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《Semiconductor Optoelectronics》 2005-06
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P-type Transparent Conducting Copper Aluminum Oxide Films with Different Cu/Al Ratio

ZHOU Qiang,JI Zhen-guo,ZHAO Li-na,CHEN Chen,WANG Chao(State Key Laboratory for Silicon Materials,Zhejiang University,Hangzhou 310027,CHN)  
P-type transparent conducting copper aluminum oxide samples with different Cu/Al ratio were prepared by the sedimentation of cupric acetate and aluminum acetate at high temperature and solid-phase-reaction.X-ray diffraction results show that the powder samples consist of tenorite structured CuO,delafossite structured CuAlO_(2),spinel structured CuAl_(2)O_(4)and corundum structured Al_(2)O_(3).EDAX analysis indicate that the actual Cu/Al ratio in the samples increases with Cu/Al ratio in raw materials.Conducting type measurement results show that all the samples are p-type.The lowest and relative stable resistivity is obtained at the Cu/Al ratio of 1.0~1.5.
【Fund】: 国家基础研究发展规划专项资助项目(973)(G20000683)
【CateGory Index】: TM241
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