Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chinese Journal of Explosives & Propellants》 2008-03
Add to Favorite Get Latest Update

Thermal Hazard in the Process of Mononitrotoluene Nitration

CHEN Li-ping1,CHEN Wang-hua1,LI Chun-guang2,PENG Jin-hua1,ZHANG You-ping2,LIU Rong-hai1,LU Li-ming3(1.Department of Safety Engineering,School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China;2.Safety Technology Research Institute of Ordnance Industrial,Beijing 100053,China;3.MTEELER TOLEDO,Shanghai 200233,China)  
To get thermal hazard information in the process of forming dinitrotoluene from mononitrotoluene(MNT),DSC was used to test the thermal decomposition behaviors of these substance referred,and reaction calorimeter(RC1e) was used to study the heat generation in the reaction process.The results show that the decompositon of mixed acid easily took place and the onset temperature of decomposition reaction for mixed system after the reaction is 113.3℃.And the maximal temperature attainable by runaway of the desired synthetic reaction(MTSR) is lower than 100℃ if MNT dosing could stop as soon as cooling failure,or else,the adiabatic temperature arise can be higher than 140℃,and lead a secondary decomposition reaction.
【CateGory Index】: TQ560.72
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 XU Ruo-qian,JI Yue-ping,DING Feng,YANG Wei,LIU Wei-xiao(Xi′an Modern Chemistry Research Institute,Xi′an 710065,China);Energized Synthesis and Characterization of 1,3,5-Tris(2-hydroxy ethyl)-1,3,5-triazinane-2,4,6-trione[J];Chinese Journal of Explosives & Propellants;2009-04
【Citations】
Chinese Journal Full-text Database 3 Hits
1 CHEN Mei-jun~1,ZHANG Yuan-wen~2,CAO Duan-lin~1,WANG Jian-long~1,WANG Hui-ning~1(1.Department of Chemical Engineering,North University of China,Taiyuan 030051,China;2.Institute of Environment Inpact Assessment,Baoji 721000,China);Preparation of 2,6-dinitrotoluene[J];Applied Chemical Industry;2006-01
2 CHEN Li-ping CAI Liu-lin PENG Jin-hua,Prof. CHEN Wang-hua,Assoc. Prof.(Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China);Study on the Safety Synthesis of Methylamine Nitrate[J];China Safety Science Journal(CSSJ);2006-12
3 CHEN Wang-hua1,Assoc. Prof. CHEN Li-ping1 WU Yan1 PENG Jin-hua1,Prof. Daniel Freiner2 (1 Department of Safety Engineering, School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China 2 Mettler-toledo AutoChem, Inc.,Switzerland);Influence of Nitrate Acid and Chlorine Ion on the Decomposition of Ammonium Nitrate in Aqueous Solution with High Temperature[J];China Safety Science Journal(CSSJ);2007-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 CHEN Xian-ming, LUO Cheng-ping, LIU Jiang-wen, LI Wen-fang (College of Mechanical Engineering, South China University of Technology, Guangzhou 510641, China);Thermodynamic and kinetic analysis of micro-arc oxidation on magnesium alloy[J];Ordnance Material Science and Engineering;2006-03
2 LI Zai-yuan,ZHAI Yu-chun,TIAN Yan-wen,WANG Tian-ran (School of Material and Metallurgy,Northeastern University,Shenyang110004,China);Research on preparation of Cu/Mo compound powder by hydro gen reducing Cu/Mo compound[J];Semiconductor Information;2003-04
3 ZHOU Cheng,ZHOU Yan-shui,HUANG Xin-ping,WANG Xi-jie (Xi′an Modern Chemistry Research Institute, Xi′an 710065, China);Synthesis and Properties of 1,1-Diamino-2,2-Dinitroethylene[J];Chinese Journal of Explosives & Propellants;2005-02
4 GUO Feng-bo, LIU Yu-cun,LIU Dengcheng,YU Yan-wu(Department of Environmental and Safety Engineering,North University of China,Taiyuan 030051,China);Optimization of the Synthetical Craft of 2,6-Diamino-3,5-Dinitropyrazine-1-Oxide[J];Chinese Journal of Explosives & Propellants;2006-01
5 LIU Li-rong1,2,LüChun-xu1,LI Xia1(1.Department of Chemistry,Nanjing University of Science and Technology,Nanjing 210094,China;2.Department of Chemical Engineering,Huaihai Institute of Technology,Lianyungang Jiangsu 222005,China);Progress on Regioselective Nitration of Toluene[J];Chinese Journal of Explosives & Propellants;2006-01
6 LIU Li-rong~(1,2),Lü Chun-xu~1,LI Xia~1(1.Department of Chemistry,Najing University of Science and Technology,Nanjing 210094,China;2.Department of Chemical Engineering,Huaihai Institute of Technology,Lianyungang Jiangsu 222005,China);Regioselective Nitration of Toluene with Nitric Acid in the Presence of Solid Super Strong Acid ZrO_2-TiO_2/SO_4~(2-) Catalysts[J];Chinese Journal of Explosives & Propellants;2006-02
7 XU Zhi-xiang,HU Yi-ting,LIU Da-bin,YE Zhi-wen,WEI Yan-an(School of Chemical Engineering,Nanjing University of Science of Technology,Nanjing 210094,China);Application of Pressure Data Obtained by Accelerating Rate Calorimeter[J];Chinese Journal of Explosives & Propellants;2009-03
8 XI Xiao-li, GUO Yan-qun, ME Zuo-ren, YANG Jian-can, ZUO Tie-yong ( College of Materials Science and Engineering, Beijing University of Technology, Beijing 100022, China );Study on the Carbon Pollution in SPS[J];Journal of Beijing Polytechnic University;2004-01
9 Song Bo; Zhao Baodong; Han Qiyong' Liu Yong(Applied Science School, UST Beijing, Beijing 100083,China);Dissolution Equilibrium of Bismuth Vapor in Liquid Iron and the Interaction Effect of Third Element[J];JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING;1997-02
10 Liu Pengru; Shao Guangdi; Liu Wenhua(Applied Science School,UST Beijing,Beijing 100083, China)(General Research Institute for Non-Ferrous Metals of Beijing);Influences of Instrumental Parameters on Signal Intensity of Rare Earth Ions in ICP-MS[J];Journal of University of Science and Technology Beijing;1999-04
China Proceedings of conference Full-text Database 10 Hits
1 Hu Jin-Xia,Cai Chun School of Chemical Engineering.Nanjing University of Science and Technology,Nanjing 210094,China;Synthesis of 4-Fluoro-6-methylbenzimidazole as a Nonpolar Isostere of Guanosine[A];[C];2005
2 Liu Yan~(1*) Zhai Yuchun~1 Wang Jinxia~2 (1.School of Material and Metallurgy,Northeastern University,Shengyang 110004,China;2.School of Sciences,Northeastern University,Shengyang 110004,China);Thermodynamics of Irreversible Process in Reaction of Alumina with Anhydrous Sodium Carbonate[A];[C];2008
3 Huang Bifang~(1,2) Wang Haifeng~(1,2) Tang Daowen~(1,2) Li Yuanhui~1 (1.College of Materials Science and Metallurgy Engineering,Guizhou University,Guiyang 550003,China;2.Guizhou University Research Center for Material Recycle and Industrial Ecology,Guiyang 550003,China);Thermodynamic Analysis of Chloridizing Leaching of Zinc Oxide Dust with Germanium[A];[C];2008
4 Yang Zhongdong~* Xue Xiangxin Liu Sulan Liu Qi (School of Materials and Metallurgy,Northeastern University,Shenyang 110004,China);Study on Desiliconization of Boron Containing and High Silicon Content Liquid Iron Adopting Submerged O_2 Blowing Method[A];[C];2008
5 Zhang Nianbing~(1,2,*) Li Zhiying~3 (1.College of Materials Science and Engineering,Chongqing University,Chongqing 400044,China;2.School of Material and Architectural Engineering,Guizhou Normal University,Guiyang 550001,China;3.College of Materials Science and Metallurgy Engineering,Guizhou University,Guiyang 550003,China);Study on the Desulphurizing Mechanism of Barium Aluminate with Sodium Aluminate and Test[A];[C];2008
6 Li Zhiying~(1,4) Zhang Nianbing~(2,3) Quan Bianli~(1,4) (1.School of Material and Architectural Engineering,Guizhou Normal University,Guiyang 550001;2.College of Materials Science and Engineering,Chongqing University,Chongqing 400044,China;3.College of Materials Science and Metallurgy Engineering,Guizhou University,Guiyang 550003,China;4.Guizhou University Research Center for Material Recycle and Industrial Ecology,Guiyang 550001,China);Study on the Composition Mechanism of Barium Aluminate with Barium Carbonate and Riopone[A];[C];2008
7 Kang Xue Wang Changzhen~* Tian Yanwen Duan Hongwei (Northeast University,Shenyang 110004,China);Study on Phosphorus Sensor of Carbon Saturated Iron Melts[A];[C];2008
8 Dong Yunhui~(1,2),Li Degang~2,Wang Ping~2,Yu Xianjin~2,Zhang Lipeng~2,Zhai Yuchun~1(1.School of Metallurgy and Materials,Northeastern University,Shenyang 110004,China;2.School of Chemical Engineering,Shandong University of Technology,Zibo 255049,China);New Technology of Preparation of ZrNi Alloy by Direct Electrodeoxidation[A];[C];2008
9 Li Danke Wang Yu College of Materials Science and Engineering,Chongqing University,Chongqing 400044,China;Advances in Oxidation Kinetics of Vanadium in Vanadium Recovery from Hot Metal Containing Vanadium[A];[C];2008
10 Zhang Zhengfu, Wang Fuming, Wang Linjun (School of Metallurgy and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China);Thermodynamic Study on SEN of CaO-ZrO_2-TiO_2-BN[A];[C];2006
【Co-references】
Chinese Journal Full-text Database 1 Hits
1 SHI Fei,WANG Qing-fa,ZHANG Xiang-wen,WANG Li,MI Zhen-tao(Key Laboratory for Green Chemical Technology of State Education Ministry,School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China);The Green Synthesis of 1,2-Propylene Glycol Dinitrate[J];Chinese Journal of Explosives & Propellants;2007-02
【Secondary Citations】
Chinese Journal Full-text Database 5 Hits
1 Zhao Jie,Fu Yanjun Fuxin Shengnuo Chemical Co.,Ltd(Liaoning Fuxin,123003);Comparison and Analysis of Two Kinds of Manufacturing Technology for MMAN[J];Explosive Materials;2006-03
2 CHEN Huai yin,SHAO Jia yu,XU Jin (910 Chemical Co.Itd,Huaibei Coal Mining Corporation,Anhui,235042);Mechanism of Explosion and Deflagration in PR-M Neutralize Procedure[J];;2000-04
3 Zhang Weipeng Zhang Yi'an and Zhao Shengxiang;Effect of Impurities and Prevention of Explosion Accident in Production of Ammonium Nitrate[J];JOURNAL OF THE CHEMICAL FERTILIZER INDUSTRY;2000-01
4 Zhang Weipeng, Zhao Shengxiang and Zhang Yi'an;Effect of Impurities on Thermal Decomposition Properties of Ammonium Nitrate Solution[J];Journal of Chemical Fertilizer Industry;2001-04
5 Wang Xiaohong Guo Ziru Anhui University of Science and Technology (Huainan Anhui 232001);Researching Cases of the Thermal Decomposition and Thermal Stabilization of AN[J];Coal Mine Blasting;2004-01
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved