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《Chinese Journal of Catalysis》 2002-05
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Preparation and Catalytic Activity of SBA-15 Mesoporous Silica Functionalized with Sulfonic Acid Groups

YUAN Xingdong 1,2*, SHEN Jian 1, LI Guohui 2, Ji-Man KIM 3, Sang-Eon PARK 3 (1 Department of Petrochemical Technology, Fushun Petroleum Institute, Fushun 113001, Liaoning, China; 2 Institute of Coal Chemistry, The Chinese Academy of Sciences, Tai  
The well-ordered SBA-15 mesoporous silica material containing alkyl sulfonic acid group was prepared by post-synthetic grafting of (3-mercaptopropyl)trimethoxysilane (MPTMS) to the surface of SBA-15 synthesized under strong acidic conditions. X-ray diffraction patterns revealed that the crystallinity of SBA-15-SH and SBA-15-SO 3H does not change as compared with SBA-15. 13C and 29Si MAS NMR results showed that MPTMS is grafted onto the surface of the pore wall of SBA-15. IR spectra indicated that sulfonic acid groups are the surface strong Br*insted acid sites, which are efficient catalysts for the esterification of methanol with oleic acid. High conversion of oleic acid was obtained in a shorter time over SBA-15-SO 3H than that over zeolite catalysts such as HUSY and Hβ. SBA-15-SO 3H has higher catalytic activity than sulfuric acid with the same number of acid sites, and maybe has higher acid strength than sulfuric acid. The catalyst retains highly ordered structure in the esterification reaction, which suggests that this catalyst has good hydrothermal stability.
【CateGory Index】: O643.3
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【References】
Chinese Journal Full-text Database 10 Hits
1 YUAN Xingdong 1,2*, SHEN Jian 1, LI Guohui 2, ZHOU Jinglai 2, Ji-Man KIM 3, Sang-Eon PARK 3(1 Department of Petrochemical Technology, Fushun Petroleum Institute, Fushun 113001, Liaoning, China; 2 Institute of Coal Chemistry, The Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China; 3 Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), PO Box 107, Taejon 305-600, Korea);Direct Synthesis of SBA-15 Mesoporous Silica Functionalized with Sulfonic Acid Groups[J];Chinese Journal of Catalysis;2003-02
2 HAN Yu, XIAO Feng-Shou * (State Key Laboratory of Inorganic Synthesis and Preparative Chemistry and Department of Chemistry, Jilin University, Changchun 130023, Jilin, China);Catalytically Active and Hydrothermally Stable Mesoporous Materials Assembled from Preformed Nanosized Zeolite Precursors[J];Chinese Journal of Catalysis;2003-02
3 HUANG Yanlei1, CHEN Yangying2, LIU Xiumei2, ZHOU Danhong 1*, FAN Yinheng1 (1 College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Synthesis and Sulfonation of Phenyl-Modified SBA-15 Mesoporous Molecular Sieve[J];Chinese Journal of Catalysis;2004-05
4 ZHANG Li,YUAN Xing-dong*,QI Yu-tai, SUN Ming-zhu (Petrochemical Engineering Faculty, Liaoning University of Petroleum & Chemical Technology, Liaoning Fushun 113001,China);Catalytic Synthesis of Ethyl Acetate by Mesoporous Sieve SBA-15-SO_3H Containing Sulfonic Acid Group[J];Journal of Fushun Petroleum Institute;2003-02
5 YAN Jina, LI Liang, HUA Zile, CHEN Hangrong, RUAN Meiling, LI Lei, SHI Jianlin (State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China);STRUCTURAL AND HYDROGEN TEMPERATURE PROGRAMMED REDUCTION PROPERTIES OF MCM-41 SUPPORTED COPPER OXIDE CATALYSTS[J];Journal of The Chinese Ceramic Society;2005-04
6 WANG Birong YUAN Dong YUAN Jigang(School of Material and Chemical Engineering,Sichuan University of Science & Engineering Zigong,Sichuan 643000);Study on Ammonia Nitrogen Treatment in Wastewater by SBA-15 Mesoporous Molecular Sieve[J];Industrial Safety and Environmental Protection;2012-04
7 ZHANG Wei1,2,XU Hengyong2,BI Yadong 2,LI Wenzhao2(1 Department of Chemistry,Harbin Normal University,Harbin 150025,Heilongjiang,China;2 Laboratory of Applied Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China);Recent progress of modification of mesoporous silica SBA-15[J];Chemical Industry and Engineering Progress;2007-02
