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《Chinese Journal of Catalysis》 2001-01
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Effect of Zinc Content on Properties of Zn/HZSM-5 Zeolite Catalyst

YIN Shuangfeng, LIN Jie *, YU Zhongwei (Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China)  
The surface properties of Zn/HZSM 5 zeolite with different zinc content and its catalytic performance for n C 6H 14 aromatization were studied. The results showed that, by loading zinc, the Lewis acidity and the total acidity of HZSM 5 increased, while the Brnsted acidity decreased. With the increase of zinc content, the catalytic activity and aromatization selectivity were improved. The stability of the catalyst declined when the zinc content exceeded 1%, and the more zinc on HZSM 5, the more rapid did the catalyst deactivate. The preferred zinc content in Zn/HZSM 5 is 1 0%~2 9%. It is supposed that the catalytic properties of Zn/HZSM 5 is closely correlated with its surface acidity and shape selectivity, as well as the dehydrogenation function of zinc component.
【CateGory Index】: O643
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