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《China Surfactant Detergent & Cosmetics》 2001-03
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Improvements to the Production Technology and Properties of Heavy Alkylbenzene Sulfonate as Surfactant for EOR

CUI Zheng gang LIU Shi xia WANG Feng ZOU Wen hua ZHANG Tian lin (Chemical and Material Engineering School,Wuxi University of Light Industry,Wuxi 214036,China)[HJ12]  
Heavy alkylbenzene sulfonate(HABS)is a kind of cheap surfactant suitable for enhanced oil recovery(EOR).The sulfonation yield of HAB,however,is generally lower than 70 % with ordinary sulfonation technology,and the tolerance to alkali of HABS is not satisfactory.By analyzing the amount and composition of unsulfonated product and their dependence on sulfonation technology,it is showed that the sulfonation yield of HAB can be increased to a certain extent with evere sulfonation(SO 3/HAB mole ratio of 1 2)but can be easily enhanced to about 80 % by adding some dilution agent with mild sulfonation.Using improved formulations with HABS as major surfactant,the IFT between Daqing crude oil and reservoir water can be reduced to ultra-low(10 -3 mN/m)in wider alkali and surfactant concentration ranges,and the ultra low interfacial tension is obtainable for Daqing crude oil to the hard water of 400 mg/L~500 mg/L.
【CateGory Index】: TQ423
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