8 ZHAO Xin1,SHEN Jian1,LIU Dianzhao2,ZHOU Peng2(1 Liaoning University of Petroleum and Chemical Technology,Fushun 113001,Liaoning,China;2 Daqing Oilfield Construction Group,Daqing 163712,Heilongjiang,China);Synthesis of 2-t-butyl-p-cresol over supported SBA-15-SO_3H catalyst[J];Chemical Industry and Engineering Progress;2008-03
9 HUANG Yong1,CHEN Weiqing2,SHI Qiujie1,SUN Wuchen1 (1Institute of Applied Chemistry,Nanchang University,2 College of Materials Science and Engineering,Nanchang University,Nanchang 330031,Jiangxi,China);Application of mesoporous molecular sieves SBA-15 in catalysis[J];Chemical Industry and Engineering Progress;2009-12
10 YUAN Xingdong and SHEN Jian(School of Petrochemical Technology, Liaoning University of Petroleum & Chemical Technology, Fushun 113001, Liaoning,China)KIM Ji Man(Functional Materials Laboratory, Department of Molecular Science & Technology,Ajou University, Suwon 442-749, Korea);BASE MODIFIED PERIODIC MESOPOROUS ORGANOSILICA AND CATALYTIC PROPERTY[J];Journal of Chemical Industry and Engineering(China);2004-10
【Citations】
Chinese Journal Full-text Database 1 Hits
1 SUN Jin-Yu, ZHAO Dong-Yuan* (Department of Chemistry, Fudan University, Shanghai 200433, China);Synthesis of Highly Ordered Donut-like Mesoporous Silica SBA-15[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 WANG Wei, ZHAO Ruixue, CHEN Minggui, HU Weihua , GUAN Xin, J1ANG Tiansu , ZHAI Qingzhou (Research Center for Nanotechnology, Changchun University of Science and Technology, Changchun 130022, China);Some Development of Studies on Molecular Sieves During Recent Years[J];Journal of Changchun Institute of Optics and Fine Mechanics;2003-01
2 Zhao Li, Yu Jiaguo, Zhao Xiujian, Cheng Bei, Zhang Xiequn, Guo Rui (Wuhan University of Technology, Wuhan 430070, China);Research and Development of Mesoporous Nanostructured Materials[J];Rare Metal Materials and Engineering;2004-01
3 Yuan Jinfang1,2,Li Jiansheng1,Shen Zhanhui1,Gu Juan1,Li Huijun1,Sun Xiuyun1,Wang Lianjun1(1.Nanjing University of Science and Technology,Nanjing 210094,China)(2.Henan University,Kaifeng 475001,China);Synthesis and Morphological Control of Zr-Ce-SBA-15 Mesoporous Materials[J];Rare Metal Materials and Engineering;2011-03
4 YI Nan, LIU Yong-mei, FENG Wei-liang, CAO Yong, DAI Wei-lin, FAN Kang-nianlecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433,China);Highly Selective Oxidative Dehydrogenation of Propane to Propylene over New Type of Mesoporous Vanadia Catalysts[J];Journal of Fudan University;2004-04
5 ZHANG Li,YUAN Xing-dong*,QI Yu-tai, SUN Ming-zhu (Petrochemical Engineering Faculty, Liaoning University of Petroleum & Chemical Technology, Liaoning Fushun 113001,China);Catalytic Synthesis of Ethyl Acetate by Mesoporous Sieve SBA-15-SO_3H Containing Sulfonic Acid Group[J];Journal of Fushun Petroleum Institute;2003-02
6 Li Dongyu,He Yong,Wang Kai(Xinjiang Academy of Safety and Technology,Urumqi 83002,China);Methods of Modulating Pore Size of SBA-15[J];Guangdong Chemical Industry;2011-06
7 ZHANG Xue Zheng, YUE Ying Hong, GAO Zi * (Department of Chemistry, Fudan University, Shanghai 200433, China);Studies on 12-Tungstophosphoric Heteropolyacid Supported SBA-15 Catalysts[J];Chemical Research In Chinese Universities;2001-07
8 FAN Jie, YU Cheng Zhong, TU Bo, ZHAO Dong Yuan *(Department of Chemistry, Fudan University, Shanghai 200433, China);Sponge-like Architectured Macroporous Oxides Templating by Egg White[J];Chemical Research In Chinese Universities;2001-09
9 LI Gong 1, KAN Qiu Bin 1* , WU Tong Hao 1, HOU Chang Min 1, HUANG Jia Hui 1, WU Shu Jie 1, LI Can 2(1. College of Chemistry, Jilin University, Changchun, 130023, China; 2. State Key Laboratory of Catalysis, Dalian Institute of Chmical;Synthesis and Catalytic Performances of Mesoporous Aluminosilicates of Cubic and Hexagonal Structure with Stronger Acid Sites[J];Chemical Research In Chinese Universities;2002-06
