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《JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY》 2001-02
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Morphology and rheological properties of blends of poly(phenylene oxide) with SEBS and maleated SEBS

WANG Xiao dong ZHANG Qiang FENG Wei JIN Ri guang (College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China)  
The morphology of poly(phenylene oxide)(PPO) blends with styrene ethylene co butadiene styrene block copolymer(SEBS) and a version grafted with maleic anhydride(SEBS g MA) was investigated using a transmission electron microscopy(TEM). SEBS was found to show a typical “sea-island” structure in PPO domain for PPO/SEBS blends. However, SEBS g MA demonstrated a network structure in PPO matrix for PPO/SEBS g MA blends. Toughness improvement for PPO blends with SEBS g MA was contributed to stress releasing in micro cavity. The rheological properties study revealed that the apparent viscosity of PPO/SEBS blends increased with the increasing of SEBS content at all non Newtonian shear rate range, but opposite for PPO/SEBS g MA blends. The main reason of this phenomenon is due to the difference of the miscibility between PPO and SEBS or SEBS g MA, and melt viscosity of SEBS and SEBS g MA.
【Fund】: 国家“8 6 3”高新技术项目 !(715 0 0 7 0 0 6 0 )
【CateGory Index】: TQ316
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