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《Chinese Journal of Explosives & Propellants》 2002-04
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Synthesis of Lead(Ⅱ) and Copper(Ⅱ) Salts of 4-Hydroxy-3,5- dinitropyridine Oxide

ZHENG Yu mei, DENG Min zhi, ZHAO Feng qi, YUAN Chao (Shanghai Institute of Organic Chemistry Chinese Academy of Sciences,Shanghai 200032, China)  
The paper describes that synthesis of lead(Ⅱ) and copper(Ⅱ) salts of 4 hydroxy 3,5 dinitropyridine oxide in good yields from pyridine via the multiple steps. The salts were characterized by M.S and microanalysis. DSC and TG experimental results of the salts showed that the salts could effectively catalyze the thermal decomposition of RDX, AP and NC+NG. Meanwhile, the decomposition heats of mixtures containing different salts were larger than those of the corresponding pure RDX, AP and NC+NG. The all facts suggested the salts might be better energetic burning catalysts.
【Fund】: 国防重点实验室基金项目 (CD980 2 2 )
【CateGory Index】: V512
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