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《Journal of Beijing University of Chemical Technology(Natural Science Edition)》 2006-04
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Catalytic synthesis of cyclohexanone ethylene ketal with H_3PW_6Mo_6O_(40)/TiO_2

YANG Shui-jin TONG Wen-long LV Bao-lan (Department of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China)  
A new environmentally friendly catalyst,H_3PW_6Mo_6O_(40)/TiO_2 has been prepared.The optimum conditions have been found to be: masses of TiO_2 and H_3PW_6Mo_6O_(40) of 1.0?g,volume of water 30?mL,a soaking time of 12?h,and activation temperature of 150?℃.H_3PW_6Mo_6O_(40)/TiO_2 was used as the catalyst in the synthesis of cyclohexanone ethylene ketal.The effects of varying the n(cyclohexanone)∶n(glycol) ratio,catalyst dosage and reaction time on the yield were investigated.The optimal conditions were found to be: n(cyclohexanone)∶n(glycol)=1∶1.5;mass fraction of catalyst to reactants,1.0%;reaction time,0.75?h and dried cyclohexane,8?mL.Under these conditions,the yield of cyclohexanone ethylene ketal was 87.7%.
【Fund】: 湖北省自然科学基金(2005ABA053)
【CateGory Index】: TQ234.2;O643.32
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