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《CHINESE JOURNAL OF CATALYSIS》 2000-03
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Preparation of γ- Butyrolactone from 1,4 Butanediol Dehydrogenation over Cu/ZnO/Al_2O_3 Catalyst

CHEN Xuegang, SHEN Wei, XU Hualong, XIANG Yifei (Department of Chemistry, Fudan University, Shanghai 200433, China)  
The catalytic activity of Cu/ZnO/Al 2O 3 catalyst for dehydrogenation of 1,4 butanediol has been studied. The effects of reaction conditions on the catalytic activity have been examined and a more than 95% yield of γ butyrolactone obtained. Moreover, the above results are comparable with the catalytic activity of the same catalyst for hydrogenation of maleic anhydride. Combined with the results of catalytic activity, XRD and AES results show that the catalytic activity depends on Cu 0 and ZnO is good to the high dispersion of Cu 0 on support, while ZnO has a positive effect on dehydrogenation activity, and the structure of the active unit is Cu 0/ZnO x(x≤1).
【CateGory Index】: O643
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