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《China Surfactant Detergent & Cosmetics》 2006-03
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Interactions between anionic surfactants and cationic surfactants(Ⅰ)——Surface activity

DU Zhi-ping,WANG Wan-xu(China Research Institute of Daily Chemical Industry,Taiyuan 030001,China)  
The surface activity of mixed anionic surfactants and cationic surfactants has been reviewed by critical micelle concentration(cmc),surface tension at cmc(γ_(cmc)),surface adsorption,strength of surface membrane(lifetime of air bubbles and heptane droplets),and wetting power(contact angle at paraffin surface) and so on.Due to strong electrostatic attraction between the molecules of anionic and cationic surfactants,the aggregations of mixed solution should be much easier than this of single-ionic surfactant solution.At the same time hydropobicity is enhanced.Thus,under suitable conditions,the formation of micelles becomes much easier and the mixtures blend may have higher surface activity.The values of cmc and γ_(cmc) of mixed systems were obviously lower than these of single systems not only at 1∶1 mole ratio but also at other mole ratios.The mole ratio of the molecules at surface adsorption layer is nearly 1∶1 whether the mole ratio of bulk solution at 1∶1 or not.Therefore,the surface viscosity,the strength of the surface membranes and the wetting powerability were improved by mixing anionic surfactants and cationic surfactants.
【CateGory Index】: TQ423.12
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