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《CHINESE JOURNAL OF CATALYSIS》 2000-01
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Study on the Surface Acid Properties of Hβ Zeolite

Xie Zaiku 1, Chen Qingling 2, Zhang Chengfang 1, Bao Jiaqing 2, Cao Yuhua 2, Yang Yiqing 2(1 Institute of Chemical Technology, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical  
A method of increasing the amount of acid sites, specially Brnsted acid site, of Hβ zeolite is reported. Hβ samples were prepared through ion exchange with NH 4NO 3 solution, citric acid treatment and 550 ℃ calcination for as synthesized zeolite Beta used NaAlO 2 and α Al 2O 3·H 2O respectively as aluminium source, and characterized by NH 3 TPD, Pyridine IR, 29 Si NMR and 27 Al NMR. It is found that through citric acid treatment, the characteristics of Hβ zeolite change: acid strength decreased, total acid amount increased, Brnsted acid sites increased and Lewis acid sites unvaried.The citric acid treatment of zeolite Beta may have the function of both dealuminization at Si(2Al) site and realuminization at Si(0Al) D site. Therefore the acidity and acid sites of Hβ zeolite are proved to be related to the conditions of synthesis, ion exchange and acid treatment of zeolite Beta, and determined by number and distribution of Al in framework Si configuration in a certain Si/Al ratio range of Hβ(10 15).
【CateGory Index】: O643.36
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