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《Acta Scicentiarum Naturalum Universitis Pekinesis》 1983-04
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Studies on the Mechanism of the Polarographic Catalytic Wave of Molybdotartrate Complex with Chlorate

Li Nanqiang, Gao Xiaoxia Department of Chemistry  
In a supporting electrolyte containing, 0.1N H2SO4, 0.02-0.1M K2C4H4O6 and 0.01 -0.15M KClO3, We have determined the composition of the catalytic active complex as H2M0O4·HC4H4O6-. We have further confirmed that the electrode processes may be represented as follows:Where AE1/2 - BE1/2]0, k≥k'. So that the cutalytic wave is in a peak form.
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【References】
Chinese Journal Full-text Database 2 Hits
1 Zheng Xiaoling Lin Shuchang Li Qilong(Department of Chemistry);STUDY ON THE MECHANISM OF THE POLAROGRAPHIC CATALYTIC WAVE OF SULPHOXINE(HQSA)-Mo(Ⅵ) COMPLEX WITH CHLORATE[J];Journal of Beijing Normal University(Natural Science);1989-03
2 Li Nanqiang (Department of Chemistry, Peking University);Electroanalytical Chemistry in China[J];Analytical Laboratory;1987-Z1
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Jiao Kui Zhang Manping Gao XiaoxiaDepartment of Chemistry;Electroanalytical Determination of Micro Amount of Bare Earth Elements in Plants by Polarographic Adsorptive Complex Wave[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1982-06
2 Ye Xianzhen, Jiang Ziwei, Zhou Shengwn, Zhang Zhenyyu, Gao XianxiaDepartment of Chemistry;Polarographic Determination of Tetracycline[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1983-06
3 Jiao Kui He Chengjie Zhang Xiyu Department of Chemistry;The Determination of Trace Amounts of Selenium By Single-Sweep Polarography Ⅰ. On the mechanism of the polarographic catalytic wave of SeSO_~3=-KIO_3[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1984-04
4 Li Nanqiang Zhang Jiankang Department of Chemistry;Studies On the Polarographic Adsorptive Complex Wave of Indium-Alizarin Red S[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1984-06
5 Ye Xianzeng Guan Fuyu Zhao Changming (Department of Chemistry);Single-Sweep Polarographic Determination of Bare Earth Ions by the Substitution Beaction of Cd(Ⅱ)-EDTA in the Presence cf 2,2'-bipyridyl[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1985-04
6 Li Nanqiang Cos Mingxiang (Department of Chemistry);Studies on the Polarographic Behaviours of Dipicolinic Acid[J];Acta Scicentiarum Naturalum Universitis Pekinesis;1986-02
7 Li Qilong Zhu Huiqing Wang Zhenghao (Department of Chemistry);STUDY ON THE MECHANISM OF THE ADSORPTIVE CATALYTIC WAVE OF Ti (Ⅳ)-CUPFERRON COMPLEX[J];Journal of Beijing Normal University(Natural Science);1987-01
8 Zhang Shousong Li Wenhong (Changchun Institute of Applied Chemistry,Academia Sinica);Potentiometric Stripping Analysis with a Thin Film Mercury Glassy Carbon Electrode[J];Chinese Journal of Analytical Chemistry;1982-01
9 Tan Zhengzhi (Laboratory of Geological Bureau of Hunan Province);Cathode-ray Polarographic Determination of Microamounts of Tantalum[J];Chinese Journal of Analytical Chemistry;1982-05
10 Guo Du Wang Erkang (Changchun Institute of Applied Chemistry,Academia Sinica);Polarographic Study of Calcium Complex with Murexide[J];Chinese Journal of Analytical Chemistry;1982-05
【Secondary References】
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1 Lin Hong 1,2 , Guo Wei *1 , Qiang Guanghui 1 1(Department of Chemistry, Northwest University, Xi′an 710069) 2(Department of Chemistry and Environmental Science, Yuxi Teacher′s College, Yuxi 653100);Determination of Dexamethasone Using Its Polarographic Catalytic Wave[J];Chinese Journal of Analytieal Chemistry;2002-04
2 Jiang Zhiliang; Qin Chenszhe(Guangxi Normal University, Cuilin, P. R. China);Oscillopolarographic Study on the Catalytic System of V (Ⅴ)-(NH_4) _2S_2O_8-Benzoglycolic Acid-OP and Its Application[J];JOURNAL OF ANALYTICAL SCIENCE;1995-02
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4 Jiang Zhiliang, Li Xiaojin, Wu Daqiang and Dai Guozhong (Department of Chemistry, Guangxi Normal University, Guilin 541004);OscillopolarographicDetermination of Manganese in ng/L Level by Catalytic Reaction[J];Analytical Laboratory;1992-05
5 GUO Wei, YANG Yia-Ni, SONG Jun-Feng(Institute of Electroanalytical Chemistry, Northwest University, Xian 710069, China);Studies and Application of Polarographic Catalytic Wave of Lysozyme in the Presence of KIO_3[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-02
6 WANG Fu-min*,LIU Bing-zhi (Department of Chemistry and Chemical Engineering,Weinan Teacher′s College,Weinan 714000,China);Polarographic catalytic wave of amiodarone hydrochloride in presence of persulphate and its applications[J];Chemical Reagents;2006-07
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8 LIN Hong LI De-liang SUN Li-mei(Department of Chemistry and Environmental Science,Yuxi Teachers' College,Yuxi,Yunnan 653100);Research on Electrochemistry of Corticosteroids[J];Journal of Yuxi Teachers' College;2006-03
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