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《Chinese Journal of Catalysis》 2002-05
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Highly Efficient Synthesis of Zeolite MCM-22 under Static Hydrothermal Crystallization Conditions

LIU Zhongqing *, WANG Yimeng, FU Jun, HE Mingyuan(Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China)  
Zeolite MCM-22 has been synthesized under static hydrothermal crystallization conditions using silica gel, sodium aluminate and hexamethyleneimine (HMI). The typical crystallization conditions are HMI/SiO 2 molar ratio of 0.09~0.2, H 2O/SiO 2 molar ratio of 12~20 and crystallization time of 60~80 h. The template to silica ratio and water to silica ratio are much lower than those in the literature. The utilization of silica gel with high surface area (486 m 2/g) and high activity as the silica source is the key to the highly efficient synthesis of MCM-22, while the aging step during the preparation of gel is not closely related to the synthesis. The investigation of the crystallization conditions indicates that the product obtained and its trans-crystallization depend on the SiO 2/Al 2O 3 ratio of the gel system. When the SiO 2/Al 2O 3 ratio equals to 18~80, the product is MCM-22, which may be trans-crystallized into ZSM-5 at a higher SiO 2/Al 2O 3 ratio such as 50 and into MOR at a lower SiO 2/Al 2O 3 ratio such as 20; when the SiO 2/Al 2O 3 ratio equals to 13~17, MCM-49 is produced.
【Fund】: 国家重大基础研究规划项目 (G2 0 0 0 480 0 0 1)
【CateGory Index】: TQ426
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