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《Chinese Journal of Catalysis》 2003-10
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Catalytic Performance of Pd/Al_2O_3 Catalyst Prepared by Glow Discharge Plasma Method for Selective Hydrogenation of Acetylene

CHEN Muhua, CHU Wei *, ZHANG Xiongwei(College of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China)  
The selective hydrogenation of acetylene to ethylene is an important process used to purify ethylene streams containing trace amount of acetylene for the production of polyethylene. Palladium based catalyst supported on α Al 2O 3 for selective hydrogenation of acetylene was prepared by glow discharge plasma. The effects of preparation methods, palladium content, promoter and reaction temperature on the catalytic performance of the catalyst were investigated. It was found that the performance of the catalyst samples prepared by plasma is superior to that of the samples prepared by conventional impregnation, and the preparation process via plasma method is simple, quick, and easy to be controlled. The catalyst was stable during the reaction for more than 20 h, and C 2H 2 conversion of 100% and C 2H 4 selectivity of 71 3% were obtained over the catalyst at 50 ℃ with a short induction period. As a new kind of amelioration technique, the treatment of glow discharge plasma enhanced effectively the adhesion and interaction between the metal and the support, then obtained a new active material with superior surface property and catalytic performance. The cerium oxide promoter can improve the catalyst performance, and the PVP modification can improve the catalyst stability.
【Fund】: 国家自然科学基金资助项目 (2 990 3 0 11);; 国家重点基础研究发展规划项目专题 (G19990 2 2 40 0 )
【CateGory Index】: O643.3
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