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《CHINESE JOURNAL OF CATALYSIS》 2000-03
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Catalytic Performance of ZnCl_2/Y Catalyst Prepared by Solid State Microwave Irradiation for Rearrangement Reaction of α-Pinene Oxide

YIN Dulin, YIN Donghong, LI Qianhe, FU Zaihui (Institute of Fine Catalysis and Synthesis, Hunan Normal University, Changsha 410081, China)  
The rearrangement reaction of α pinene oxide over ZnCl 2/Y catalyst prepared by solid state microwave irradiation was investigated. The catalytic performance of the catalyst related to the surface acid properties of Y zeolite. ZnCl 2 was intercalated in Y zeolite and dispersed on its surface, a part of ZnCl 2 give rise to solid state ion exchange with cation of zeolite under microwave irradiation. The dispersed ZnCl 2 (medium Lewis acid strength) and the solid state ion exchanged ZnY (weak Lewis acid strength) favored to produce campholenic aldehyde and pinocamphone, respectively. The strong Brnsted acid on the surface of HY zeolite favored to produce monoterpene which was caused by the second intermolecular dehydration of the alcohol products. The selectivity for carveol increased with the increase of ZnCl 2 loading, and the selectivity for pinocamphone was up to 24% in cyclohexane solvent. The rearrangement products of α- pinene oxide can be obtained selectively by adjusting the surface acid property of Y zeolite.
【Fund】: 国家自然科学基金资助项目 !(29572042;29972011)
【CateGory Index】: O643
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