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《Journal of Beijing University of Chemical Technology》 2003-04
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Catalytic synthesis of linear alkylbenzene using supported heteropoly acid catalyst

ZHU Zuo-gang ZHANG Jin-chang LI Cheng-yue (The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China)  
The influences of molar ratios of benzene to dodecene on catalytically synthesizing linear alkylbenzene using supported heteropoly acid catalyst was investigated at a fixed bed reactor and certain reaction conditions. It is showed that the conversion ratio of dodecene and the selectivity of producing 2-alkylbenzene are slightly increased with increasing molar ratio of benzene to dodecene, respectively. The catalyst stability was also investigated at the following reaction conditions. The molar ratio of benzene to dodecene was 4∶1, total liquid space velocity 10?h -1 , and the reaction temperature 120?℃. The results show that the catalyst activity is obviously decreased after it is undergone continuously 70?h reaction at the fixed bed reactor. The deactivated catalyst was characterized by SEM, FT-IR and TG. The results show that the probably reason resulting in the catalyst losing its activity is the polymers, which was produced during the alkylation process, deposited on the catalytic sites.
【Fund】: 国家重点研究发展规划项目 (G2 0 0 0 0 4 80 0 6 )
【CateGory Index】: O625
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【Citations】
Chinese Journal Full-text Database 5 Hits
1 WEN Langyou 1, SHEN Shikong 1, MIN Enze 2 (1 School of Chemical Engineering, University of Petroleum (Beijing), Beijing 102200, China; 2 Research Institute of Petrochemical Processing, SINOPEC, Beijing 100083, China);Alkylation of Benzene with 1-Dodecene Catalyzed by Heteropoly Acids[J];Chinese Journal of Catalysis;2000-06
2 Han Binbing Wang Yao Han Shejiao Jin Yong (Department of Chemical Engineering, Tsinghua University, Beijing, 100084);STUDY ON THE ALKYLATION REACTION OF BENZENE WITH LINEAR DODECENE USING ZEOLITE AS CATALYST[J];CHEMICAL REACTION ENGINEERING AND TECHNOLOGY;1997-02
3 Reaction Process CUI Zhe,HAN Ming-han,CHEN Wei and JIN Yong (Department of Chemical Engineering,Qinghua University,Beijing 100084);Synthesis of Linear Alkylbenzene Using TH-06 Catalyst[J];PETROCHEMICAL TECHNOLOGY;1999-10
4 WT5BX]JIN Ying-jie 1,SHEN Jian 1,REN Jie 1,ZHOU Jing-lai 2 [WT6BZ](1 Department of Petrochemical Technology,Fushun Petroleum Institute,Fushun Liaoning 113001,China; 2 Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan;Study of Solid Acid Catalysts for Alkylation of Benzene with Long Chain Olefine Ⅰ.Preparation and Characterization of Heteropoly Acid Catalysts Supported on Mesoporous Molecular MCM-41[J];PETROCHEMICAL TECHNOLOGY;2000-07
5 MAO Dong-sen,LU Guan-zhong,CHEN Qing-ling,LU Wen-kui 152MAO Dong sen 1,2 ,LU Guan zhong 1,CHEN Qing ling 1,2 ,LU Wen kui 2(1.Research Institute of Industrial Catalysis,East China University of Science And Technology,Shangh;Environmentally Friendly Technology with Solid Acids Substituting Liquid Acids as Catalysts[J];Petrochemical Technology;2001-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 XIE Fu-sheng ZHANG Jin-chang LI Cheng-yue(The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry ofEducation, Beijing University of Chemical Technology, Beijing 100029, China);Investigation of reaction conditions in synthesis of linear alkylbenzene using supported heteropoly acid in a fixed-bed reactor[J];Journal of Beijing University of Chemical Technology;2005-02
2 LI Juan~1 YAN Shi-cheng~2 LI Jian-wei~1 CHEN Biao-hua~1 DENG Wei~1(1.State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Jilin Vocational College of Industry and Technology,Jilin 132000,China);Dodecylbenzene synthesis by the alkylation of benzene with 1-dodecene over mesoporous zeolites[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2006-06
