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《Journal of Beijing University of Chemical Technology》 2004-06
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Effects of n(SiO_2)/n(Al_2O_3) in MCM-22 acid properties and catalysis in alkylation of benzene with propylene

Cheng Liang 1 Li Ying-xia 1 Chen Biao-hua 1 Li Cheng-yue 1 Cao Gang 2 (1.The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029; 2.Chemicals Division of Beijing Yanshan Petrochemical Co. Ltd, Beijing 102500,China)  
Molecular sieve with n(SiO 2)/n(Al 2O 3) ratios of 20~60 were hydrothermally synthesized with hexamethyleimene used as template. The synthesized zeolites were characterized by XRD. The acidity properties of the synthesized zeolites were investigated by means of NH 3-TPD and Pyridine-IR. The catalytic performance of the synthesized zeolites was also studied in alkylation of benzene with propylene. The experimental results show that (1) MCM-22 molecular sieve can be synthesized as purer phase in n(SiO 2)/n(Al 2O 3) from 30 to 60,(2) with increasing n(SiO 2)/n(Al 2O 3), the Bronsted acid amount of MCM-22 molecular sieve is increased. The catalytic activity of MCM-22 molecular sieve is increased too, and (3) when the n(SiO 2)/n(Al 2O 3) is equal to 40, the selectivity of cumene is the highest, and the amount of di-isopropylbenzene and tri-isopropylbenzene in cumene is the lowest, however, the amount of n-propylbenzene is the highest. The catalytic performance was correlated with the Bronsted acid amount and its proportion of MCM-22 molecular sieve.
【Fund】: 国家重点基础研究发展规划项目 (G2 0 0 0 0 4 80 0 6 )
【CateGory Index】: O643.3
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【References】
Chinese Journal Full-text Database 1 Hits
1 Shi Jiangong1,Lu Guanzhong1,2,Cao Gang3(1.SINOPEC Beijing Yanshan Catalyst Company,Beijing 102500;2.Industrial Catalysis Institute,East China University of Science and Technology,Shanghai 200237;3.No.3 Chemical Plant,SINOPEC Beijing Yanshan Company,Beijing 102500);Advances in the Research on Synthesis and Properties of MWW Zeolite[J];Sino-Global Energy;2010-12
【Citations】
Chinese Journal Full-text Database 2 Hits
1 MENG Wei-Juan, CHEN Biao-hua, LI Ying-xia, LI Cheng-yue, CAO Gang ( The Key Laboratory of Controllable Chemical Reactions of Ministry of Education , Beijing University of Chemical Technology, Beijing 100029, China; Chemicals Division of Yanshan Petrochemical Industry Corporation , Beijing 102500, China );THE CATALYTIC PROPERTIES OF BETA AND MCM-22 IN ALKYLATION OF BENZENE WITH PROPYLENE[J];Acta Petrolei Sinica (Petroleum Processing Section);2003-05
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【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 CHENG Yue1,2,SU Xiao-yuan1,2,JIAO Chuang1,2(1.School of Materials Science and Engineering,Jingdezhen Ceramic Institute,Jingdezhen 333403,China; 2.Key Laboratory of Jiangxi Province for Advanced Ceramic Materials,Jingdezhen 333001,China);Synthesis and Adsorption Performance of Ce-MCM-22 Molecular Sieve[J];Bulletin of the Chinese Ceramic Society;2011-05
2 LI Yongxin,WU Runze,XUE Bing (Department of Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,Jiangsu,China);Synthesis of HMCM-22/MCM-41 and catalytic performance for toluene alkylation with dimethyl carbonate[J];Chemical Industry and Engineering Progress;2010-05
3 Hang Chunyan Li Jianwei Sun Xiaoyan Li Yingxia Chen Biaohua (State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Effects of Alcohol as Organic Auxiliary Chemical on Textural Property and Catalytic Performance of MCM-22 Zeolite[J];Chemical Reaction Engineering and Technology;2008-03
4 Sun Huoyan Li Jianwei Li Yingxia Chen Biaohua (The Key Laboratory of Chemical Resources Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Liquid Phase Alkylation of Benzene with Propylene over YSBH-4 Catalyst[J];Chemical Reaction Engineering and Technology;2010-04
5 Gao Congru,Li Jianwei,Li Yingxia,Chen Biaohua(The Key Laboratory of Chemical Resources Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Boiling Point Alkylation of Benzene with Propylene over YSBH-3 Zeolite Catalyst[J];Chemical Reaction Engineering and Technology;2012-01
6 Gai Xinjun, Wang Li and Deng Jianbiao (Tianjin University, Tianjin, 300720; Chemical Works No.l of Beijing Yanhua Petrochemical Co., Ltd., SINOPEC, Beijing, 102500);The Effects of Molecular Sieve Pore and Acid on Benzene Alkylation with Propylene[J];Petrochemical Industry Technology;2006-02
