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《Journal of Jiangxi Normal University (Natural Sciences Edition)》 2003-01
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Synthesis of α,β-Unsaturated Ketones and Esters Using Polymer-Supported Selenium Bromide

LIU Xiao-ling,WANG Xing-cong,SHENG Shou-ri,SONG Cai-sheng(Institute of Chemistry,Jiangxi Normal University, Nanchang 330027,China)  
Treatment of the polymer-supported α-phenylseleno ketones and esters prepared from polymer-supported selenium bromide with ketone and ester enolates with hydrogen peroxide afford α,β-unsaturated ketones and esters in good yields and high purities (95%) without further purification. This procedure provides a convenient, wild and high-yielding method for preparation of α,β-unsaturated ketones and esters.
【Fund】: 江西省自然科学基金资助课题(001109)
【CateGory Index】: O621.3
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1 LIU Xiao-ling 1, YU Li-ming 2, SHENG Shou-ri 1, SONG Cai-sheng 1 (1.Institute of Chemistry and Biological Science,Jiangxi Normal University,Nanchang 330027,China;2.Department of Chemistry, Zhejiang University, Xixi Campus, Hangzhou 310028,China);Solid-Phase Synthesis of (E)-1,2-Disubstituted Ethenes by Polystyrene-Supported Vinyl Selenides[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2002-03
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1 XU Qu,LIU Xiao-ling,ZHOU Li-yun,SONG Cai-sheng(Institute of Chemistry,Jiangxi Normal University, Nanchang 330027,China);Solid-Phase Synthesis of Allylic Esters and Ethers[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2003-02
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1 YIN Cai-xia~(1),GAO Zhu-lin~(1),LIU Fu-chu~(1),L(U)·· Jun~(2)(1.Department of Applied Chemistry,Yunnan University,Kunming 650091,China;2.College of Life Science,Yunnan University,Kunming 650091,China);Synthesis of 3-Methylcyclohex-2-en-1-one and(±)3-Methylcyclohex-2-en-1-ol and Measurement on Bioactivity[J];Chemistry & Bioengineering;2006-04
2 Zhang Wanxuan, Chen Jiawei (School of Chemistry and Material Science,Hubei University,Wuhan 430062,China);Study on addition reactions of supported pheylselenol[J];JOURNAL OF HUBEI UNIVERSITY(NATURAL SCIENCE EDITION);2000-01
3 Duan Niejing Yang Guichun (Faculty of Chemistry and Material, Hubei University, Wuhan, 430062);The Study of the Nitrocompounds Reduced to Amines With Polymersupported Borohydride Aniou Resin[J];JOURNAL OF HUBEI UNIVERSITY(NATURAL SCIENCE EDITION);1998-03
4 Fang Guangrong, Zou Qichao, Zhang Yuhong, Wang Rongbo(Analytical Centre of Faculty of chemistry and material science,Hubei University, Wuhan,430062);Preparation and Properties of H_3PW_(12) O_(40) Catalyst supported by polymer[J];Chinese Journal of Colloid and Polynier;2000-04
5 WU Minghu, YANG Guichun, CHEN Zuxing (Department of Chemistry, Xianning Normal College, Xianing 437005 Faculty of Chemistry and Material Science, Hubei University Wuhan 430062);STUDY ON POLYMER SUPPORTED PERBORATE OXIDIZER[J];ION EXCHANGE AND ADSORPTION;2000-02
6 FAN Yunge SHI Zuoqing SHI Rongfu LU Yanling State Key Laboratory of Functional Polymer Materials for Adsorption and Separation Institute of Polymer Chemstry, Nankai University, Tianjin, 300071;PREPARATION OF REM RESIN AND APPLICATION ON NUCLEOPHILIC ADDITIONAL REACTION[J];Ion Exchange and Adsorption;2002-05
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1 LIU Xiao ling, SHENG Shou ri, CHENG Cai xia, SONG Cai sheng (Insistute of Chemistry and Biological Science,Jiangxi Normal University,Nanchang 330027,China);A New Technological Synthetic Process of 4- Phenoxybenzoic Acid[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2001-03
2 SHENG Shou-ri, LIU Xiao-ling, CHENG Cai-xia, SONG Cai-sheng (Institute of Chemistry and Biological Sciences,Jiangxi Normal University,Nanchang 330027,China);Catalytic Synthesis Methyl Chloroacetate with the Sulfonated Poly(Aryl Ether Ketone Ketone) Resin[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2001-04
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