3 MAO Dongsen 1,2* , LU Guanzhong 1, CHEN Qingling 1,2 , XIE Zaiku 2, ZHANG Yuxian 2 (1 Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237; 2 Shanghai Research Institute of Petrochemical;Study on Vapor-Phase Beckmann Rearrangement of Cyclohexanone Oxime over B_2O_3/TiO_2-ZrO_2 Catalyst Ⅰ. Effect of B_2O_3 Loading[J];Chinese Journal of Catalysis;2002-01
4 SUN Xuewen*, ZHAO Suoqi, WANG Ren'an(State Key Laboratory of Heavy Oil Processing, University of Petroleum (Beijing), Beijing 102249, China);Mechanism of Alkylation of Benzene with Ethylene Catalyzed by [bmim]Cl/FeCl_3 Ionic Liquid[J];Chinese Journal of Catalysis;2004-03
5 MAO Dongsen 1*, LU Guanzhong 2, CHEN Qingling 1,2(1 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China; 2 Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China);Preparation and Physico-chemical Properties of Titanium-Zirconium Mixed Oxide and Its Application as a Catalyst Support[J];Chinese Journal of Catalysis;2004-06
6 MAO Dongsen 1,2*, LU Guanzhong 2, CHEN Qingling 1,2(1 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China;2 Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China);Effect of Solvents on Catalytic Performance of B_2O_3/TiO_2-ZrO_2 for Vapor-Phase Beckmann Rearrangement of Cyclohexanone Oxime[J];Chinese Journal of Catalysis;2005-04
7 XU Mei-xian,XU Li-min,HUANG Qiu-feng,LIN Shen (Department of Chemistry, Fujian Normal University, Fuzhou 350007, China);Synthesis of Butyl Acetate Catalied by H_4[PMo_(11)VO_(40)][J];Journal of Fujian Teachers University(Natural Science);2003-01
8 MAO Dong-sen+{1,2}, LU Guan-zhong+2, CHEN Qing-ling+{1,2}, ZHANG Yu-xian+1(1. Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China; 2. Research Institute of Industrial Catalysis,East China University of Science and Technology, S;Study on Vapor-phase Beckmann Rearrangement of CyclohexanoneOxime over B_2O_3/TiO_2-ZrO_2 CatalystⅡ. Effect of Calcination Temperature[J];Journal of Molecular Catalysis (China);2002-03
9 FAN Guang,LIN Cheng (College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou,Fujian 350002,China);Study of one-stage synthesis of terpinyl acetate with Hβ zeolite[J];Journal of Fuzhou University(Natural Sciences Edtion);2005-05
10 Fu Xin(College of Chemistry and Life Science,Weinan Teachers University,Weinan 714000);Research Progress on Solid Acid Catalysts[J];Guangdong Chemical Industry;2012-05
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Bu Yifeng Yang Liying Chen Shu Research Institute of Chemical Engineering, Beijing Institute of Clothing Technology, Beijing 100029;Static Synthesis of Zeolite MCM-22[J];Journal of Beijing Institute of Clothing;2001-02
2 LI Juan~1 YAN Shi-cheng~2 LI Jian-wei~1 CHEN Biao-hua~1 DENG Wei~1(1.State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Jilin Vocational College of Industry and Technology,Jilin 132000,China);Dodecylbenzene synthesis by the alkylation of benzene with 1-dodecene over mesoporous zeolites[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2006-06
3 Xu Yi Wu Peicheng (Research lnstitute of LAB Plant,Jinling Petrochemical Corporation,Nanjing,210046);The Research on Solid Acid Catalyst for Alkylate of Benzene woth Long Chain Olefines to Produce LAB[J];CHINA SURFACTANT DETERGENT & COSMETICS;1998-05
4 LI Yingxia 1, CHEN Biaohua 1*, MENG Weijuan 1, LI Chengyue 1, WANG Wenxing 1, CAO Gang 2(1 The Key Laboratory of Controllable Chemical Reactions of Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China; 2 Beijing Yanshan Petrochemical Corporation, Beijing 102500, China);Effect of Pore Structure and Acidic Property of MCM-22 Zeolite on Product Distribution of Benzene Alkylation with Propylene[J];Chinese Journal of Catalysis;2003-07
5 LI Gong 1,2, KAN Qiubin 1, TONG Huijuan 2, WU Tonghao 1*, XU Ning 1, WU Peng 1, WANG Dongyang 1 (1 College of Chemistry, Jilin University, Changchun 130023, Jilin, China; 2 Department of Chemical Engineering,Jiangsu Polytechnic University, Changzhou 213016, Jiangsu, China);Catalytic Performance of Nanometer MCM-49 Zeolite for Alkylation Reaction of Benzene with 1-Dodecene[J];Chinese Journal of Catalysis;2004-10
