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《Acta Scicentiarum Naturalum Universitis Pekinesis》 2001-02
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Study on Catalytic Property of Hemin in the Presence of Anion Surfactant

GUO Zhongxian\ LI Yuanzong (College of Chemistry and Molecular Engineering, Peking University,Beijing,100871) SHEN\ Hanxi (Department of Chemistry,Nankai University,Tianjin,300071)  
A novel catalytic property of hemin is described.In ammonium buffer medium of pH 8 0~8 9,hemin has an ability to catalyze the decoloration of bromopyro\|gallol red.Oxygen dissolved in solution plays a role as an oxidant in the reaction.With sodium dodecylbenzenesulfonate and ethanol as effect\|enhancing agents,the catalytic system obeys the Michaelis\|Menten equation of enzymatic catalysis.The Michaelis constant,catalytic constant and specificity constant of the system are estimated by Lineweaver\|Burk plot to be 3.7×10 -5 ?mol/L,0.64?s -1 and 1.7×10 4?L·mol -1 ·s -1 ,respectively.The mechanism of the hemin oxidase\|like catalytic system is discussed.Based on this,hemin can be spectrophotometrically determined by equilibrium and kinetic procedures with a linear range and 3 σ limit of detection being 2.0×10 -8 ~6.0×10 -7 and 5.0×10 -9 ?mol/L,respectively.
【Fund】: 国家自然科学基金项目! (2 9875 0 11);; 教育部跨世纪优秀人才基金项目;; 中国博士后科学基金项目
【CateGory Index】: O647;O643
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