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《Chinese Journal of Catalysis》 1993-04
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Zhao, Dong-yuan;Yang, Ya-shu;Xin, Qin;Zhang, Hui and Guo, Xie-xian (Dalian Institute of Chemical Physics, Academia Sinica, Dalian 115023)  
The surface hydroxy and surface acidic properties of various cross--linked montmorillonites (CLM) containing hydroxy-Al,Ni,and mixed--metal hydroxy-Ni-Al complexes have been investigated by IR and NH3--TPD.The effect of preparation methods and Al/Ni ratio on the acidic properties and cumene cracking activity of these CLM has been also studied.The results show that the Bronsted and dominant Lewis acid sites are present in CLM.Surface acidity of CLM probably originates from the pillars and its surface hydroxy group.The thermal stabilities of the pillars affect greatly the surface hydroxy and acidity.Bronsted and Lewis acid sites and cumene cracking activities are increased with the introduction of Ni.NiAl-CLM prepared by substitution method has more acid sites than that prepared by co-polymerization method.
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Chinese Journal Full-text Database 10 Hits
1 YAO Ming1, LIU Ziyang 1*, WANG Kaixiong1, HAO Xiaoming2, TIAN Huiping2, MIN Enze2(1 Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China; 2 Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China);Effect of Aqueous Ammonia Medium and Fluorine Treatment on Properties of Alumina-Pillared Clays[J];Chinese Journal of Catalysis;2004-03
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Chinese Journal Full-text Database 10 Hits
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