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《Chinese Journal of Catalysis》 2004-02
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The Effects of Composite Template System with Fluoride on the Acidity of Hβ Zeolite

QI Xiaolan 1, LI Shijie 1, LI Bin 1, LI Neng 1, LIU Xiyao 1,2*, LIN Bingxiong 1(1 Institute of Physical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China; 2 Research Institute of Yanshan Petrochemical Company, Beijing 102500, China)  
The effects of the composite template system with fluoride on the acidity of Hβ zeolite were investigated systematically by XRD, NH 3-TPD, FT-IR and MAS NMR methods and the probe reaction of methanol dehydration. The results showed that the acidity of Hβ zeolite was related to the synthesis conditions. The composite template system was in favor of the incorporation of Al into the framework of Hβ zeolite compared with the traditional template system (without fluoride). Furthermore, the total acid sites, especially strong acid sites, in Hβ zeolite synthesized using the composite template system were more than those in Hβ zeolite synthesized using the traditional template system owing to the change of aluminum configuration resulted from different crystallization mechanism of Hβ zeolite. The ratio of strong acid sites to weak acid sites in the former was markedly higher than that in the latter. The catalytic activity of the two Hβ samples for methanol dehydration was compared, and the results showed that their methanol conversion was 72.6% and 43.5%, respectively, under the conditions of WHSV=2 h -1, θ=180 ℃ and t=8 h.
【Fund】: 国家自然科学基金资助项目 ( 2 0 0 73 0 0 1)
【CateGory Index】: O643.3
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【References】
Chinese Journal Full-text Database 4 Hits
1 ZHANG Shengzhen1,2,CHEN Shengli1,DONG Peng1,JI Zhiyong1,Zhao Junying1,Xu Keqi1(1 State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China;2 Datang International Chemical Technology Research Institute,Datang International Power Generation Co.,Ltd.,Beijing 100070,China);Synthesis and Catalytic Hydroisomerization Performance of SAPO-11 Molecular Sieve with Small Crystals[J];Chinese Journal of Catalysis;2007-10
2 TONG Weiyi1,KONG Dejin1,2,3,LIU Zhicheng2,GUO Yanglong1,FANG Dingye3(1 Laboratory for Advanced Materials,Research Institute of Industrial Catalysis,East China University of Science and Technology,Shanghai 200237,China;2 Shanghai Research Institute of Petrochemical Technology,SINOPEC,Shanghai 201208,China;3 State Key Laboratory of Chemical Engineering,School of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China);Synthesis and Characterization of ZSM-5/Silicalite-1 Core-Shell Zeolite with a Fluoride-Containing Hydrothermal System[J];Chinese Journal of Catalysis;2008-12
3 CHEN Gang 1 , LI Shi-jie 2 , LI Bin 2 , HUANG Xiao-wei 1 , QI Xiao-lan 2 , LIU Xi-yao 2 (1. Research Institute of Yanshan Petrochemical Company, Beijing 102500, China; 2. Institute of Physical Chemistry, Peking University, Beijing 100871, China);Alkylation of Toluene-Propylene over Zeolite[J];Journal of Molecular Catalysis;2006-02
4 GONG Yan-Jun LI Qiang DOU Tao ZHAO Zhen XU Qing-Hu(China National Petroleum Corporation,Key Laboratory of Catalysis,China University of Petroleum,Beijing 102249,P.R.China);Direct Synthesis and Characteristics of NH_4-β Zeolite with Hierarchical Pore Structure[J];Acta Physico-Chimica Sinica;2009-03
【Citations】
Chinese Journal Full-text Database 7 Hits
1 Xie Zaiku 1, Chen Qingling 2, Zhang Chengfang 1, Bao Jiaqing 2, Cao Yuhua 2, Yang Yiqing 2(1 Institute of Chemical Technology, East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical;Study on the Surface Acid Properties of Hβ Zeolite[J];CHINESE JOURNAL OF CATALYSIS;2000-01