10 GAO Feng, ZHAO Jian Wei, ZHANG Song, ZHOU Feng, JIN Wan, ZHANG Xiang Min, YANG Peng Yuan *, ZHAO Dong Yuan (Department of Chemistry, Fudan University, Shanghai 200433, China);Application of C_(18)-Modified Mseoporous SBA-15 as the Substrate for High Performance Liquid Chromatography[J];Chemical Research In Chinese Universities;2002-08
China Proceedings of conference Full-text Database 1 Hits
1 LIU Yu-ping WANG Jin-gui ZHOU Hui-jing CHEN Tie-hong YUAN Zhong-yong (College of Chemistry,Nankai University,Tianjin 300071,China);INFLUENCE OF Sn~(2+) IONS ON THE MORPHOLOGY AND PROPERTIES OF MESOPOROUS SBA-15[A];[C];2008
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 LIU Zhen-dong, YUAN Di-qiang (Departmet of Material Engineering, Beijing Institute of Clothing technology, Beijing 100029, China);An Esterification Reaction Catalyzed by β-zeolite[J];Journal of Beijing Institute of Clothing;2003-01
2 CAO Hong-yuan CAO Wei-liang ZHANG Jing-chang(College of Science,Beijing University of Chemical Technology,Beijing 100029,China);Preparation of biodiesel with soybean oil through solid acid catalyst Zr(SO_4)_2·4H_2O[J];Journal of Beijing University of Chemical Technology;2005-06
3 YANG Shuijin, LIANG Yongguang, DONG Jiinghua, SUN Jutang, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China;Synthesis of Propionates by using TiSiW12O40/TiO2 as Catalyst[J];Journal of University of Science and Technology Beijing;2003-04
4 ZHAO Li fang 1, HE Zhu sheng 1, MA Yu ying 2 (1.Dept.Chem.& Chem.Engn.;2.Attached Middle School, Baoji Coll. Arts & Sci.,Baoji 721007,Shaanxi,China);Catalytic synthesis of dimethyl fumarate using solid-supported catalyst[J];Journal of Baoji College of Arts and Science(Natural Science Edition);2002-02
5 LIU Jian, YE Qiao?ming, PENG Hai?dong (Chengdu Institute of Technology, Sichuan Chengdu 610059, China);Research and Development of Fe-Rich Slag Glass-Ceramic[J];Glass & Enamel;2001-06
6 Liu Xiaobo Fu Yongjian Xiao Qiuguo(Xiangtan Mining Institute);Research on Chemical Stablility of Nepheline Glass-Ceramics of Na_2O-Al_2O_3-SiO_2 System[J];GLASS & ENAMEL;1998-02
7 Cui Lin,Liu Jianguo,Xu Xinxiang (The Department of Orthopedics of the First Clinical College of Normen Bethune University of Medical Sciences);Experimental study of repairing articular cartilage defect using porous biodegradable PCL[J];JOURNAL OF NORMAN BETHUNE UNIVERSITY OF MEDICAL SCIENCE;1999-05
8 LIANG Liu yan, WANG Ping (College of Chemical Engineering, Beijing Technology and Business University, Beijing 100037, China);STUDY ON METHOD OF NITROGEN REMOVAL FROM WASTEWATER[J];Journal of Beijing Institute of Light Indusry;2001-01
9 WANG Qi,TIAN Yuan,MA Kun-lun,LIU Xiao-lan(College of Chemical and Environmental Engineering,Beijing Technology and Business University,Beijing 100048,China);ABILITY OF COMPOSITE MOLECULAR SIEVE TO REMOVE NH_3-N FROM WATER[J];Journal of Beijing Technology and Business University(Natural Science Edition);2010-05
10 XU Jing Shi, ZHOU Guo Bin, WANG Hong Ming, CHEN Hui Zong (Institute of Chemistry and Biology Sciences,Jiangxi Normal University,Nanchang 330027,China);Study on Synthesis of Hydroxybenzoic Esters with TiO_2/SO_4~(2-) Solid Acids Zeolites as Catalyst[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2002-01
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Lili Cui1),Huili Fan1),Junping Xiao1),Xiaowei Xu2),and Dong Su3) 1) Applied Science School,University of Science and Technology Beijing,Beijing 100083,China 2) Materials Science and Engineering School,University of Science and Technology Beijing,Beijing 100083,China 3) Civil & Environment Engineering School,University of Science and Technology Beijing,Beijing 100083,China;Surface modification of up-conversion luminescence material Na[Y_(0.57)Yb_(0.39)Er_(0.04)]F_4 with hydrosulfide group[J];北京科技大学学报(英文版);2008-05
2 Huang Chao Guo Zhiwu Jin Haibo Yang Suohe(Department of Chemical Engineering,Beijing Institute of Petro-chemical Technology,Beijing 102617);Study on the Synthesis of Butyl Lactate Catalyzed by Modified Bentonite[J];Journal of Beijing Institute of Petro-Chemical Technology;2007-04
