Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chinese Journal of Catalysis》 2002-02
Add to Favorite Get Latest Update

Preliminary Study on Enzymatic Conversion of Carbon Dioxide to Methanol by Sol-Gel Encapsulation

JIANG Zhongyi 1,2 , WU Hong 2* , XU Songwei 2, HUANG Shufang 2, XIE Qing 2 (1 State Key Laboratory of C1 Chemical Technology, College of Chemical Engineering, Tianjin University, Tianjin 300072, China; 2 College of Chemical Engineering, Tianj  
In order to explore the new approaches for immobilizing and utilizing carbon dioxide, the greenhouse gas, the modified sol gel process was employed to co immobilize formate dehydrogenase, formaldehyde dehydrogenase and alcohol dehydrogenase using tetraethyl orthosilicate as the precursor. The enzymatic conversion of carbon dioxide to methanol was realized under low temperature and low pressure with the three encapsulated enzymes as the catalysts and NADH as the electron donor. The effects of the reaction temperature, pH, amounts of enzymes and NADH on the yield of methanol were preliminarily investigated. The highest yield of methanol is up to 92 4%. The gel immobilized enzymes show a little lower activity than the free enzymes under the same reaction conditions. This is due to the minor conformation change of enzymes and the existence of steric hindrance.
【Fund】: 国家自然科学基金资助项目 (2 0 1760 3 9)
【CateGory Index】: O643.3
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
Chinese Journal Full-text Database 10 Hits
1 CUI Junru, XIN Jiaying *, NIU Jianzhong, XIA Chungu, LI Shuben (State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, Gansu, China);Biosynthesis of Methanol from Methane by Methanotrophic Bacteria in the Presence of Carbon Dioxide[J];Chinese Journal of Catalysis;2004-06
2 LIU Wenfang,HOU Benxiang,HOU Yanhui,ZHAO Zhiping * School of Chemical Engineering and Environment,Beijing Institute of Technology,Beijing 100081,China;Synthesis of Formic Acid from CO_2 Catalyzed by Formate Dehydrogenase Immobilized on Hollow Fiber Membrane[J];Chinese Journal of Catalysis;2012-04
3 Gu Xujiong, Liu Lin, Lou Jian, Zhang Chengli;Studies on coimmobilization of α-Amylase and glucoamylas on celite[J];Feed Industry;2006-18
4 HUANG Shu\|fang\+1, JIANG Zhong\|yi\+\{1, 2\}, WU Hong\+1, XU Song\|wei\+1 (1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 0072, China);Study on Enzymatic Reaction Kinetics Catalyzed by Free and Sol-gel Immobilized Formaldehyde Dehydrogenase[J];Journal of Molecular Catalysis;2003-04
5 CUI Jun-ru, XIN Jia-ying, NIU Jian-zhong, XIA Chun-gu, LI Shu-benInstitute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China);Biosynthesis of Methanol from Carbon Dioxide by Methanotrophic Bacteria[J];Journal of Molecular Catalysis;2004-03
6 HUANG Shu\|fang 1, JIANG Zhong\|yi 1,2 , WU Hong 1, XU Song \|wei 1 (1.School of Chemical Engineering,Tianjin University,Tianjin\ 300072,China; 2.State Key Laboratory of C1 Chemical Technology,Tianjin Universi ty,Tianjin\ 300072,China);Problems and Solutions of Enzyme Encapsulation through Sol-gel Process[J];Polymer Bulletin;2003-05
7 XU Sheng-xian~1, LI Feng-yi~2 (1.Department of Chemical Engineering,South China University of Technology,Guangdong Guangzhou 510640, China; 2.Institute of Applied Chemistry,Nanchang University,Jiangxi Nanchang 330047, China);Application of sol-gel technique in synthesis of heterogeneous catalysts[J];Industrial Catalysis;2004-05
8 JIN Yun-zhou,QIAN Jun-lü, WU Yan-hui(Department of Chemistry,Tongji University,Shanghai 200092,China);Advances in preparation of catalysts by sol-gel method[J];Industrial Catalysis;2006-11
9 YANG Shu1,XUE Li-mei2,CHEN Bin2,SONG Ya-nan2,LI Cheng-lin2,KONG Xiao-hong2,GAO Xue-peng2(1 Institute of Petrochemistry,HLJ Academy of Science,Heilongjiang Harbin 150040; 2 Heilongjiang institute of Science and Technology,Heilongjiang Harbin 150027; 3 Harbin Aircraft Industry Refco(Group) Co.,Ltd.,Heilongjiang Harbin 150001,China);Preparation and Performance of Composite Photocatalyst LaFeO_3/TiO_2[J];Guangzhou Chemical Industry;2013-10
10 PENG Yan-li1,ZHAO Hua-zhang2,YANG Qin-zheng1,SONG Juan3(1.School of Food and Bioengineering,Shandong Institute of Light Industry,Jinan 250353,China;2.College of Environmental Sciences and Engineering,Peking University,Beijing 100871,China;3.Jinan Bosi Compiled Services Ltd.,Jinan 250100,China);Progress in Microbial and Enzyme Immobilization of Carbon Dioxide[J];Chemistry & Bioengineering;2010-07
China Proceedings of conference Full-text Database 1 Hits
1 LIU Wen fang,HOU Yanhui,ZHAO Zhiping, ZHU Dan,HOU Benxiang (School of Chemical Engineering & the Environment,Beijing Institute of Technology,Beijing 100081,China);Research on the immobilization of formate dehydrogenase on grafted PE hollow fibre membrane[A];[C];2010
Chinese Journal Full-text Database 10 Hits
1 WANG Bao-kang (1.Hunan Agricultural University,Changsha 410128,China; 2.The First Light Industrial School of Anhui Province,Bengbu 233010,China);Effect of Preparation of Porous Glass Microsphere Carrier on Immobilized α-Amylase[J];Anhui Chemical Industry;2007-06
2 LIN Fan-hua,ZHANG Qing-qing,TANG Bin,JIN Qing-bo(Dept of Bioch.Engn.,Anhui University of Technology and Science,Wuhu 241000,China);On the acetylcellulose/polypropylene composite membrane-immobilized lipase[J];Journal of Anhui University of Technology and Science(Natural Science);2007-03
3 SHAO Bing et al(School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,Jiangsu 212013);Preparation for Polyvinyl Alcohol Hollow Microsphere and Its Sustained Release Effect on Urea[J];Journal of Anhui Agricultural Sciences;2008-33
4 LAN Li-xin et al (Applied Chemistry Department of Hunan Chemical Industry and Vocation Technology College,Zhuzhou,Hunan 412004);Research Progress of Microbial Llipases Application[J];Journal of Anhui Agricultural Sciences;2010-14
5 FENG Hui,XIE Ji-an,MEI Li-hua(Anhui Center for Disease Control and Prevention,Hefei Anhui,230061,China);Experimental Research on Rapid Test for Sudan 1 in Chili Powder with HPLC[J];Anhui Journal of Prevent Medicine;2006-02
6 Zhang Yizhu Peng Xiao Tang Jiafang Yu Dunshou (College of life Science,Wuhan University,Wuhan 430072);Enzymatic Resolution of DL phenylalanine with Hog Renal Acylase[J];AMINO ACIDS & BIOTIC RESOURCES;1999-02
7 Fan Jun Li Chun Ji Yaoqing Cheng Beijiu Jiang Like (The Biotechnoligical Research Center,Anhui Agricultural University,Hefei 230036);Horseradish Peroxidase:Isolation,Preparation and Purification[J];JOURNAL OF ANHUI AGRICULTURAL UNIVERSITY;1998-03
8 LIU Li,QU Li-ya(Analysis Centre,Guizhou Research and Designing Institute for Environmental Science,Guiyang 550002,China);Advances in study of electrochemical biosensor for determining organophosphorus pesticides[J];Journal of Safety and Environment;2005-05
9 Fu Jun 1,He Ping 2 and Dong Mingyou 3(1 Department of Physics,Hainan Normal University,Haikou 571158,China) (2 Department of Physics,Guangxi Teachers College,NanNing 530001,China) (3 Haikou Keyu Electronic Component Factory,HaiKou 571100,China);Gas-Sensing Catalysis Characteristics of CeO_2-TiO_2 Co-Oxide[J];Chinese Journal of Semiconductors;2002-03
10 Zhou Xiaowen; Li Xueping; Lin Yuan and Xiao Xurui (Institute of Photographic Chemistry,The Chinese Academy of Sciences,The Centre of Photoclectrochemittry, Beijing 100101);Preparation and Photophysical Properties of CdS Ultrasmall Particles in Polymer Films[J];CHINESE JOURNAL OF SEMICONDUCTORS;1994-12
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 LU Bing et al(Guangxi Key Lab of Environmental Engineering and Protection and Assessment,Guilin,Guangxi 541004);Immobilization of Laccase from Ganoderma lucidum LYL 263 in Sol-gel System[J];Journal of Anhui Agricultural Sciences;2012-10
2 Chen Dong-mei(Yili Kazakh Autonomous Prefecture Product Quality Inspection Institne in Xinjiang Uygur Auto Nomous Reginon,Yining Xinjiang 835000);Immobilized Enzyme and Its Application in the Food Industry[J];Modern Agricultural Sciences and Technology;2010-19
3 Zou Ying,Xu Ting,Zhuang Yafeng(Department of Chemistry,School of Science,Changzhou Institute of Technology,Changzhou 213022,China);Sensing Technology for the Determination of Formaldehyde[J];Environmental Science and Management;2011-03
4 YANG Xiao-he,YANG Hao,PAN Min,CHEN Yu-quan(State Specialized Laboratory of Biomedical Sensors,Department of Biomedical Engineering,Zhejiang University,Hangzhou 310027,China);Glucose Biosensors Based on Screen-Printed Carbon Paste Electrodes Modified by Nano-SiO_2[J];Chinese Journal of Sensors and Actuators;2007-09
5 YANG Benhong~1,CAI Jingmin~(2*),WU Ke~2,PAN Renrui~2(1 Department of Chemical and Material Engineering,Hefei University,Hefei 230022,Anhui,China;2 Department of Biological and Environmental Engineering,Hefei University,Hefei 230022,Anhui,China);Preparation and Properties of Sodium Alginate-Immobilized Rhizopus delemar Lipase[J];Chinese Journal of Catalysis;2005-11
6 LIU Wenfang,HOU Benxiang,HOU Yanhui,ZHAO Zhiping * School of Chemical Engineering and Environment,Beijing Institute of Technology,Beijing 100081,China;Synthesis of Formic Acid from CO_2 Catalyzed by Formate Dehydrogenase Immobilized on Hollow Fiber Membrane[J];Chinese Journal of Catalysis;2012-04
7 WANG Chao,CHEN Da,LIU Shu,HUANG Yuexiang,FAN Meiqiang,SHU Kangying(College of Materials Science and Engineering,China Jiliang University,Hangzhou 310018);Recent Progress in Photocatalytic Reduction of Carbon Dioxide Utilizing Titania Catalysts[J];Materials Review;2011-07
8 MA Zhongcheng,WANG Lan(State Key Laboratory of Green Building Materials,China Building Materials Academy,Beijing 100024);Technical Progress of Emission-reduction and Utilization of Carbon Dioxide in Cement Industry[J];Materials Review;2011-19
9 Huang Zhixin (School of Environment and Resource,Fuzhou University,Fujian,350002);Properties of Immobilization of Laccase by Sol-gel[J];Chemical Engineering & Equipment;2008-11
10 QIU Ling-feng,HUANG Zhi-xin(College of Environment and Resources,Fuzhou University,Fuzhou,Fujian 350002,China);Chlorophenols treatment with immobilization of laccase by Sol-gel[J];Journal of Fuzhou University(Natural Science Edition);2008-06
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved