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《Journal of Jiling University (Earth Science Edition)》 2004-04
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Geochemistry characters of inorganic natural gas

WANG Lian-sheng~(1),GUO Zhan-qian~(2),MA Zhi-hong~(1) ,WANG Pu-jun~(1),YUAN Shi-jiang~(3)(1. College of Earth Sciences,Jilin University,Changchun130026,China; 2.Exploration and Development Research Institute of Daqing Oil Field Company Ltd., Daqing163712,China;3.No.2 Drilling Company of Daqing Administrative Bureau, Daqing163413,China)  
CH_4, as well as CO_2, CO, N_2, H_2S, H_2, He, Ne and Ar etc., which were freed from the deep of the earth, is generally called inorganic natural gas. There are some distinct geochemical differences between the organic and inorganic gases,mainly in chemical composition and the composition of isotopes. Inorganic CH_4 have the higher dryness coefficients and its δ~(13)C_1 ratios are almost completely higher than -25‰, and carbon isotope of the CH_4 homologue seems to observe an inverted sequence (changed into lighter with increased carbon number); the carbon isotope of inorganic CO_2 is heavier than that of organic CO_2, and the w(~3He)/w(~4He) of the companying rare gases are lower, etc. These geochemistry differences can be used to discern inorganic natural gases.
【Fund】: 国家自然科学基金项目(40372066)
【CateGory Index】: P618.13
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