2 QI Xiaolan 1, LIU Xiyao 1, LIN Bingxiong 2(1 Research Institute of Yanshan Petrochemical Company, Beijing 102500, China; 2 Institute of Physical Chemistry, Peking University, Beijing 100871, China);Synthesis of β Zeolite Using TEABr Fluoride as Composite Template Ⅰ. Stability Phase Area on Thermodynamics of Crystallization[J];CHINESE JOURNAL OF CATALYSIS;2000-01
3 QI Xiao Lan, LIU Xi Yao *, CHEN Gang, CHEN Xue Yi (Research Institute of Yanshan Petrochemical Corporation, Beijing 102500, China) LI Shi Jie, LIN Bing Xiong (Institute of Physical Chemistry, Peking University, Beijing 100871, China);Synthesis of β Zeolite Using Tetraethylammonium Brom ide Together with Fluoride as Composite of Template(Ⅱ) ── Studies on Crystallization Process of β Zeolite[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-08
4 BAO Jia-Qing, XIE Zai-Ku *, LU Xian, CHEN Qing-Ling (Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China);Distribution of Silicon and Aluminium Atoms as Well as Surface Acid Properties of Aluminated β Zeolite[J];Chemical Research In Chinese Universities;2002-10
5 LIU Zhi jian,LIAO Jian jun and TAN Jing pin (Changling Petroleum Processing and Chemical Complex,Yueyang 414012) LI Da dong (Research Institute of Petroleum Processing,SINOPEC,Beijing 100083);Study on the Zeolite Catalysts for Dimethyl Ether Synthesis from Methanol[J];PETROCHEMICAL TECHNOLOGY;1999-04
6 Zhang Jianye Li Xuanwen Liu Xingyun (College of Chemistry & Molecular Engineering, Peking University,Beijing 100871);Study on the Framework Stability and Surface Acidity of Hβ Zeolite by Infrared Spectroscopy[J];ACTA PHYSICO-CHIMICA SINICA;1999-12
7 Deng Debin Ma Lijing Liu Xiuying (Department of Applied Chemistry,Beijing University of Chemical Technology,Beijing 100029) Li Xuanwen (College of Chemistry &Molecular Engineering,Peking University,Beijing 100871);Study of the Realumination of H Zeolite Framework by Infrared Spectroscopy[J];ACTA PHYSICO-CHIMICA SINICA;2000-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Liu Ai quan Ma Li jing Yuan Liang jing (College of Science, Beijing University of Chemical Technology, Beijing 100029, China);The effect of dealumination of β zeolite with HCl on its structure and catalytic activity[J];Journal of Beijing University of Chemical Technology;2003-06
2 QI Xiaolan 1, LIU Xiyao 1* , CHEN Gang 1, LIN Bingxiong 2 (1 Research Institute of Beijing Yanshan Petrochemical Corporation, SINOPEC, Beijing 102500, China; 2 Institute of Physical Chemistry, Peking University, Beijing 100871, China);Synthesis of β Zeolite Using TEABr-Fluoride as Composite Template Ⅲ. Crystallization Kinetics and Influencing Factors[J];Chinese Journal of Catalysis;2001-01
3 WANG Guoliang 1,2* , LIU Jinlong 2, LI Shuben 1 (1 Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, Gansu, China; 2 Refining Research Institute of Luoyang Petrochemical Engineering Corporation SINOPEC, Luoya;Study on Improving Hydrothermal Stability of β Zeolite[J];Chinese Journal of Catalysis;2002-03
4 LIU Hongxing 1* , XIE Zaiku 2, ZHANG Chengfang 1, CHEN Qingling 2(1 Chemical Technology Institute East China University of Science and Technology, Shanghai 200237, China; 2 Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China);Synthesis of SAPO-34 Molecular Sieve Using Hydrogen Fluoride and Triethylamine as Composite Template[J];Chinese Journal of Catalysis;2003-04
5 FU Jiquan *, CAO Tingbing (Beijing Key Laboratory, Center of Chemical Engineering, Beijing Institute of Clo thing Technology, Beijing 100029, China);Influence of Coke-Burning Regeneration Using Steam-Containing Air Flow on Dealumination of β Zeolite Catalyst[J];Chinese Journal of Catalysis;2003-11
6 QI Xiaolan~(1,2*),LI Bin~1,LI Shijie~1,LIU Xiyao~1,LIN Bingxiong~1(1 Institute of Physical Chemistry,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China;2 Shanghai Research Institute of Petrochemical Technology,SINOPEC,Shanghai 201208,China);Acidity and Catalytic Performance of BEA/MOR Intergrowth Zeolites[J];Chinese Journal of Catalysis;2006-03
7 ZHANG Shengzhen,CHEN Shengli~*,DONG Peng,JING Xiujuan,JIANG Kai(State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China);Synthesis and Characterization of SAPO-11 Molecular Sieve in the Presence of Fluoride Ions[J];Chinese Journal of Catalysis;2006-10
8 NIU Tianying,LI YingxiaLI Jianwei,CHEN Biaohua State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China;Synthesis of Zeolite Beta by the Vapour-Phase Transport Method Using Tetraethylammonium Bromide as the Organic Template[J];Chinese Journal of Catalysis;2009-03
9 DING Chun-Hua, WANG Xiang-Sheng*, GUO Xin-Wen(State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China);Effect of Hydrothermal Treatment of MCM-22 Catalyst on the Acidity, Pore Structure and Alkylation Properties of Toluene with Methanol[J];Chemical Journal of Chinese Universities;2007-05
10 XIE Zai ku,CHEN Qing ling (Shanghai Research Institute of Petrochemical Technology,Shanghai 201208,China);Study on realuminated zeolite and its catalytic performance[J];Gongye Cuihua (Industrial Catalysis);2001-03
China Proceedings of conference Full-text Database 2 Hits
1 Jiang Rui-xia Qi Xiao-lan Wang Jian Kong De-jin Xie Zai-ku Shanghai Research Institute of Petrochemical Technology,Shanghai,201208;The ~(29)Si MAS NMR Study of BEA/MOR composite zeolite[A];[C];2006
2 SHI Xiu-feng~1 LI Yu-ping~2 REN Lei~1 DOU Tao~1 (1.Institute of Special Chemicals,Taiyuan University of Technology,Taiyuan 030024,China; 2.College of Materials Science and Engineering,Taiyuan University of Technology,Taiyuan 030024,China);THE SYNTHESIS OF SAPO-34 AND ITS EUTECTIC MOLECULAR SIEVES IN EXTREMELY DENSE SYSTEM[A];[C];2008
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 QI Xiaolan~(1,2*),LI Bin~1,LI Shijie~1,LIU Xiyao~1,LIN Bingxiong~1(1 Institute of Physical Chemistry,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China;2 Shanghai Research Institute of Petrochemical Technology,SINOPEC,Shanghai 201208,China);Acidity and Catalytic Performance of BEA/MOR Intergrowth Zeolites[J];Chinese Journal of Catalysis;2006-03
2 WU Jianmei, WANG Baoyu, LI Niu, XIANG Shouhe~*(Institute of New Catalytic Material Science, College of Chemistry, Nankai University, Tianjin 300071, China);Effect of Aging with Ultrasound on the Synthesis of MCM-49 Zeolite[J];Chinese Journal of Catalysis;2006-05
3 WU Jianmei, WANG Baoyu, LI Niu, XIANG Shouhe(Institute of New Catalytic Material Science, College of Chemistry, Nankai University, Tianjin 300071, China);Effect of Aging Method on the Synthesis of MCM-22 Zeolite in Fluoride System[J];Chinese Journal of Catalysis;2006-07
4 ZHANG Qiang,LI Chunyi,SHAN Honghong,YANG Chaohe(State Key Laboratory of Heavy Oil Processing,China University of Petroleum(East China),Dongying 257061,Shandong,China);Comparison of Core/Shell Binary Structure Zeolite ZSM-5/SAPO-5 Synthesized by Vapor-Phase Transport and Hydrothermal Synthesis[J];Chinese Journal of Catalysis;2007-06
5 Hua Ruinian (Jilin Air Force Medical Academy, Jilin,132001) Gong Jian Wang Dongren Qu Lunyu (Department of Chemistry, Northeast Normal University, Changchun,130024);Preparation of Dimethylether Via Methanol Condensation Catalyzed by Loaded Heteropoly Acid[J];JOURNAL OF NORTHEAST NORMAL UNIVERSITY (NATURAL SCIENCE EDITION);1997-04
6 Wu Yue; Ye Xingkai; Yang Xiangguang; Wang Xinping; Chu Weiling; Hu Yucai (Changchun Institute of Applied Chemistry, the Chinese Academy of Sciences, Changchun 130022);Heterogenization of Heteropolyacids A General Discussion on the Preparation of Supported Acid Catalysts[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1996-04
7 GE Qingjie HUANG Youmei QIU Fengyan LI Shuben (Lanzhou Institute of Chemical Physics The Chinese Academy of Sciences Lanzhou 730000);Study on the Promoters of Bifunctional Catalyst for Conversion of Synthesis Gas to Dimethyl Ether[J];JOURNAL OF MOLECULAR CATALYSIS (CHINA);1998-04
8 WANG Shou guo, WANG Yuan hong, SHAO Yun, GONG Jian, QU Lun yu (Faculty of Chemistry, Northeast Normal University, Changchun 130024,China);Preparation of dimethylether by Catalyzed Dehydration of methanol with H_4SiW_(12)O_(40)-La_2O_3/γ-Al_2O_3 as catalyst[J];Journal Fo Molecular Science;2001-02
9 He Chijian He Hongyun **(Institute of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,China);Influence Factors of Synthesizing Nanosized Zeolite[J];Progress In Chemistry;2005-01
10 Kong Dejin1,2,Tong Weiyi2,Zheng Junlin1,Liu Zhicheng1,Zou Wei1,Qi Xiaolan1,Fang Dingye2(1 Shanghai Research Institute of Petrochemical Technology,SINOPEC Shanghai 201208;2 East China University of Science and Technology,Shanghai 200237);Progress in the Preparation,Characterization and Applications of Core-Shell Composite Zeolites[J];Chemistry;2008-04
【Secondary References】
Chinese Journal Full-text Database 2 Hits
1 HUANG Shang-shun1,HUANG Ke-lin1,ZHANG Shou-li2,WANG Jun2,SUN Guo-song1 (1.Guangxi Research Institute of Chemical Industry,Nanning 530001,China;2.Department of Chemistry,Guangxi Teachers Education University,Nanning 530001,China);Study Progress on Selective Synthesis of Diethanolameine[J];Technology & Development of Chemical Industry;2009-03
2 SHAO Gang-qin,SUN Peng,ZHANG Qing-jie,ZHOU Fu-rong,WANG Tian-guo,XIONG Zhen(State Key Laboratory of Advanced Technology for Materials Synthesis & Processing,Wuhan University of Technology,Wuhan 430070,China);Hydroisomerization Properties of Platinum-like Tungsten Carbide Catalyst[J];Journal of Wuhan University of Technology;2009-19
China Proceedings of conference Full-text Database 1 Hits
1 GU Jian-feng WANG Jing-zhong REN Tie-zhen YUAN Zhong-yong (1.Institute of New Catalytic Materials Science,College of Chemistry,Nankai University,Tianjin 300071,China; 2.School of Chemical Engineering and Technology,Hebei University of Technology,Tianjin 300130,China);SYNTHESIS OF SAPO-34 IN THE PRESENCE OF NH_4F[A];[C];2008
【Secondary Citations】
Chinese Journal Full-text Database 6 Hits
1 SHEN Jian-Ping;LI Yue;SUN Tie;GUO Jun;ZHANG Bo;JIANG Da-Zhen(Department of Chemistry,Jilin University,Changchun,130023)MIN En-Ze(Research Institute of Petroleum Processing,Beijing)JIANG Ting-Shun(Keshan Normal College,Keshan);Effect of Acid Treatment on the Structure and Acidity of Beta Zeolite[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1995-06
2 WANG Ying Xia, MENG Xian Ping *, LI Neng, ZHANG Wan Jing, LIN Bing Xiong (Institute of Physical Chemistry, Peking University, Beijing, 100871) LIU Xi Yao (Research Institute, Yanshan Petrochemical Coorporation, Beijing, 102549);Non framework Cation Locations in Zeolite Beta[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-08
3 Wang Lijun Tang Xianghai Zhu Ruizhi Pan Lürang(Department of Chemistry,Nankai universtity,Tianjin 300071);RESEARCH ON ZEOLITE CATALYST FOR SYNTHESIS OFMETHYL PHENYL ETHER WITH PHENOL ANDMETHANOL[J];ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION);1998-02
4 Huang Daqing Kang Guocai Zhang Shicai Wang Xuezai (Southwest Research Institute of Chemical Industry,Chengdu 610041);Application of dimethyl ether and development of its derivatives[J];Natural Gas Chemical Industry;1996-04
5 Yang Chun;Xu Qinhua(Department of Chemistry, Nanjing University Naning 210093);Alumination of Zeolite β[J];Acta Physico-chimica Sinica;1996-12
6 Yang Chun; Xu Qinhua(Department of Chemistry, Nanjing University Nanjing 210093);States and Assignment of Aluminium in Zeolite β[J];ACTA PHYSICO-CHIMICA SINICA;1998-02
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