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《China Surfactant Detergent & Cosmetics》 2004-01
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Interactions between gemini cationic surfactants and methyl orange

LIU Juan,YU Hong-wei,GUO Xiang-feng,DENG Qi-gang (Chemical and Chemistry Engineering College of Qiqihaer University,Qiqihaer161006,China)  
The interactions of methyl orange(MO)with a series of di(gemini)-cationic surfactants with ester bond(EDC)in aqueous solution were investigated by UV-vis spectroscopy.It is observed that the aggregation of the surfactant and MO takes place at surfactant concentrations far below the critical micelle concentration of the individual surfactants.The aggregation results in a ca.98 nm hypsochromic shift of the π?→π~* absorption band of MO.That is formation of a new absorption band of 365 nm.As the cencentration of EDC further increases to be higher than the cmc,due to the solubilization of MO in EDC micelle,λ_(max) shifts to 430 nm,and the complex formed by the aggregation of EDC and MO separates out.~1HNMR analysis shows that the molar ratio of EDC to MO is 1∶2.
【Fund】: 黑龙江省高校骨干教师创新能力资助计划资助项目(2002)
【CateGory Index】: TQ423
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