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《Chinese Journal of Catalysis》 2003-07
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Catalytic Degradation of N-Nitrosopyrrolidine over Fe_2O_3-Modified NaY Zeolite

LIU Huadao, CAO Yi, ZHU Jianhua *, MA Lili (College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China)  
Recently more attention has been paid to the degradation of N-nitrosopyrrolidine (NPYR) that exists in cigarette smoke and is a threat to human health. Zeolites were used to degrade NPYR, but their catalytic activity needs to be enhanced. In this paper, the preparation and evaluation of the Fe 2O 3-modified NaY zeolite catalyst for the degradation of nitrosamines with high activity were reported. The catalyst samples were prepared by impregnation, microwave radiation, and calcination methods, characterized by XRD, NH 3-TPD and TG-MS techniques, and used in the temperature-programmed surface reaction (TPSR) and pulse reaction. Fe 2O 3 was dispersed more completely on the catalyst prepared by impregnation than that by microwave irradiation or by direct calcination. As a result, Fe 2O 3/NaY obtained by impregnating NaY with Fe(NO 3) 3 solution showed the highest activity for the degradation of NPYR. NO x was detected at 443 K in the TPSR process, representing the decomposition of NPYR, and reached the maximum amount at 533 K and the adsorption of product NO 2 on the sample was found to be weakened at the same time. The experiment of TG-MS revealed that the temperature of NO desorption on the impregnated sample decreased in comparison to the NaY zeolite. In the pulse reaction the Fe 2O 3/NaY catalyst showed high activity at 553 and 673 K, which may be related with the oxidation capability of Fe 2O 3 at high temperature. XPS results indicated that the Fe component in the catalyst can migrate from the inner surface to the external surface of NaY during the degradation of NPYR, covering the Al component on the catalyst surface and making the catalyst to exhibit characteristics of Fe 2O 3 in the reaction.
【Fund】: 国家自然科学基金 (2 0 2 730 31);; 南京大学分析中心资助项目
【CateGory Index】: O643.3
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