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《Chinese Journal of Catalysis》 2002-04
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Study on Reaction Kinetics of COS Hydrolysis at Lower Temperature

LIANG Meisheng 1,2*, LI Chunhu 1, GUO Hanxian 1, XIE Kechang 1 (1 State Key Laboratory of C1 Chemistry and Technology, Research Institute for Chemical Engineering of Coal; 2 College of Architecture and Environmental Engineering, Taiyuan University  
A microreactor-GC apparatus was used for studying the reaction kinetics of COS hydrolysis over TGH catalyst. The COS hydrolysis in lower temperature range (50~70 ℃) and higher H 2O/COS molar ratio range (60~550) was investigated. By fitting different objective functions with nonlinear Marquart computer program to the data obtained under the experimental conditions, the optimal reaction rate expression for COS hydrolysis was gained as follows r(COS)=-dXd(W/f(COS))=1.82·10 14 p(COS) p -0.5(H 2O)exp- 75?8008.374T. The model was tested by mathematical statistic method and residual distribution. The results showed that the kinetic model can reasonably describe the characteristics of COS hydrolysis over TGH catalyst. The reaction mechanism was also discussed. The reaction rate of COS hydrolysis was significantly inhibited by the higher H 2O/COS molar ratio.
【CateGory Index】: O643.3
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【References】
Chinese Journal Full-text Database 8 Hits
1 WANG Huina,SHANGGUAN Jü,WANG Xiaopeng,ZHU Yongjun (Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province,Institute of Coal and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China);Advances in catalytic hydrolysis of carbonyl sulfide[J];Industrial Catalysis;2007-02
2 FANG Lei1,ZHANG Yong-chun1,ZHOU Jin-xia1,DING Wei2(1.State Key Laboratory of Fine Chemical,Dalian University of Technology,Dalian 116012,China;(2.Academy of Dalian University of Technology,Liaohe Petroleum Exploration Bureau,Dalian 124010,China);The Development of Removal Low Concentration COS From Industrial Exhaust Gas[J];Low Temperature and Specialty Gases;2007-04
3 FANG Lei1,ZHANG Yong-chun1,ZHOU Jin-xia1,DING Wei2(1.State Key Laboratory of Fine Chemical,Dilian University of Technology,Dalian 116012,China 2.Academy of Dilian University of Technology,Liaohe Peroleum Exploration Bureau 124010,China);Development of the Research in Removal of Low Concentration of COS from Industrial Exhaust Gas[J];Guangzhou Chemistry;2008-01
4 Zhang Kongyuan, Yu Changchun, Dai Xiaoping ( University of Petroleum (East China),Donying 257061; Research Institute of Qilu Branch Co. , SINOPEC; University of Petroleum (Beijing));KINETIC STUDY OF LS-951 HYDROGENATION CATALYST FOR TREATING TAIL GAS FROM CLAUS PROCESS[J];Petroleum Processing and Petrochemicals;2006-01
5 LIANG Li-tong, SHANG GUAN Ju, LI Chun-hu (Research Institute for Chemical Engineering of Coal, Taiyuan University of Technology, Taiyuan 030024, China);Research Progress of Carbonyl Sulfide Hydrolysis Technology[J];Natural Gas Chemical Industry (C1 Chemistry and Technology );2005-01
6 LIANG Meisheng1,2, LI Chunhu1, GUO Hanxian1, XIE Kechang1, CHU Jianglin3eering of Coal, Taiyuan030024, China; 2Architectural and Environmental Engineering College, Taiyuan University of Technology, Taiyuan030024, China; 3 Jinling Institute of Technology, Nanjin210001, China);STUDY OF COS HYDROLYSIS REACTION KINETICS AT LOWER TEMPERATURE AND IN THE PRESENCE OF CO_2[J];Journal of Fuel Chemistry and Technology;2003-02
7 GAO Zhihua, YIN Lihua, LI Chunhu, XIE Kechangof Education, Institue of Coal Chemical Engineering, Taiyuan University of Technology, Taiyuan030024, China);STUDY ON SIMULTANEOUS REMOVAL OF COS AND H_2S BY USING α-FeOOH NANOPARTICLE[J];Journal of Fuel Chemistry and Technology;2003-03
8 HAO Chang-qing, ZHANG De-xiang, WU Ting-ting(Department of Chemical Engineering for Energy Resources and Key Laboratory of Coal Gasification of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China);Status and Prospect of Research on Removal of COS from Gas[J];Shandong Metallurgy;2009-01
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Zhang Qin-lin and Guo Han-xian (Research Institute of Coal Chemical Engineering, Taiyuan University of Technology);KINETICS OF THE HYDROLYSIS OF CARBONYL SULFIDE OVER γ-Al_2O_3 CATALYST AT LOWER TEMPERATURE[J];Chinese Journal of Catalysis;1988-01
【Co-citations】
Chinese Journal Full-text Database 9 Hits
1 WANG Huina,SHANGGUAN Jü,WANG Xiaopeng,ZHU Yongjun (Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province,Institute of Coal and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China);Advances in catalytic hydrolysis of carbonyl sulfide[J];Industrial Catalysis;2007-02
2 Zhang Qing-lin and Guo Han-xian (Research Institute of Coal Chemical Engineering, Taiyuan University of Technology);THE CHARACTERISTIC AND MECHANISM OF DEACTIVATION OF CARBONYL SULFIDE HYDROLYSIS CATALYST[J];Chinese Journal of Catalysis;1988-02
3 Li Chunhu;Guo Hanxian;Tan Shishao(Research Institute of Coal Chemical Engineering,Taiyuan University of Taiyuan 030024);Study on the Alkalized γ-Al_2O_3 Catalyst for its Base Strength Distribution and Catalytic Activity[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1994-04
4 Li Jianwei;Li Chengyue(Dept Chem Eng,Beijing Univ Chem Technol Beijing,100029)Liu Jindun;Fang Wenji(Dept Chem Eng,Zhengzhou Inst Technol Zhengzhou,450002);Study on COS Hydrolysis Kinetics on Y-906 Catalyst in Reducing Atmosphere[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);1996-02
5 Tan, Shi-shao;Li, Chun-hu;Guo, Han-xian;Shi, Jian-ping and Yang, Xing-min (Research Institute of Coal Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024);CARBONYL SULFIDE HYDROLYSIS ON ALKALIZED Y-A_2O_3 CATALYST AT LOWER TEMPERATURE Ⅰ.CATALYST ACTIVITY AND COMPENSATION EFFECT[J];Chinese Journal of Catalysis;1993-03
6 ZHOU Guang-lin,FU Yuan-sheng,ZHOU Hong-jun (Research Institute of Qilu Petrochemical Corp.,Zibo Shangdong 255400,China);Deactivation and Regeneration of Ambient Temperature COS Hydrolysis Catalyst[J];Petrochemical Technology;2001-08
7 LIANG Li-tong, SHANG GUAN Ju, LI Chun-hu (Research Institute for Chemical Engineering of Coal, Taiyuan University of Technology, Taiyuan 030024, China);Research Progress of Carbonyl Sulfide Hydrolysis Technology[J];Natural Gas Chemical Industry (C1 Chemistry and Technology );2005-01
8 Shangguan Ju Guo Hanxian (Research Institute of Chemical Engnieering for Coal, Taiyuan University of Technology, Taiyuan);STUDY ON HYDROLYSIS REACTIVITY OF CARBON DISULFIDE OVER ALUMINA CATALYSTS[J];JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY;1997-03
9 LIANG Meisheng1,2, LI Chunhu1, GUO Hanxian1, XIE Kechang1, CHU Jianglin3eering of Coal, Taiyuan030024, China; 2Architectural and Environmental Engineering College, Taiyuan University of Technology, Taiyuan030024, China; 3 Jinling Institute of Technology, Nanjin210001, China);STUDY OF COS HYDROLYSIS REACTION KINETICS AT LOWER TEMPERATURE AND IN THE PRESENCE OF CO_2[J];Journal of Fuel Chemistry and Technology;2003-02
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 LI Kaixi 1, LING Licheng 2, LIU Lang 1, ZHANG Bijiang 1, LIU Zhenyu 2 (1 Institute of Coal Chemistry; 2 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, The Chinese Academy of Sciences, Taiyuan 030001, China);Desulfurization Activity of Activated Carbon Fiber Modified by Heat Treatment[J];CHINESE JOURNAL OF CATALYSIS;2000-03
2 LIU Shouxin 1,2 , SUN Chenglin 1* , ZHANG Shirun 2 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Northeast Forestry University, Harbin 150040, Heilongjiang, China);Photocatalytic Regeneration of Coal-Based Activated Carbon[J];Chinese Journal of Catalysis;2003-05
3 GUO Han-xian(Res Inst Coal Chem Eng, Taiyuan Univ Technol, Taiyuan 030024, China)MIAO Mao-qian; ZHANG Yun-qiang(Shanxi CLEAN Company of Catalysis & Purification, Taiyuan 030024, China);Performance of TGH-3Q COS hydrolysis catalyst at ambient and low temperature[J];GONGYE CUIHUA (INDUSTRIAL CATALYSIS);1999-05
4 HU Xiao-min,LIU Hua-zhang (College of Chemical Engineering & Materials,Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China);Activated carbon fiber and its application in catalysis[J];Industrial Catalysis;2005-01
5 Xu Lina,Zhou Kaichang,Zhai Ya ,Zhang Xueyun,Ou Danlin Liu Chunping,Gu Ning,Zhang Haiqian,Liu Juzheng(Southeast University,Nanjing 210096,China);Quick Nickel Metallization and Magnetic Properties on the Surface of Alumina Powder[J];Rare Metal Materials and Engineering;2003-05
6 PEI Li-zhai 1,LIU Cui-juan 2 (1.College of Materials Science and Engineering Hunan University,Changsha 410082,China; 2.Guangzhou Zhonghui Electronics Ltd.,Guangzhou 510000,China);Progress of Application on Porous Silicon[J];Electro-optics & Passive Countermeasures;2004-04
7 Hua Jian;Yi Huaqiang;Liu Thongrhen;Chuan Yaquan;Lou Deming and Hu Yuyin(Chengdu University of Science and Technology,Chengdu);STUDY ON PITCH-BASED ACTIVED CARBON FIBERS──(Ⅱ) THE ASPECTS IN THE CARBONIZATION AND ACTIVATION OF PITCH FIBERS[J];POLYMERIC MATERIALS SCIENCE & CNGINEERING;1995-03
8 Liu Shouxin; Wang Yan(NorthCast Forestry University. Harbin 150040. P. R. China); Zheng Wenchao(Zoological Garden of Harbin);Progress in Activated Carbon Regeneration[J];Journal of Northeast Forestry University;2001-03
9 WU Zhi-hong (Department of Chemistry and Biology, Guangxi Hechi College, Guangxi Yizhou 546300, China);Preparation of nanoparticle alumina and its application in catalysis[J];Industrial Catalysis;2004-02
10 SUN Fu-nan,FENG Qing-xiang ,WU Jiang-hong (Guangming Research & Design Institute of Chemical Industry,Dalian 116031,China);The Production of High Purity Carbonyl Oxysulfide[J];Low Temperature and Specialty Gases;2004-03
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 SHAO Chun-hong , JIANG An-xi ,YAN Bo ,LI Fen, ZHOU Bai-bin ( School of Municipal and Environment Engineering, Harbin Institute of Technology, Harbin 150090,China, E-mail; 2004hongcs@ 126. com; School of Physics and Chemistry, Harbin Normal University, Harbin 150080, China);Research on the process condition of low temperature desulfur of nanocrystalline ZnO[J];Material Science and Technology;2005-04
2 FAN Jian1,LEI Jun2(1.Shanxi Jinfeng Coal Chemical Co.Ltd.,Jincheng 048400,China;2.Hubei Research Institute of Chemistry,Wuhan 430074,China);Technique Development of COS Removal[J];Anhui Chemical Industry;2007-04
3 WANG Huina,SHANGGUAN Jü,WANG Xiaopeng,ZHU Yongjun (Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province,Institute of Coal and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,Shanxi,China);Advances in catalytic hydrolysis of carbonyl sulfide[J];Industrial Catalysis;2007-02
4 LI Xiuping,LI Chunhu,YANG lin,WANG Linxue (Key Laboratory of Marine Chemistry Theory and Technologyof Ministry of Education,Ocean University of China,Qingdao 266003,Shandong,China);Homogenous catalytic hydrolysis of high-concentration COS in CO atmosphere[J];Industrial Catalysis;2007-03
5 FANG Lei1,ZHANG Yong-chun1,ZHOU Jin-xia1,DING Wei2(1.State Key Laboratory of Fine Chemical,Dalian University of Technology,Dalian 116012,China;(2.Academy of Dalian University of Technology,Liaohe Petroleum Exploration Bureau,Dalian 124010,China);The Development of Removal Low Concentration COS From Industrial Exhaust Gas[J];Low Temperature and Specialty Gases;2007-04
6 FANG Lei1,ZHANG Yong-chun1,ZHOU Jin-xia1,DING Wei2(1.State Key Laboratory of Fine Chemical,Dilian University of Technology,Dalian 116012,China 2.Academy of Dilian University of Technology,Liaohe Peroleum Exploration Bureau 124010,China);Development of the Research in Removal of Low Concentration of COS from Industrial Exhaust Gas[J];Guangzhou Chemistry;2008-01
7 FANG Lei1,ZHANG Yong-chun1,ZHOU Jin-xia1,DING Wei2(1.State Key Laboratory of Fine Chemical,Dilian University of Technology,Dalian 116012,China)(2.Academy of Dilian University of Technology,Liaohe Petroleum Exploration Bureau 124010,China);Simultaneous Removing COS and H2S by Using Activated Carbon Fibre in Feedstock of Carbon Dioxide[J];Guangzhou Chemistry;2008-02
8 Zhang Kongyuan, Yu Changchun, Dai Xiaoping ( University of Petroleum (East China),Donying 257061; Research Institute of Qilu Branch Co. , SINOPEC; University of Petroleum (Beijing));KINETIC STUDY OF LS-951 HYDROGENATION CATALYST FOR TREATING TAIL GAS FROM CLAUS PROCESS[J];Petroleum Processing and Petrochemicals;2006-01
9 ZHAO Hai, ZHANG De-xiang, WANG Fang-fang, WU Ting-ting, GAO Jin-sheng(Department of Chemical Engineering for Energy Resources, East China University of Science and Technology, Key Laboratory of Coal Gasification of Ministry of Education, Shanghai 200237, China);Effect of CeO_2 doping on desulfurization performance of iron-manganese composite oxide in COS removal[J];Journal of Fuel Chemistry and Technology;2008-02
10 ZHANG Hai-ying1,WANG Xu-zhen1,2,ZHENG Jun1,ZHAO Zong-bin2(1.Department of Chemistry,School of Chemical Engineering,Dalian University of Technology,Dalian 116023,China;2.Carbon Research Laboratory,State Key Lab of Fine Chemicals,School of Chemical Engineering,Dalian University of Technology,Dalian 116012,China);Research progress of hydrodesulfurization of carbonyl sulfide in hot coal gas[J];Applied Chemical Industry;2008-08
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