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《CHINESE JOURNAL OF CATALYSIS》 2000-02
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Catalytic Performance of Zeolite Catalysts for Shape Selective Isopropylation of Naphthalene

ZHANG Mingjin 1, CHEN Songying 2, SHEN Shide 1, SUN Yuhan 2, WU Dong 2(1 Department of Chemistry, Wuhan University of Science and Technology, Wuhan, 430081, China; 2 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, The Chinese A  
Naphthalene alkylation with i PrOH was studied over HM, HZSM 5, Hβ and HY zeolites. It was found that the catalytic performance of the catalysts for naphthalene conversion decreased in the order of HYHβHMHZSM 5, but for the selectivity to 2 isopropyl naphthalene (IPN) and 2,6 diisopropyl naphthalene (DIPN) in the order of HMHβHY. It is quite evident that the catalytic activity and selectivity observed for isopropylation of naphthalene strongly depends on the pore structure of the zeolites except their acidity. The product distribution varied with the reaction conditions and Si/Al ratio of the zeolites. Naphthalene conversion decreases slightly or remains unchanged with mild dealumination, but the selectivity especially for 2,6 DIPN increases markedly with steam dealumination. Steam treatment and hydrochloric acid extraction can increase the activity and selectivity of the zeolite catalysts. The conversion and selectivity increase slightly with reaction time but markedly with reaction temperature. The reaction condition n ( i PrOH)/ n (C 10 H 8)=2, θ =250 ℃ and t =4 h may be satisfied for naphthalene isopropylation on mordenite.
【CateGory Index】: O643
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