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《Journal of University of Science and Technology Beijing》 2003-06
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Synthesis of Butyraldehyde Glycol Acetal by using TiSiW_(12)O_(40)/TiO_2 as Catalyst

YANG Shuijin, YU Xieqing, SUN Jutang Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China  
Butyraldehyde glycol acetal was synthesized from butyraldehyde and glycol in the presence of TiSiW12O40TiO2. The factors influencing the yield of product and the optimum reaction condition were discussed. The optimum condition is the molar ratio of butyraldehyde to glycol is 1:1.5, the quantity of catalyst is equal to 0.5% in mass fraction, and the reaction time is 1.0 h. TiSiW12O40/TiO2 is an excellent catalyst to synthesize butyraldehyde glycol acetal and the yield can be up to 81.9%.
【Fund】: 国家自然科学基金(No.29971024);; 湖北省教育厅重点科研基金(2002A00008)
【CateGory Index】: TQ655
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