Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Beijing University of Chemical Technology》 2005-05
Add to Favorite Get Latest Update

Catalytic synthesis of butanone 1,2-propanediol ketal over H_4SiW_6Mo_6O_(40)/PAn

YANG Shui-jin~1 WANG Min~2(1.Department of Chemistry and Environmental Engineering,Hubei Normal University,Hubei Huangshi 435002,China;2.College of Chemistry,Central China Normal University,Hubei Wuhan 430079,China)  
A new environmentally friendly catalyst,H_4SiW_6Mo_6O_(40)/PAn was prepared.Butanone 1,2-propanediol ketal(Ⅰ) was synthesized from butanone(Ⅱ) and 1,2-propanediol(Ⅲ) in the presence of H_4SiW_6Mo_6O_(40)/PAn(Ⅳ).The factors influencing the synthesis were discussed and the optimum conditions were found.Experimental results show that Ⅳ is an excellent catalyst.With n(Ⅱ)∶n(Ⅲ)=1.0∶1.7,(w(Ⅳ)=)0.6%,and reaction time t=40?min,the yield of Ⅰ can reach 83.1%.
【Fund】: 湖北省自然科学基金和湖北省教育厅重点科研基金(2004D007)
【CateGory Index】: TQ224.2
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 YANG Shui-jin,YIN Guo-jun(Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China);Synthesis of Benzaldehyde 1,2-Propanediol Acetal Catalyzed with La_4(SiW_6Mo_6O_(40))_3[J];Chinese Rare Earths;2008-05
【Citations】
Chinese Journal Full-text Database 5 Hits
1 YANG Shui jin DU Xin xian LV Bao lan(Department of Chemistry and Environmental Engineering, Hubei Normal University, Hubei Huangshi 435002,China);Synthesis of acetals and ketals catalyzed by phosphotungstic acid supported on active carbon[J];Journal of Beijing University of Chemical Technology;2005-01
2 Ma Xueqin Ding Chenyuan Department of Chemistry;Catalytic Synthesis of Acetal by Tungsten Silicic Acid[J];;1997-02
3 Li Yiezhi, Huang Huamin, Jin Hui and Xu Yaqin (Department of Chemistry Jilin University,);Aldol Condensation of Cyclohexanone and Synthesis of Acetal or Ketals[J];Journal of Jilin University;1989-02
4 Li Yaoxian; Liu Zaiqun; Xu Wenguo; Liu Fuan(Department of Chemistry, Jilin University, Changchun, 130023);Synthesis of Acetal (Ketal) Irradiated by Microwave under Normal Pressure[J];ACTA SCIENTIARIUM NATURALIUM UNIVERSITATIS JILINENSIS;1996-03
5 Yu Shanxin (Department of Chemistry,Hunan Normal University);Study on Preparation and Catalytic Activity of a New Polymer Lewis Acid Catalyst[J];Ion Exchange and Adsorption;1991-02
【Co-references】
Chinese Journal Full-text Database 2 Hits
1 Tong Shuang LI;Sheng Hui LI; Ji Tat LI; Hui Zhang LI and Xiu Xiang WU(Department of Chemistry, Hebei University, Babeing 071002, Hebei Province);Efficient and Convenient Procedures for the Formation andCleavage of Steroid Acetals Catalysed by Montmorilloaite K 10[J];中国化学快报(英文版);1996-11
2 Wang Cunde Niu Youqin Qian Wenyuan Yang Xinhua;CATALYSIS OF SIME SOLID SUPERACID MxOy/SO_4~(2-)FOR THE SYNTHESIS OF ACETALS AND KETALS[J];;1991-02
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 Ran Ruicheng, Mao Guoping (Department of Chemistry, Peking University, Beijing);Polymer-Supported Stannic Tetrachloride Complex Catalysts (Ⅱ )——Copolymer (Styrene-Methyl Methacrylate)-Stannic Tetrachloride Complex[J];Chemical Research In Chinese Universities;1989-07
2 Yu Shanxin Department of Chemistry;CATALYTIC ESTERIFICATION BY POLYMER PROTECTED CATALYST PVC-FeCI_3[J];Journal of Natural Science of Hunan Normal University;1990-01
3 Liu Fuan; Li Yaoxian; Xu Wenguo;Song Yanqiu(Department of chemistry,Jilin University, Changchuan 130023);THE MICROWAVE SYNTHESIS OF DIMETHYL FUMARATE[J];CHEMICAL RESEARCH AND APPLICATION;1994-03
4 Li Yiezhi, Huang Huamin, Jin Hui and Xu Yaqin (Department of Chemistry Jilin University,);Aldol Condensation of Cyclohexanone and Synthesis of Acetal or Ketals[J];Journal of Jilin University;1989-02
5 Wang Cunde Yang Xinhua Qian Wenyuan (Yangzhou Institute of Technology, ZIP225001);SYNTHESIS OF ACETALS AND KETALS WITH SOLID SUPERACID CATALYST TiO_2/so_4~(2-)[J];Fine Chemicals;1992-03
6 YANG Shui jin,LIANG Yong guang (Department of Chemistry,Hubei Normal University,Huangshi 435002,China);Study of Catalytic Synthesis of Glucose Esters with TiSiW_(12)O_(40)/TiO_2[J];Fine Chemicals;2001-07
7 YANG Shui jin 1,2 ,CHEN Lu chun 1,LIANG Yong guang 1,SUN Ju tang 2 (1.Department of Chemistry and Environmental Engineering,Hubei Normal University, Huangshi 435002,China;2.College of Chemistry and Molecular Sciences, Wuhan University,Wuhan;Synthesis of Cyclohexanone 1,2-Propylene Ketal Catalyzed by TiSiW_(12)O_(40)/TiO_2[J];Fine Chemicals;2002-10
8 Ma Xueqing(Department of Chemistry,Capital Normal University);Catalytic Synthesis of Bis(2-ethylhexyl)Sebacate using Tungstosilicis Acid[J];JOURNAL OF CAPITAL NORMAL UNIVERSITY(NATURAL SCIENCE EDITION);1994-04
9 WEN Rui-ming, YOU Pei-qing, LUO Xin-xiang, YU Shan-xin (Department of Chemistry, Yiyang Teachers College, Yiyang Hunan 413049, China);Catalytic Synthesis of Acetals or Ketals with Vitamin C[J];Petrochemical Technology;2002-05
10 YANG Shui-jin 1,2 ,YU Xie-qing 2,LIANG Yong-guang 2,SUN Ju-tang 1 (1 College of Chemistry and Molecular Sciences,Wuhan University,Wuhan Hubei 430072,China; 2 Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi Hubei 435002,China);Synthesis of Cinnamates by Using TiSiW_(12) O_(40) /TiO_2 as Catalyst[J];Petrochemical Technology;2003-03
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved