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《Chinese Journal of Catalysis》 2000-05
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Synthesis of ZSM-5 Zeolite Membrane and Its Influencing Factors by a Novel Method

ZHANG Xiongfu, WANG Jinqu , YIN Dehong , LIU Changhou (Research Institute of Adsorption and Inorganic Membrane, Dalian University of Technology, Dalian 116012, China)  
Most zeolite membranes are obtained by conventional hydrothermal synthesis in recent years. However, there exit some problems, such as severe pretreatment of substrates, complicated operation process and the synthesized membrane with some defects. In this paper, ZSM 5 zeolite membranes were prepared by in situ hydrothermal synthesis on porous α Al 2O 3 tubes coated with ZSM 5 seeds by using spraying method. A colloidal ZSM 5 suspension was prepared by dispersing the ZSM 5 seeds in silica sol at concentration of 0.8%~1.0%. During the hydrothermal treatment, a continuous ZSM 5 zeolite membrane was formed. The ZSM 5 zeolite membrane was characterized by XRD, SEM and single gas permeation measurement. Some parameters, such as the concentration of SiO 2 and seeds and the quality of seed crystals in the colloidal suspension, were investigated in detail. It has been shown that the suitable concentration of SiO 2 and seeds and smaller, uniform seed crystals are beneficial to the formation of a continuous smooth coating layer, which is suitable for the formation of defect free ZSM 5 zeolite membrane. The performance of the ZSM 5 zeolite membrane synthesized by using spraying seed coating method is much better than that of the ZSM 5 zeolite membrane synthesized by using the conventional hydrothermal method. The permeability for H 2 is 2.70 μmol/(s·m 2·Pa), the separation factor for H 2/C 3H 8 is as high as above 14 through the membrane synthesized by using the spraying seed coating method. This technique is especially suitable for the industrial synthesis of zeolite membranes.
【Fund】: 中国石油化工集团公司“九五”重大攻关项目!(4970 16 )
【CateGory Index】: O647
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【References】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Xiongfu 1* , LIU Hai'ou 1, WANG Jinqu 1, King Lun YEUNG 2 (1 Institute of Adsorption and Inorganic Membrane, Department of Chemistry and Technology, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 Department of Chemical Engineering, Hong Kong University of Science and Technology, Hong Kong, China);Synthesis of NaA Zeolite Membrane on Seeded Substrate and Its Characterization[J];Chinese Journal of Catalysis;2004-07
2 Cheng Yue Wang Lianjun Li Jiansheng Sun Xiuyun (Dept. of Chem.Eng.,Nanjing University of Science and Technology, Nanjing 210 094);Synthesis and Gas Permeation Performance of ZSM-5 Zeolite Film by Immersing Seeds[J];Bulletin of the Chinese Ceramic Society;2005-03
3 LU Xuwang, TANG Zhigang(New Separation Process Group, Department of Chemical Engineering, Tsinghua University, Beijing100084, China);SYNTHESIS OF ZSM5 ZEOLITE MEMBRANE ON DIFFERENT CARRIERS BY ONE STEP IN SITU HYDROTHERMAL METHOD[J];Journal of The Chinese Ceramic Society;2004-10
4 WANG Li-na,LI Yong-hong(School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China);Factors Affecting the Synthesis of ZSM-5 Zeolite Membranes and Its Formation Process[J];Chemical Industry and Engineering;2006-06
5 ZHANG Xiongfu, WANG Jinqu, LIU Changhou (Institute of Adsorption and Inorganic Membrane, Dalian University of Technology, Dalian 116012, China);Developments of the synthesis of ZSM-5 zeolite membrane and dehydrogenation of ethylbenzen in membrane reactors[J];Membrane Science and Technology;2001-02
6 LU Jinming, LI Yanling, WANG Jinqu, Li Bangmin, SONG Xuezhang(Institute of Adsorption and Inorganic Membrane,Dalian University of Technology,Dalian 116012,China);Synthesis of high permeability ZSM-5 zeolite membrane by adjusting seed size[J];Membrane Science and Technology;2005-01
7 HUANG Aisheng, LI Yanshuo, LIU Jie, YANG Weishense Academy of Sciences, Dalian 116023, China);Isopropanol dehydration by pervaporation using A-type zeolite membrane prepared by vacuum seeding method[J];Membrane Science and Technology;2005-02
8 CHENG Yue~(1,2),WANG Lianjun~1,LI Jiansheng~1,SUN Xiuyun~1,LIU Xiaodong~1 (1.School of Chemstry and Engineering,Nanjing University of Science and Technology,Nanjing 210094,China; 2.School of Materials,Jingdezhen Ceramics Institute,Jingdezhen 333001,China);Study on synthesis law of ZSM-5 zeolite membrane by the secondary growth method[J];Membrane Science and Technology;2006-04
9 Guan Hui1,2 Zheng Junlin2 Kong Dejin2 Huang Min1(1.Dpartment of Chemistry,Tongji University,Shanghai 200092,China;2.Shanghai Research Institute of Petrochemical Technology,Sinopec,Shanghai 201208,China);Synthesis of High Quality Silicalite-1 Membrane by a Novel Two-Step Method[J];Chemical Reaction Engineering and Technology;2009-05
10 ZHANG Xiong-fu,LI Bang-min,WANG Jin-qu,LIU Chang-hou (Institute of Adsorption and Inorganic Membrane,Dalian University of Technology,Dalian Liaoning?116012,China);Study on the Removal Process of Template from ZSM-5 Zeolite Membrane on Porous α-Al_2O_3 Substrate[J];Petrochemical Technology;2002-01
【Citations】
Chinese Journal Full-text Database 1 Hits
1 ZHANG Xiong fu and WANG Jin qu (Institute of Adsorption and Inorganic Membrane,Dalian University of Technology,Dalian 116012);Developments in Synthesis and Application of Zeolite Membrane[J];PETROCHEMICAL TECHNOLOGY;1999-04
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 ZHANG Yanfeng 1, LU Guanzhong 1, XU Zhongqiang 1,2 , CHEN Qingling 2 (1 Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology of SINOPEC, Shanghai 201208, China);The Synthesis and Characterization of MFI Zeolite Membrane[J];Chinese Journal of Catalysis;2000-05
2 ZHANG Yanfeng 1, XU Zhongqiang 2* , CHEN Qingling 2 (1 School of Chemistry and Pharmaceutics, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201;In Situ Synthesis of Mordenite Membrane on Alumina Tube by Hydrothermal Method[J];Chinese Journal of Catalysis;2001-04
3 ZHANG Yanfeng 1, XU Zhongqiang 2* , CHEN Qingling 2 (1 School of Chemistry and Pharmaceutics, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201;Preparation and Characterization of Small Crystal Mordenite Membrane[J];Chinese Journal of Catalysis;2002-02
4 ZHANG Yanfeng 1, XU Zhongqiang 2* , CHEN Qingling 2 (1 School of Chemistry and Pharmaceutics, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201;Preparation of High Permselective Mordenite Membrane and Its Use for Separation of Alcohol/Water Mixture[J];Chinese Journal of Catalysis;2002-03
5 LI Yong-Sheng *, WANG Jin Qu, GUO Shu Cai [WT5”BX](Institute of Adsorption and Inorganic Membrane, Dalian University of Technology, Dalian 116012, China) [WT5HZ];Synthesis of High Permeances of ZSM-5 Zeolite Membranes[J];Chemical Research In Chinese Universities;2000-12
6 LI Jun, LONG Ying Cai  (Department of Chemistry, Fudan University, Shanghai 200433, China);A Novel Method for Preparation of Silicalite-1 Zeolite Membrane in Vapor Phase[J];Chemical Research In Chinese Universities;2001-02
7 ZHANG Xiong-fu, WANG Jin-qu, LIU Hai-ou, LIU Chang-hou (Institute of Adsorption and Inorganic Membrane,Dalian University of Technology, Dalian 116012, China);Studies of Dehydrogenation of Ethylbenzene in Zeolite Membrane Reactors[J];Journal of Chemical Engineering of Chinese Universities;2001-02
8 ZHAO Yan (SINOPEC Fushun Research Institute of Petroleum & Petrochemicals, Liaoning Fushun 113001, China);Acidity of alumina, modified alumina and aluminum silicate(Continued)[J];Gongye Cuihua (Industrial Catalysis);2002-03
9 KONG Chun-long, WANG Jin-qu, LU Jin-ming, TAO Kai (Inst. Adsorption & Inorganic Membrane, State Key Lab. Fine Chem., Dalian Univ. Technol., Dalian, Liaoning 116012, China);Synthesis of Silicalite-1 Zeolite Membrane by Nanocrystal Seed Coating Method[J];The Chinese Journal of Process Engineering;2007-01
10 YUAN Wen-hui,LUO Yi-ke,HU Xiao-fang (Research Institute of Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong Province,China);Preparation and gas permeation properties of MFI-type zeolite membrane[J];Chemical Engineering;2006-10
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Wang shusen;Zeng Meiyun;Wang Zhizhong(Department of Chemistry and Environment Engineering, Beijing Polytechnic University,100022);Carbon Membranes for Gas Separations-Effect of Pore Size on Membrane Separation Characteristics[J];JOURNAL OF BEIJING POLYTECHNIC UNIVERSITY;1994-02
2 LI Po~1, XIE Hai-fen~(1,2), LIU Zhi-cheng~3, HUANG Yi-ping~2, ZHAO Dong-yuan~3 (1.Dept of Microelectronices,Fudan University,Shanghai 200433,China;2.Dept of Phys,East China University of Science and Technology,Shanghai 200237,China;3.Dept of Chemistry,Fudan University,Shanghai 200433,China);Novel gas sensor based on nano-zeolite[J];Journal of Transducer Technology;2004-05
3 Li Yongxiang; Ma Aifen; Wu Chongruo (Southeast University);Zeolites as Sensitive Material for Gas Sensors[J];JOURNAL OF TRANSDUCER TECHNOLOGY;1996-03
4 ZHANG Yanfeng 1, LU Guanzhong 1, XU Zhongqiang 1,2 , CHEN Qingling 2 (1 Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology of SINOPEC, Shanghai 201208, China);The Synthesis and Characterization of MFI Zeolite Membrane[J];Chinese Journal of Catalysis;2000-05
5 LIN Haiqiang, CHAO Zisheng, CHEN Guozhou, WAN Huilin (State Key Laboratory of Physical Chemistry for the Solid Surface, Department of Chemistry, Xiamen University, Xiamen 361005, China);Synthesis and Gas Separation Performance of NaA Zeolite Composite Membrane[J];CHINESE JOURNAL OF CATALYSIS;2000-05
6 LI Xiansen, XIANG Shouhe (Department of Chemistry, Nankai University, Tianjin 300071, China);Preparation of Silicalite-1 and β Zeolite/Ceramic Composite Membranes and Their Separation Performance for PhOH/H_2O and C_6H_6/H_2O[J];CHINESE JOURNAL OF CATALYSIS;2000-05
7 XU Zhongqiang 1, 2 , LU Guangzhong 1, CHEN Qingling 2, MA Yi Hua 3 (1 The Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINO;Synthesis of X Zeolite Membrane on Mesoporous Substrates by Secondary Growth[J];CHINESE JOURNAL OF CATALYSIS;2000-05
8 ZHANG Yanfeng 1, XU Zhongqiang 2* , CHEN Qingling 2 (1 School of Chemistry and Pharmaceutics, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201;In Situ Synthesis of Mordenite Membrane on Alumina Tube by Hydrothermal Method[J];Chinese Journal of Catalysis;2001-04
9 WANG Lan 1, MENG Shuanghe 1, TAN Zhicheng 1* , LIANG Dongbai 1, GUO Xinwen 2, WANG Xiangsheng 2 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, China; 2 State Key Laboratory of Fine Chemicals, Dalian Un;Study on Thermostability of Nanosized ZSM-5 Zeolite[J];Chinese Journal of Catalysis;2001-05
10 ZHANG Yanfeng 1, XU Zhongqiang 2* , CHEN Qingling 2 (1 School of Chemistry and Pharmaceutics, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201;Preparation and Characterization of Small Crystal Mordenite Membrane[J];Chinese Journal of Catalysis;2002-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 CHEN Xiang-shu,HU Na,ZHOU Rong-fei,WANG Zhen-zhuo (Institute of Chemistry and Chemical Engineering,Jiangxi Normal University,Jiangxi Inorganic Membrane Materials Engineering Research Center,,Nanchang 330022,China);Studies on Synthesis of Zeolite NaA Membrane and Their Pervaporation Performance[J];Journal of Jiangxi Normal University(Natural Sciences Edition);2008-05
2 ZHANG Xiong-fu~(*1),LIU Hai-ou~2,WANG An-jie~2,WANG Jin-qu~1(1.Dept.of Chem.and Technol.,School of Chem.Eng.,Dalian Univ.of Technol., Dalian 116012,China;2.State Key Lab.of Fine Chem., Dalian Univ.of Technol.,Dalian 116012,China);Synthesis and structural analysis of Silicalite-1 membranes by coating technique with nanosized seed[J];Journal of Dalian University of Technology;2006-02
3 ZHANG Xiong-Fu~(1*), LIU Hai-Ou~1, King-Lun Yueng~2, WANG Jin-Qu~1 (1. Institute of Adsorption and Inorganic Membrane, Department of Chemical Technology, School of Chemical and Engineering, Dalian University of Technology, Dalian 116012, China; 2. Department of Chemical Engineering, Hong Kong University of Science and Technology, Hong Kong, China);Growth Mechanism of Zeolite NaA Membranes and the Thickness Control of the Membrane by Secondary Synthesis from Clear Solutions[J];Chemical Research In Chinese Universities;2005-05
4 SHAO Guo-lin1,WANG Ji-ping1,LIU Chang2,ZHOU Zhi-hui1,WANG Jin-qu1(1.State Key Laboratory of Fine Chemicals,Institute of Adsorption and Inorganic Membrane,Dalian University of Technology,Dalian 116012,China;2.Fushun Research Institute of Petroleum and Petrochemicals,Fushun 113001,China);Studies on the Preparation of Beta Zeolite Membrane on Porous α-Al_2O_3 Tubes[J];Bulletin of the Chinese Ceramic Society;2007-02
5 Liu Zan1,Wang Xinzhong2,Chen Aimin1(1.Tianjin Research and Design Institute of Chemical Industry,Tianjin 300131,China; 2.Zhenghe Group Co.,Ltd.,Dongying 257300,China);Progress of the research on zeolite membrane separating technology[J];Industrial Water Treatment;2006-11
6 HUANG Yanke1,XU Wenqing1,YANG Weishen2,ZHU Linghui1,TAN Zhenming1(1 Research Institute of Dushanzi Petrochemical Company,PetroChina,Dushanzi 833600,XinJiang,China;2 Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China);Separation of ethylene glycol/water mixture with A-type zeolite membrane[J];Chemical Industry and Engineering Progress;2006-09
7 YIN Xiaowei,FENG Hui,JU Shengui (State Key Laboratory of Materials-Oriented Chemical Engineering,Nanjing University of Technology,Nanjing 210009,Jiangsu,China);Investigation on desulfurizing performance of ZSM-5 membrane loaded with cupric ion[J];Chemical Industry and Engineering Progress;2008-11
8 Liu Xiujun~(1,2) Zhao Naiqin~1 1.School of Material Science and Engineering,Tianjin University,Tianiin 300072,China; 2.School of Material Science and Chemical Engineering,Tianjin Polytechnic University,Tianjin 300160,China;Effect of Carbon Fiber Doping on Performance of Catalyst for Ethylbenzene Dehydrogenation[J];Chemical Reaction Engineering and Technology;2006-03
9 Sun Shuhong1,Ding Wei1,Li Chaoxin2,Wang Li1,Pang Xinmei1,Gao Xionghou1 (1.Lanzhou Petrochemical Research Center,PetroChina,Lanzhou 730060,China;2.Catalyst Plant of Lanzhou Petrochemical Company,PetroChina,Lanzhou 730060,China);Synthesis of zeolites ZSM-5 by using water glass[J];Petrochemical Technology & Application;2007-06
10 WANG Lina 1, QIAN Jinwen 1, CHEN Huanlin 2 (1 Department of Polymer Science and Engineering; 2.Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China);The latest development of pervaporation separating membranes for xylene isomers[J];Membrane Science and Technology;2003-03
【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 FAN Shuanshi ;LI Chunhua; WANG Jinqu; CHEN Fangzhen(Dalian University of Technology);PREPARATION AND CHARACTERIZATION OF A PURE ZEOLITIC MEMBRANE[J];CHINESE JOURNAL OF MATERIAL RESEARCH;1994-01
2 Zhang Xiongfu,Wang Jinqu;The progress of the catalytic conversion of lower alkanes to aromatics by inorganic membrane[J];MEMBRANE SCIENCE AND TECHNOLOGY;1998-02
3 Fan Shuanshi;Shi Xiaonong;Li Chunhua and Wang Jinqu(Institute of Adsorption and Inorganic Membranes,Dalian University of Thechnology,Dalian 116012);Studies on Synthesis of ZSM-5 Zeolite Membrane on Porous Supports[J];PETROCHEMICAL TECHNOLOGY;1995-05
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