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《China Surfactant Detergent & Cosmetics》 2006-05
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Synthesis of hexadecylbenzene over supported HF on USY catalyst

CHENG Yu~1,SHEN Jian~1,BA Heng-fei~2,KONG De-lin~2(1.School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,China;2.Petroleum & Chemical Technology Company of Fushun,Fushun 113001,China)  
Hexadecylbenzene was prepared by the alkylation of benzene with hexadecene over supported hydrofluoric acid on USY.The performances of the catalyst were studied by alkylation reaction in a laboratory fixed bed reactor under pressure of(2.5 MPa) and mole ratio of benzene to hexadecene 10∶1.The influences of reaction temperature,space velocity and the composition of the catalyst on the conversion and selectivity were studied.When the mass fraction of fluorine is 3.0%,reaction temperature is 130 ℃ and the space velocity is 3.0 h~(-1),conversion of hexadecene alphaolefin achieves 99.15% and selectivity of hexadecylbenzene achieves 97.03%.The results showed that the catalyst has good activity and stability.
【CateGory Index】: TQ423.9
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【Citations】
Chinese Journal Full-text Database 1 Hits
1 Li Ji Liang (LAB Plant of Jinling Petrochemical Corp.,Nanjing 210046,China);The Recent Application Status of Linear Alkylbenzene Derivatives[J];CHINA SURFACTANT DETERGENT & COSMETICS;2000-03
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 XIE Fu-sheng ZHANG Jin-chang LI Cheng-yue(The Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry ofEducation, Beijing University of Chemical Technology, Beijing 100029, China);Investigation of reaction conditions in synthesis of linear alkylbenzene using supported heteropoly acid in a fixed-bed reactor[J];Journal of Beijing University of Chemical Technology;2005-02
2 LI Juan~1 YAN Shi-cheng~2 LI Jian-wei~1 CHEN Biao-hua~1 DENG Wei~1(1.State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Jilin Vocational College of Industry and Technology,Jilin 132000,China);Dodecylbenzene synthesis by the alkylation of benzene with 1-dodecene over mesoporous zeolites[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2006-06
3 WEN Langyou 1, SHEN Shikong 1, MIN Enze 2 (1 School of Chemical Engineering, University of Petroleum (Beijing), Beijing 102200, China; 2 Research Institute of Petrochemical Processing, SINOPEC, Beijing 100083, China);Alkylation of Benzene with 1-Dodecene Catalyzed by Heteropoly Acids[J];Chinese Journal of Catalysis;2000-06
4 TIAN Ling,LI Jianwei,LI Yingxia,CHEN Biaohua(State Key Laboratory of Chemical Resources Engineering,Beijing University of Chemical Technology,Beijing 100029,China);Synthesis of Dodecylbenzene with Benzene and 1-Dodecene over MCM-22 Zeolite Modified with Phosphorus[J];Chinese Journal of Catalysis;2008-09
5 LIU Chuan-bin,WANG Yue-mei,SHEN Jian~* (School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology, Fushun Liaoning 113001,P.R.China);Catalytic Synthesis of Tetradecylbenzene With Supported HF/USY Catalyst[J];Journal of Liaoning University of Petroleum & Chemical Technology;2006-02
6 LI Li1,2,GAO Wen-yi1,DAI Xi-hai2,REN Li-guo1﹡,LU Zhen-hua(1.School of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China;2.Detergent Chemical Factory of Fushun Petrochemical Company CNPC,Fushun Liaoning 113001,P.R.China)Received 11 September 2006;revised 15 December 2006;accepted 25 December 2006;Liquid Phase Alkylation of Benzene With 1-Dodecene Catalyzed by Methanesulfonic Acid[J];Journal of Liaoning University of Petroleum & Chemical Technology;2007-01
7 LIAO Ke-jian,ZHANG Ling,CONG Yu-feng,SUN Feng-jiao,YU Hong-bo(School of Petrochemical Engineering,Liaoning University of Petroleum & Chemical Technology,Fushun Liaoning 113001,P.R.China);Preparation of Horniness Oxidized Wax by Catalytic Oxidation[J];Journal of Liaoning University of Petroleum & Chemical Technology;2008-04
8 XU Zhao-yu (Anhui Research Institute of Chemical Industry,Hefei 230041,China);Development and Application of Molecular Sieve[J];Technology & Development of Chemical Industry;2007-07
9 WEN Qinwu,SHEN Jian,YANG Lina,LIU Chuanbin (Department of Petrochemical Technology,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning China);Synthesis of dodecylbenzene over supported HF/USY catalyst[J];Industrial Catalysis;2007-07
10 SHEN Jian1*,LIU Chuanbin2,WEN Qinwu2,ZHAO Xin2(1.College of Petrochemical Engineering,Liaoning University of Petroleum & Chemical Technology,Fushun 113001,Liaoning,China; 2.Weifang Hongrun Petrochemical Company,Weifang 261061,Shandong,China);Behavior of trace HF reaction promoter in alkylation catalyzed by HPWA/SBA-15[J];Industrial Catalysis;2008-01
【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 Li Ji Liang (LAB Plant of Jinling Petrochemical Corp.,Nanjing 210046,China);The Recent Application Status of Linear Alkylbenzene Derivatives[J];CHINA SURFACTANT DETERGENT & COSMETICS;2000-03
2 Deng Wei, Jin Yingjie, Ren Jie (Department of Petrochemical Technology, Fushun Petroleum Institute, Liaoning Fushun 113001, China);Alkylation of Benzene with Long Chain Olefins over PW/MCM-41[J];JOURNAL OF FUSHUN PETROLEUM INSTITUTE;2000-01
3 Liang Wugeng. Wang Yao. Yu Zhiqing. Jin Yong and Wang Zhanwen(Department of Chemical Engineering,Tsinghua University Beijimg 100084);SYNTHESIS OF LINEAR ALKYLBENZENE IN LIQUID-SOLID CIRCULATING FLUIDIZED BED REACTOR[J];Journal of Chemical Industry and Engineering(China);1995-01
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