3 JIANG Hui-liang,GUO Hong-zhen,ZENG Hong-zhou (School of Chemical and Material Engineering,Southern Yangtze University,Wuxi 214122,China);Continuous synthesis of methyl oleate and its kinetics[J];China Surfactant Detergent & Cosmetics;2007-04
4 ZHAO Yong-jie~1,QU Ji-fang~2 (1.China Research Institute of Daily Chemical Industry,Taiyuan,Shanxi 030001,China; 2.School of Chemistry & Chemical Engineering,Shanxi University,Taiyuan,Shanxi 030006,China);Preparation of MCM-41 molecular sieve with PEG/CTAB as template agent[J];China Surfactant Detergent & Cosmetics;2010-06
5 REN Yu, QIAN Linping, YUE Bin *, HE Heyong *(Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, China);Synthesis of Ti-Containing Silica Mesoporous Molecular Sieves with High Catalytic Activity for Epoxidation[J];Chinese Journal of Catalysis;2003-12
6 LIU Yunqi *, LI Wangliang, LIU Chunying, CUI Min, LIU Chenguang(CNPC Key Laboratory of Catalysis, College of Chemistry and Chemical Engineering, University of Petroleum (East China), Dongying 257061, Shandong, China);Hydrogenation of Naphthalene on HY/MCM-41/γ-Al_2O_3- Supported Sulfided Ni-Mo-P Catalyst[J];Chinese Journal of Catalysis;2004-07
7 CHEN Honglin, SHEN Baojian *, PAN Huifang(State Key Laboratory of Heavy Oil Processing, The Key Laboratory of Catalysis of CNPC, Faculty of Chemical Engineering, University of Petroleum, Beijing 102249, China);Acidity and Catalytic Performance of ZSM-5/Y Composite Zeolite for Heavy Oil Cracking[J];Chinese Journal of Catalysis;2004-09
8 ZHU Jinhong 1, LIU Jing 1* , ZHAO Wenjiang 1, WANG Xiangsheng 1, LIU Xiumei 2, BAO Xinhe 2(1 State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China);Synthesis and Characterization of Al-MSU-S Mesoporous and Meso-Microporous Molecular Sieves and Their Catalytic Performance[J];Chinese Journal of Catalysis;2004-09
9 LI Liang, SHI Jianlin *(State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, The Chinese Academy of Sciences, Shanghai 200050, China);Application of Mesoporous and Mesoporous Host-Guest Materials in the Field of Catalysis[J];Chinese Journal of Catalysis;2005-02
10 CHEN Jing1,HAN Mei1,2,LI Guiyun1,WANG Jintang1(1 Department of Applied Chemistry,School of Science,Nanjing University of Technology,Nanjing 210009,Jiangsu,China;2 School of Chemistry and Bioengineering,Chongqing University of Science and Technology,Chongqing 400050,China);Surface Modification of MCM-41 Molecular Sieve and Its Catalytic Performance for Synthesis of Iso-amyl Acetate[J];Chinese Journal of Catalysis;2007-10
China Proceedings of conference Full-text Database 4 Hits
1 SHANG Huijian,ZHANG Shaohong,ZHAO Dan,ZHOU Yanli,ZHAO Yan,ZHANG Gao,ZHENG Xueming(Hebei Scientific and Technical University,Chemical and Pharmaceutical Engineering Institute,shijiazhuang 050018,Hebei,China);Research progress of molecular sieve catalyst[A];[C];2011
2 XIA Housheng, TONG Dongshen, ZHOU Chunhui*, JIANG Genfeng, ZHANG Di(College of Chemical Engineering and Materials Science, Zhejiang University of Technology, ZJUT Renheng R&D Center For Clay-based Materials, Hangzhou 310032, Zhejiang,China);Preparation and application of functionalized periodic mesoporous organosilicas catalysts[A];[C];2008
3 LIU Fang , JIN Haibo, LUO Shijie , SUN Jihong ( College of Energy Environmental & Engineering, Beijing University of Technology, Beijing 100022, China; Department of Chemical Engineering , Beijing Institute of Petrochemical Technology . Beijing 102617, China);THE EFFECT OF ALUMINIUM SOURCE ON THE PHYSICO-CHEMICAL PROPERTIES OF BIMODAL MESOPOROUS MOLECULAR SIEVE[A];[C];2006
4 Yu Kang lunjia Xie* Yanqiang Wang Siyuan Zhao Yu Tian Beijing Research Insititute of Chemical Industry, SINOPEC,Beijing 100013, China;The synthesis and esterification of the catalyst large pore size SBA-15 loading zinc trifluoromethanesulfonate[A];[C];2010
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