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《Journal of Beijing University of Chemical Technology(Natural Science Edition)》 2007-01
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Interaction of 17β-estradiol and its structural analogues with functional monomers

ZHU QiuJin~(1,2) GU XiaoHong~1 TANG Jian~(1) WANG LinXiang~1 FENG Yu~1 LI GaoYang~1(1.Key Laboratory of Food Science and Safety,Ministry of Education,Southern Yangtze University,Wuxi Jiangsu 214036;2.School of Life Science,Guizhou University,Guiyang Guizhou 550025;3.Testing & Analysis Centre,Southern Yangtze University,Wuxi Jiangsu 214036,China)  
The interaction of 17β-estradiol(17β-E)and its structural analogues with six different functional monomers,namely methyl methacrylate(MMA),acrylamide(AM),methacrylamide(MA),4-vinylpyridine(4-VP),methacrylic acid(MAA) and 2-(trifluoromethyl)acrylic acid(TFMAA) has been studied by ultraviolet (UV) spectroscopy,infrared(IR) spectroscopy and high pressure liquid chromatography(HPLC),and molecularly imprinted polymers(MIP)subsequently synthesized by precipitation polymerization.The O-H and CO IR absorption maxima shift towards higher wavenumbers after imprinting 17β-E on a TFMAA-co-TRIM copolymer(TRIM=trimethylolpropane trimethacrylate) with the red shift of the O-H groups being apparent after precipitation polymerization for 16?h,and that for the CO groups being observed after polymerization for 24?h.The strong interaction between TFMAA and 17β-E was confirmed by the high selectivity for 17β-E,as indicated by the values of the separation factor(a) of isomers of 17β-E/17α-E(2.28) and the imprinted factor(IF)(3.01).The results show that in order to select a suitable functional monomer for fabrication of polymers selective to 17β-E and its structural analogues, preliminary screening may be carried out by monitoring the interaction between monomer and template by UV analysis;subsequently,the MIP should be synthesized,and IR and HPLC employed in order to characterize the properties of the polymer.
【Fund】: 贵州省自然科学基金(20052013)
【CateGory Index】: O631.3
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