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《Journal of Beijing University of Chemical Technology》 2005-02
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Reaction heat and standard enthalpy of formation of dysprosium perchlorate coordinated with L-glutamic acid

WU Xin-min 1 QI Chuan-song GONG Liang-fa 1 LIU Tai-qi 1 CHEN Li 2 QU Song-sheng 3(1.Department of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China; 2.Hubei Pharm School,Hubei Wuhan 430064; 3.College of Chemistry and Molecular Science, Wuhan University, Hubei Wuhan 430072, China)  
Rare-earth perchlorate complex compound coordinated with L-glutamic acid, Dy_2(Glu)_2(ClO_4)_4·9H_2O, was synthesized. By using TG, DTA and chemical analytic method and comparing with the literatures related, its structure was characterized with a purity of 96.54%. A thermochemical cycle was designed at 25?℃, the chemical reaction and standard enthalpy of formation were measured by a solution calorimeter, and the solution reaction of [2Dy(NO_3)_3·6H_2O+2Glu+6NaClO_4·H_2O] and [Dy_2(Glu)_2(ClO_4)_4·9H_2O+6NaNO_3] were carried out in an isoperibel reaction calorimeter, respectively. The calorimetric solvent used was 2 mol/L HCl. According to the results, the following data were obtained Δ_rH Θ_m=230.588?kJ/mol, Δ_fH Θ_m(Dy_2(Glu)_2(ClO_4)_4·9H_2O, s, 25?℃)=-6?479.828?kJ/mol.
【Fund】: 北京市组织部优秀人才培养专项资助(Z032304)
【CateGory Index】: O642.3
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