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《Journal of Beijing University of Chemical Technology》 2005-06
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Preparation of biodiesel with soybean oil through solid acid catalyst Zr(SO_4)_2·4H_2O

CAO Hong-yuan CAO Wei-liang ZHANG Jing-chang(College of Science,Beijing University of Chemical Technology,Beijing 100029,China)  
In this work,biodiesel was obtained through transesterification of soybean oil,using Zr(SO_4)_2·4H_2O as a solid acid catalyst.Three principal factors affecting the yield of methyl esters(biodiesel): molar ratio of methanol to oil,amount of catalyst and reaction time were investigated.The methyl esters composition was determined by gas chromatography(GC) at a certain interval, 2?h.The optimized factors: 6∶1 methanol/oil(molar ratio) with 3% Zr(SO_4)_2·4H_2O(mass fraction) reacted at 65?℃ for 6?h,gave a maximum ester yield of 96.6%.
【Fund】: 国家自然科学基金资助项目(20576014)
【CateGory Index】: TE665
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