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《CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS》 1998-03
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Synthesis and Properties of 2,14-dioxo-5,5,11,11-tetranitro-3,7,9,13-tetraoxapentadecane

Wang Cai Ou Yuxiang Chen Boren Chen Jing (Beijing Institute of Technology, Beijing 100081)  
The title compound, a polynitro carboxylic ester was synthesized starting with bis(2,2,2 trinitroethyl) formal via a 3 step reaction:denitration, Henry reaction and esterifiction. The structure of the obtained ester was identified by mp, IR, 1 HNMR,MS and elemental analysis. After experiencing a quite number of runs, the synthetic procedure has been improved and discussed. In addition, some important performances of the target compound were measured and are as follows: density 1.57g/cm 3 (suspension method), sensitivity to impact (explosion probability) 0%(drop hammer of 10kg,drop height of 250mm, 25 runs, charge 50±1mg), endothermic peak temperature of thermal decompersition 266.3℃(DTA method).
【CateGory Index】: TQ560.72
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 DONG Yan,LEI Peng,HU Zhi-zhi(School of Chemical Engineering,University of Science and Technology Liaoning,Anshan 114051,China);New technique on iodination of substituted anilines[J];Journal of University of Science and Technology Liaoning;2009-03
2 MENG Zheng,OU Yu-xiang,LIU Jin-quan,WANG Yan-fei(College of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China);Synthesis Mechanism of Tetranitrodiazidopropionylhexaazaisowurtzitane[J];Chinese Journal of Explosives & Propellants;2006-03
3 Ou Yuxiang Jia Huiping Chen Boren (Beijing Institute of Technology, Beijing 100081);Crystal Structure of Four Polymorphs of Hexanitrohexaazaisowurtzitane[J];CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS;1998-04
4 Fang Zhijie (Nanjing University of Science & Technology) Chen Ju Wang Shaofang (Xi'an Modern Chemistry Research Institute) Chen Li (Nanjing University of Science & Technotogy) Li Fuping (Xi'an Modern Chemistry Research Institute);NITROGEN-15 TRACER STUDIES OF THE MECHANISM OF FORMATION OF RDX[J];Acta Armamentarii;1993-03
5 Wang Naixing Chen Boren Ou Yuxiang (Beijing Institute of Technology);A STUDY ON THE SYNTHESIS OF N,N′,N″-TRI(2-NITRO-BENZO DIF URO XANYL)-MELAMINE[J];Acta Armamentarii;1993-04
6 Lu Chunxu;Cai Chun(Nanjing University of Science & Technology);INVESTIGATION ON A NITRATING AGENT CONSISTING OFMETALLIC NITRATES AND ACETIC ANHYDRIDE[J];Acta Armamentarii;1994-02
7 Lu Ming;LuChunxu;Cai Chun(Nanjing University of Science & Technology);THE CONDENSATION REACTION OF 2,4, 6 TRINITRO-3-AMINOCHLOROBENZENE WITH DIAMINES[J];Acta Armamentarii;1995-02
8 Zhao Xinqi Fang Tao Sun Chenghui (School of material Science and engineering, Beijing Institute of Technology, Beijing, 100081);RESEARCHE AND DEVELOPMENT OF HNIW SYNTHESIS[J];Acta Armamentarii;2004-03
9 CHEN Shu-sen,SHU Qing-hai,JIN Shao-hua,SHI Yan-shan(School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081,China);The Byproducts and Mechanisms of Nitrolysis of Tetraacetyldiformylhexaazaisowurtzitane[J];Acta Armamentarii;2007-01
10 Wang Naixing , Chen Boren Ou Yuxiang (College of Chamical Engineering and Material Science, Beijing Institute of Technology);Synthesis and Some Relevant Study of N,N '-Bis(2,4 -Dinitrobenzofuroxanyl) 1,3,5 -Trinitro -2,6 -Diaminobenzene[J];Journal of Beijing Institute of Technology;1992-04
【Co-references】
Chinese Journal Full-text Database 5 Hits
1 DING Li, LI Ying bo (Xi′an Modern Chemistry Research Institute, Xi′an 710065, China);Novel Development of Syntheses and Properties of 1,3,3- Trinitroazetidine (TNAZ)[J];Chinese Journal of Explosives & Propellants;2002-04
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