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《Journal of Beijing Institute of Light Indusry》 1998-04
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SYNTHESIS OF MESOTETHAPHENYLPORPHYRINS\=(TPP) BY CATALYST IN SOLVENTS AND \=UNDER MICROWAVE IRRADATION

Liu Yun\ Xu Tongkuan\ Xiao Debao\ Zhang Jun\ Sun Y e (Department of Chemical Engineering, Beijing Institute of Light Industry, Beijing 100037)  
The synthetic methods of mesoPorphyrin(TPP) by solventcatalystreaction and under microwave irradation are explored in this paper. It was discoved that the boiling point and polarity of the solvents, acidity of the catalysts, and the content of water in the reaction system were the key factos. With pnitrobentoic acid as the catalyst in toluene or xylene and with a special solvent treatment of distilationaddition at same step, TPP was given by direct condensation of pyrrole and benzaldehyde to 58\^4% of the yield. Comparing with that, 42% of the yield of TPP was got under microwave irradation by the same reaction system in 30min, faster 4\^2 times that of reaction rate of the catalyst method. UV spectrum and cocomponentcalculation were used for valuing the product according to the great difference between the maximum adsorption in the UV spectrum of TPP and its main byproduct 2Hporphyrin(TPC). The purity of the product for TPP was 97\^7% and 99\^76% for recrystallization and column purilation respec
【CateGory Index】: O626.13
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【References】
Chinese Journal Full-text Database 10 Hits
1 LI Xi-meng;ZHANG Xiao-juan;Shenyang University of Technology School of Petrochemical Engineering;School of Metallurgy Northeastern University;;Synthesis and Optical Properties of Tetra( 3,4-dimethylphenyl)Porphyrin Cobalt[J];合成化学;2016-12
2 Yang Jiandong Wang Duliu(Department of Biology & Chemistry,Longnan Normal College,Chengxian,Gansu 742500);The Progress of the Porphyrins and Metalloporphyrins in Synthesis and Application[J];首都师范大学学报(自然科学版);2012-04
3 Ma,Feng Wang,Shirong Guo,Junjie Li,Xianggao(School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072);Recent Progress of Semiconductors in Organic Thin-Film Transistors[J];有机化学;2012-03
4 Chen Lianqing,Qu Xingyu,Li Qunli,Shi Chao(Key Laboratory of Catalysis and Material Science of the State Ethnic Affairs Commission & Ministry of Education,Hubei Province,College of Chemistry and Materials Science South-Central University for Nationalities,Wuhan 430074,China);Synthesis,Characterization,Photophysical and Electrochemical Properties of Tetraphenylporphyrin Derivatives[J];中南民族大学学报(自然科学版);2009-02
5 HAO Xiao-ling,HAN Shi-tian,LIU Yan-qin(College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050016,China);The Research Development of Porphyrins and Metalloporphyrins[J];河北师范大学学报(自然科学版);2009-01
6 DING Yu-long,LI He,DU Bin,WEI Qin,DUAN Cai-hong(School of Chemistry and Chemical Engineering,Jinan University,Jinan 250022,China);Synthesis Progress of Porphyrin Reagents[J];济南大学学报(自然科学版);2005-03
7 LIU Xin-gang, FENG Ya-qing(School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China);Research Progress on Application and Synthesis of Porphyrins[J];化学推进剂与高分子材料;2004-04
8 ZHAO Sheng-fang,YANG Shui-bin,ZHENG Yan (Department of Chemistry, Huanggang Normal University, Huangzhou 438000, Hubei, China);The synthesis and application of tetraphenylporphyrin[J];黄冈师范学院学报;2004-03
9 CHEN Nian-you, ZHAO Sheng-fang, LIAO Xue-hong, SHU Feng (Department of Chemistry,Huanggang Normal University, Huanggang 438000, Hubei, China);The Microwave Synthesis of Tetraphenyl-Porphyrin[J];武汉大学学报(理学版);2004-02
10 WANG Zheng-yuan,JIANG Gui-ying(Department of Chemistry, Yangzhou Polytechnic College, Yangzhou 225002,China);The Synthesis of Tetraphenyl-Porphyrin(TPP) Under Microwave Irradiation[J];精细化工中间体;2004-01
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 WANG Man-Xiang LI Qiang(College of Science,Beijing Forestry University,Beijing 100083,P.R.China);UV-Visible Spectra of Porphyrin and Its Derivatives[J];光谱实验室;2011-03
2 LIU Mei YAN Wei-Wei RUAN Wen-Juan~* ZHANG Xiao-Hong ZHU Zhi-Ang (Department of Chemistry,Nankai University,Tianjin 300071);Studies on Spectra and Nonlinear Optical Properties of Novel Asymmetry Metalloporphyrins[J];无机化学学报;2010-03
3 LIU Xiang1,DENG Zhen-bo1,WANG Zhang-tao2,CUI Xiang-yan2,JIA Yong1 (1. Key laboratory of Luminescence and Optical Information,Ministry of Education,Institute of Optoelectronics Technology,Beijing Jiaotong University,Beijing 100044;2. Product Integration Department,Beijing BOE Optoelectronics Technology Co.,Ltd.,Beijing 100176,China);The Recent Research Progress of Organic Thin Film Transistor[J];现代显示;2007-12
