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《Journal of Jiangxi Normal University(Natural Sciences Edition)》 2006-04
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Structural Identification of the Products from Nopyl-Ethyl Ether Ozonization by GC-MS and GC-FTIR

CHEN Jin-zhu~(1a),XIAO Zhuan-quan~2,WANG Zong-de~(1b)(1a.College of Science,1b.College of Forestry,Jiangxi Agricultural University,Nanchang 330045,China;2.Institute of Chemistry and Chemical Engineering Sciences,Jiangxi Normal University,Nanchang 330027,China)  
Nopyl-ethyl ether was ozonized in ethanol at-10 ℃,then the structures of corresponding hydrolysates are confirmed by GC-MS and GCFTIR.They are: 2,2-dimethyl-3-(β-ethoxypropionyl)-cyclobutanone,2,2dimethyl-3-acryloyl-1-cyclobuatneethanal,2,2-dimethyl-3-acryloyl-1-cyclobutaneacetic ester,2,2-dimethyl-3-(β-ethoxypropionyl)-1-cyclobutaneethanal,2,2-dimethyl-3-(β-ethoxypropionyl)-1-cyclobutaneacetic ester.All of them are four-member-ring compounds,the total yield of which is 73%.The cis-isomers of them are more than 84% respectively.
【Fund】: 江西省自然科学基金资助项目(982019);; 国家自然科学基金资助项目(30360085)
【CateGory Index】: O621.25
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