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《Journal of Beijing Institute of Technology》 2005-05
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A Novel Synthesis for Glyoxylic Acid with O_2 Catalysed by Nitrogen Oxide

ZHOU Zhi-ming~1,XU Qiao~1,LOU Jun-jun~2,ZHOU Zhen~1,YU Cong-xuan~1(1.School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing100081, China; 2.Zhejiang Hengdian Group Jiayuan Chemical Industry Co. Ltd.,Dongyang, Zhejiang322118, China)  
A novel method was reported for the synthesis of glyoxylic acid from glyoxal oxidized by O_2 under the catalysis of NO_n (n=1,2). A possible reaction mechanism was proposed. Under the optimized reaction conditions (catalyst 0.13~0.15 mol(per mole glyoxal), mass fraction of glyoxylic acid 25%, Lewis acid 0.11~0.13 mol(per mole glyoxal), 40~50 ℃, 0.5 MPa), a good result was achieved with the conversion 98.7%, selectivity 79% and yield 78%. Compared with the industrial method using nitric acid, the present contribution is more safe, economical and less contaminating the environment.
【CateGory Index】: TQ224.124
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