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《Journal of Beijing Institute of Light Indusry》 1998-04
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Liu Yun\ Xu Tongkuan\ Xiao Debao\ Zhang Jun\ Sun Y e (Department of Chemical Engineering, Beijing Institute of Light Industry, Beijing 100037)  
The synthetic methods of mesoPorphyrin(TPP) by solventcatalystreaction and under microwave irradation are explored in this paper. It was discoved that the boiling point and polarity of the solvents, acidity of the catalysts, and the content of water in the reaction system were the key factos. With pnitrobentoic acid as the catalyst in toluene or xylene and with a special solvent treatment of distilationaddition at same step, TPP was given by direct condensation of pyrrole and benzaldehyde to 58\^4% of the yield. Comparing with that, 42% of the yield of TPP was got under microwave irradation by the same reaction system in 30min, faster 4\^2 times that of reaction rate of the catalyst method. UV spectrum and cocomponentcalculation were used for valuing the product according to the great difference between the maximum adsorption in the UV spectrum of TPP and its main byproduct 2Hporphyrin(TPC). The purity of the product for TPP was 97\^7% and 99\^76% for recrystallization and column purilation respec
【CateGory Index】: O626.13
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6 LI Zheng;YU Miao;College of Chemistry,Jilin University;;Synthesis and Fluorescence Properties of Meso-tetra(N-alkyl)-carbazolylporphyrins and Their Lanthanide Acetylacetone Complexes[J];吉林大学学报(理学版);2016-06
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