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《长春地质学院学报》 1994-02
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DISCOVERY OF GOLD WITH NEGATIVE OXIDATION NUMBER IN PYRITE AND ARSENOPYRITE

Oiu Zhaoming;Rang Mei;Qiu Longwei(Dep. of Applied Geochemistry)  
Pyrite and arsecopyrite are the most important goldbearing minerals.There has been a great deal of arguement on the state of invisible gold in these twominerals.To determinc the valence of gold,the authors carried out photoelectronspectroscopy study on pyrite and arsenopyrite from nine gold deposits.A binding onergypeak at 83 eV(82.8~83.2 eV)was widely found in the samplea,whieh is assigned to bethat of gold. The binding energy is lower than that of Au ̄0(about 84 eV),aswell asAu ̄(1+) and Au ̄(3+).The relationship between oxidation number and binding cnergy suggeststbat the 83 eV peak could be produced by negative valenced gold that exists in the pyriteand arsenopyrite. Such discovery is important to study of gold in various aspects.
【Fund】: 国家自然科学基金 地质行业基金,北京中关村地区联合分析测试中心基金
【CateGory Index】: P578.2
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【Co-citations】
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【Co-references】
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1 AI Guo-dong1,DAI Ta-gen1,CHEN Ming-hui2(1.School of Geosciences and Environmental Engineering,Central South University,Changsha 410083,China;2.No.245 Team of Hunan Non-ferrous Metal Geo-exploration Bureau,Jishou 416007,Hunan Province,China);TYPOMORPHIC CHARACTERISTICS OF PYRITE-ARSENOPYRITE-ANTIMONITE AND OCCURRENCE OF GOLD IN GOLD DEPOSIT:A case study of the gold deposits in Hunan Province[J];地质与资源;2010-02
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