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《Journal of Beijing Institufe of Petrochemical Technology》 2001-01
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Research on Pyrolysis Process and Kinetic Parameters of Kerogen from Songliao Basin in Presence of Mineral Matrixes

Lin Shijing Ge Minglan(Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102600)Li Shuyuan Guo Shaohui(Department of Chemical Engineering,University of Petroleum, Beijing 102200)  
The thermal simulation experiments on kerogen from Songliao basin was carried out by means of Rock -Eval and Py-GC apparatus. The effects of the mineral matrixes in rock on the pyrolysis process, composition of hydrocarbon generated and kinetic parameters were studied. The results show that matrixes have changed the composition of pyrolysis products and have decreased the apparent activation energy of pyrolysis reaction, thus speeding up the progress of reaction. The experiments prove that the catalytic effect of clay minerals can be interpreted by carbonium ion mechanism.
【CateGory Index】: P611
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