4 HUANG,Jia-Chia YANG,Li-Gong,a MO,Xionga,b SHI,Min-Mina WANG,Manga CHEN,Hong-Zheng,a (a Department of Polymer Science and Engineering,Key Laboratory of Macromolecule Synthesis and Functionalization of Ministry of Education,Zhejiang University,Hangzhou 310027) (b College of Chemistry and Chemical Engineering,Hunan University,Changsha 410082);Influence of Fluorination Position on Aggregate Structure and Electron Transport of Perylene Diimide Derivatives[J];化学学报;2007-11
5 XIAO Song (Department of Chemistry, Guiyang Medical College, Guiyang 550004, China);Studies on the Fluorescence Spectra of Tetraphenylporphyrine and Its Derivatives[J];贵阳医学院学报;2005-01
6 CHEN Nian-you, ZHAO Sheng-fang, LIAO Xue-hong, SHU Feng (Department of Chemistry,Huanggang Normal University, Huanggang 438000, Hubei, China);The Microwave Synthesis of Tetraphenyl-Porphyrin[J];武汉大学学报(理学版);2004-02
7 SONG Jian xin,GUO Can cheng *,ZHU Ling jian,SUN Zhe (College of Chemistry and Chemical Engineering,Hunan University,Changsha 410082);Synthesis,characterization and spectral property of tetra(p-hydroxyl-3-phenylazo) phenylporphyrin[J];化学试剂;2004-02
8 LUO Kai-jun~1,XIE Ming-gui~2 (1. Analysis and Testing Center, Sichuan Normal University, Chengdu 610066, Sichuan; 2. College of Chemistry, Sichuan University, Chengdu 610064, Sichuan);Synthesis of Meso-tetra-(p-hydroxyl phenyl) Porphyrin and Its Esterified Derivative with Microwave Irradiation[J];四川师范大学学报(自然科学版);2004-02
9 LI Fang 1, ZHENG Huai li 2 1. College of Chemistry, Sichuan University, Chengdu 610064, China 2. Faculty of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;Analysis of Pb(Ⅱ), Cd(Ⅱ) and Cu(Ⅱ) in Chinese Medicine by the System of Porphyrin Complexes and Sulfhydryl Cotton Fiber[J];光谱学与光谱分析;2004-02
10 HUANG Dan,TIAN Shu (Department of Chemistry,Nantong Teachers College,Nantong 226007,China);The Research Development of Porphyrins and Metalloporphyrins[J];江苏石油化工学院学报;2003-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 SUN Yue;ZHANG Xiao-juan;LI Qian-qian;WANG Ran-ran;ZHOU Xue;CHEN Tian-ci;TIAN Jun-qiang;School of Petrochemical Engineer,Shenyang University of Technology;;Synthesis of Meso-tetra(4-hydroxyphenyl) porphyrin[J];广州化工;2018-01
2 WANG Jiaming;GULMIRA·Turdi;YAN Yin;PAYZULLA·Ibirayimhaji;ABLIZ Yimit;College of Chemistry and Chemical Engineering,Xinjiang University;College of Chemistry and Environmental Science,Kashgar University;;Gas-sensing Properties to Ethylenediamine Based on Tetraphenylporphyrin Iron Sensitive Film Optical Waveguide Sensor[J];应用化学;2017-07
3 ZHOU Wen-yao;ZHOU Peng;ZHANG Bing-guang;YANG Chang-jun;DENG Ke-jian;Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission &Ministry of Education,College of Chemistry and Materials Science,South-Central University for Nationalities;;Oxidation of Benzyl Alcohol Catalyzed by Hepta(n-butylthio)-mono(n-butoxy) metalloporphyrazines Through Activating Molecular Oxygen[J];化学与生物工程;2017-06
4 GAO Xue;ZHANG Bing;TANG Yi-Wei;LIU Xiu-Ying;LI Jian-Rong;YANG Yi-Heng;College of Chemistry,Chemical Engineering and Food Safety,Bohai University,Liaoning Provincial Key Laboratory of Food Quality Safety and Functional Food,Engineering and Technology Research Center of Food Preservation,Processing and Safety Control of Liaoning Province;College of Food and Biological Engineering,Zhejiang Gongshang University;;Application of nano porphyrins in detection of fish freshness[J];食品安全质量检测学报;2017-03
5 NING Hui;SUN Shou-peng;CAI Xue;Mudanjiang Normal University Department of Chemistry;;Structural and Spectroscopic Properties of Axially Substituted Porphyrin Zinc[J];牡丹江师范学院学报(自然科学版);2017-01
6 LI Zheng;YU Miao;College of Chemistry,Jilin University;;Synthesis and Fluorescence Properties of Meso-tetra(N-alkyl)-carbazolylporphyrins and Their Lanthanide Acetylacetone Complexes[J];吉林大学学报(理学版);2016-06
7 LI Hui;PENG Hai-yan;GAO Lan-chang;DENG Ke-jian;Key Laboratory of Catalysis and Material Sciences of the State Ethnic Affairs Commission & Ministry of Education,College of Chemistry and Material Sciences,South-Central University for Nationalities;;Effect of Pyridine on Photocatalytic Performance of Cobalt Thioporphyrazine[J];化学与生物工程;2016-05
8 Dai Shengping;Kong Xiangfei;Wang Guixia;Xia Liting;Liu Peng;Yu Caili;College of Chemistry and Biological Engineering,Guilin University of Technology;;Advances in Asymmetric meso-Substituted Porphyrins[J];化学通报;2016-04
9 WANG Chang-hao;CHEN Dian-wei;YU Chun-yu;College of Sciences,Jilin Institute of Chemical Technology;Jilin Yu Wen Middle School;;The Characteristics of ZnPc Organic Photoelectric Transistor[J];吉林化工学院学报;2015-08
10 WANG Dong-xing;WANG Ze-ying;WANG Yue-yue;ZHANG Yong-shuang;WANG Yue;Key Laboratory of Engineering Dielectrics and Its Application,Ministry of Education,School of Applied Science,Harbin University of Science and Technology;;Operation Characteristics Measurements of Vertical Structure Copper Phthalocyanine Thin Film Transistor[J];哈尔滨理工大学学报;2015-04
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