7 Deng Guangjin~1,Zhang Yu~(1,3),Zhao Yin~1,Li Zheng~1,Yang Jixue~2, Niu Zhimeng~2,Jiang Guoyu~2 (1.Research Institute of Jilin Petrochemical Company,PetroChina,Jilin 132021,China; 2.Dyestujfs Factory of Jilin Petrochemical Company,PetroChina,Jilin 132021,China; 3.Jilin Institute of Chemical Technology,Jilin 132021,China);The Catalytic Performances of Nanometer MCM-49 Zeolites in Alkylation of Benzene with Propylene[J];Petrochemical Industry Technology;2011-02
8 Yang Ruochen1,2,Ma Bo1,Ling Fengxiang2,Yang Weiya2,Shen Zhiqi2,Wang Lei1,2 (1.School of Chemistry and Material Science,Liaoning Shihua University,Fushun Liaoning 113001,China; 2.SINOPEC Fushun Research Institute of Petroleum and Petrochemicals,Fushun Liaoning 113001,China);Synthesis and Characterization of Zeolite MCM-22[J];Petrochemical Technology;2012-01
9 OUYANG Su-fang,LI Ying-xia,LI Jian-wei,CHEN Biao-hua(State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,P.R.China);Synthesis and Catalytic Performance Evaluation of Three Kinds of MWW Zeolites[J];Journal of Petrochemical Universities;2008-01
10 Shi Jiangong1,2,Lu Guanzhong2,Cao Gang3(1.SINOPEC Beijing Yanshan Catalyst Company,Beijing 102500;2.Industrial Catalysis Institute,East China University of Science and Technology,Shanghai 200237;3.Chemicals Department of SINOPEC Beijing Yanshan Petrochemical Company,Beijing 102500);Advances in Research into Application of MWW-type Zeolite[J];Sino-Global Energy;2008-03
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 SUN Shu-yong CAO Da-peng WANG Wen-chuan (College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China);Grand canonical Monte Carlo simulation of pure and binary components sorption equilibria of light hydrocarbons in MCM-22 zeolite[J];Journal of Beijing University of Chemical Technology;2003-04
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3 XIE Zaiku 1, CHEN Qingling 2, ZHANG Chengfang 1, ZHANG Huining 2, CHEN Bo 2 (1 Institute of Chemical Technology, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SI;Influence of OH~-/SiO_2 Ratio on Particle Size Distribution and Structure of β Zeolite during Crystallization[J];CHINESE JOURNAL OF CATALYSIS;2000-01
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5 PENG Jianbiao, XIE Sujuan, WANG Qingxia, XU Longya * (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Control of Crystal Transformation and Mixed Crystals of Some Zeolites and Optimum Conditions for Synthesis of Monocrystal Zeolites[J];Chinese Journal of Catalysis;2002-04
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7 LI Yingxia 1, CHEN Biaohua 1*, MENG Weijuan 1, LI Chengyue 1, WANG Wenxing 1, CAO Gang 2(1 The Key Laboratory of Controllable Chemical Reactions of Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China; 2 Beijing Yanshan Petrochemical Corporation, Beijing 102500, China);Effect of Pore Structure and Acidic Property of MCM-22 Zeolite on Product Distribution of Benzene Alkylation with Propylene[J];Chinese Journal of Catalysis;2003-07
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9 LI Gong 1,2, KAN Qiubin 1, TONG Huijuan 2, WU Tonghao 1*, XU Ning 1, WU Peng 1, WANG Dongyang 1 (1 College of Chemistry, Jilin University, Changchun 130023, Jilin, China; 2 Department of Chemical Engineering,Jiangsu Polytechnic University, Changzhou 213016, Jiangsu, China);Catalytic Performance of Nanometer MCM-49 Zeolite for Alkylation Reaction of Benzene with 1-Dodecene[J];Chinese Journal of Catalysis;2004-10
10 SHANG Yongchen 1,2 , ZHANG Wenxiang1, JIA Mingjun1, PAN Weicheng1, JIANG Dazhen1, WU Tonghao 1* (1 College of Chemistry, Jilin University, Changchun 130023, Jilin, China; 2 Department of Chemistry, Harbin Normal University, Harbin 150080, Heilongjiang, China);Acidity of MCM-22 Zeolites and Their Catalytic Performance for the Skeletal Isomerization of 1-Butene[J];Chinese Journal of Catalysis;2005-06
【Secondary References】
Chinese Journal Full-text Database 3 Hits
1 Sun Huoyan Li Jianwei Li Yingxia Chen Biaohua (The Key Laboratory of Chemical Resources Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Liquid Phase Alkylation of Benzene with Propylene over YSBH-4 Catalyst[J];Chemical Reaction Engineering and Technology;2010-04
2 Gao Congru,Li Jianwei,Li Yingxia,Chen Biaohua(The Key Laboratory of Chemical Resources Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Boiling Point Alkylation of Benzene with Propylene over YSBH-3 Zeolite Catalyst[J];Chemical Reaction Engineering and Technology;2012-01
3 Shi Jiangong;Lu Guanzhong;Cao Gang;SINOPEC Catalyst (Beijing) Co.,Ltd.;Research Institute of Industrial Catalysis ,East China University of Science and Technology;SINOPEC Catalyst Co.,Ltd.;;A Study into Synthesizing MCM-22 Molecular Sieve Using Hybrid Template Agent[J];Sino-Global Energy;2015-01
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