6 REN Xingtao 1, CAO Jianqiu 1, WANG Zhenyu 2, LIU Shangyuan 2, XIANG Shouhe 1* (1 Institute of New Catalytic Material Science, College of Chemistry, Nankai University, Tianjin 300071, China; 2 Catalyst Factory, Nankai University, Tianjin 300071, China);Catalytic Performance of Hβ Zeolite Modified with Phosphorus for Isomerization of n-Decane[J];Chinese Journal of Catalysis;2005-03
7 MAO Dongsen~ 1,2* , ZHANG Bin~2, YANG Weimin~2, CHEN Qingling~2, LU Guanzhong~1(1 Research Institute of Applied Catalysis, Department of Chemical Engineering, Shanghai Institute of Technology, Shanghai 200235, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China);Preparation of Phosphorus-Modified HZSM-5 Zeolite and Its Application in the One-Step Synthesis of Dimethyl Ether from Syngas[J];Chinese Journal of Catalysis;2006-11
8 TONG Hui-Juan, LI Gong (School of Petrochemical Engineering, Liaoning University of Petroleum & Chemical Technology, Liaoning Fushun 113001 ,China);Effect of Structure and Acidity of Different Molecular Sieves for Alkylation Reaction of Benzene With 1 - Dodecene[J];Journal of Fushun Petroleum Institute;2003-04
9 LONG Li-hua~1,WANG Yan-bo~2, FU Zai-hui~1,ZHU Hua-yuan~3,HUANG Dao-pei~2 (1. Institute of Fine & Catalytic Synthesis, Hunan Normal University, Hunan Changsha 410008,China; 2. Sinopec Changling Refinery & Chemical Co., Ltd, Hunan Yueyang 414012, China; 3. Sinopec Hunan Jianchang Petrochemical Co., Ltd, Hunan Yueyang 414012,China);Catalytic cracking behaviors of ZSM-5 zeolites modified by phosphorus[J];Industrial Catalysis;2004-05
10 CHANG You-guo,ZHANG Yi,WANG Xue-li,LIAN Pi-yong(Department of Material Chemistry,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,China);Synthesis of β/MCM-41 and its catalytic performance in alkylation[J];Industrial Catalysis;2006-01
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Wu Yue(Changchun Institute of Applied Chemistry,Chineae Academy of Sciences,Changchun,130022);Exploration or Molecular Design or the Solid Acid Catalysts[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);1994-04
2 Mao Dongsen1,2,Lu Guanzhong1,Chen Qingling1,2,Lu Wenkui2,Xie Zaiku2 (1Res Inst Ind Catal,East China Univ Sci Technol,Shanghai,200237) (2Shanghai Research Institute Petrochem Technol,Shanghai,201208);Advances in the Research on the Catalysts for VaporPhase Beckmann Rearrangement of Cyclohexanone Oxime to Caprolactam[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);1999-03
3 Liang Wugeng. Wang Yao. Yu Zhiqing. Jin Yong and Wang Zhanwen(Department of Chemical Engineering,Tsinghua University Beijimg 100084);SYNTHESIS OF LINEAR ALKYLBENZENE IN LIQUID-SOLID CIRCULATING FLUIDIZED BED REACTOR[J];Journal of Chemical Industry and Engineering(China);1995-01
4 Bai Zilong, Fu Yanhong, Chen Shaozhou~*, Chang Keyi and Hu Zhushao(Petroleum Processing Research Center);Studies on Acid Sites and Diffusion Properties of Zeolite Y Catalysts for Alkylation of Aromatics with Long-Chain Alkenes[J];;1993-06
5 Min Enze (Institute of Petroleum Chemical Engineering,China Petro-Chemical Corporation);RESEARCH AREA FOR DEVELOPING NEW PETROCHEMICAL CATALYTIC TECHNOLOGY[J];Chemical Reaction Engineering and Technology;1991-04
6 Wu Dihua (Development Center, China Petrochemical Corporation, Beijing 100029, China);Cleaner Technologies for Producing Commodity Organic Chemicals[J];PROGRESS IN CHEMISTRY;1998-02
7 Wu Yue(Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022, China);Routes of Substitution for Liquid Acid Catalysts [J];PROGRESS IN CHEMISTRY;1998-02
8 Min Enze,Fu Jun;Recent Development of Green Chemistry[J];CHEMISTRY;1999-01
9 Li Yali(Shanghai Research Institute of Petrochemical Technology, Shanghai,201208);PRODUCTION PROCESSES AND MARKET OF BISPHENOL A AT HOME AND ABROAD[J];Science & Technology In Chemical Industry;1999-01
10 He Yigong Li Fen Wang Peng Min Enze (Research Institute of Petroleum Processing, Beijing 100083);RECENT ADVANCES OF ALKYLATION OF ISOPARAFFINS WITH OLEFINS[J];ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION);1997-02
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