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《Journal of Beijing University of Chemical Technology》 2001-03
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Apparent activation energy of solid-state synthesis of chlorosulfonated polyethylene from chlorinated polyethylene

DING Yun\ ZHAO Bo\ ZHOU Ming yi QIAO Hui JIAO Cui yun (College of Materials Science and Engineering ,Beijing University of Chemical Technology, Beijing 100029,China)  
The apparent activation energy of chlorosulfonation reaction of chlorinated polyethylene(CPE) was studied for the synthesis reaction of chlorosulfonated polyethylene(CSM) from CPE in the solid state. The change of reaction heat was used to measure the reaction speed. A method was proposed for approximately calculating the apparent activation energy. The result indicated that the apparent activation energy was low( E a=9 12 kJ/mol), and the chlorosulfonation reaction of CPE by solid phase could be carried out at low temperature.
【CateGory Index】: O643.1
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【Citations】
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1 ZHAO Bo ZHOU Ming yi QIAO Hui JIAO Cui yun DING Yun (College of Materials Science and Engineering, Beijing University of Chemical Technology,Beijing 100029, China);Study on synthesis of chlorosulfonated polyethylene by solid state method from chlorinated polyethylene[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;2001-02
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