Polyaniline doped with doedecyl-benzene sulphonic acid(DBSA) is studied on photoelectric property.The result shows that when polyaniline doped with DBSA is irradiated with light,the concentration of carrier increases obviously.Mixture of sensitive material is advantageous to the absorption of polyaniline in visible light spectrum,and the conductivity is also improved.The results of dielectric measurements carried out on polyaniline doped with DBSA in an Al-PAn-DBSA-Al configuration as function of frequency and temperature are reported.The space-charge polarization phenomenon is observed.Lifetime of carrier is microsecond level and mobility is 1×10 -3 ~1×10 -1 cm 2/(V·s),which are obtained by calculation or experiment.The active energy is obtained from the relation between conductivity and temperature.The conducting mechanism of PAn-DBSA is analyzed.
【Fund】: 国家自然科学基金
【CateGory Index】: O631.23
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