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《Chinese Journal of Catalysis》 2005-01
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Activation of Methane Using Propane as Co-reactant over Cu-Zn/HZSM-5 Catalyst

ZHENG Haitao 1, ZHU Hongling 2, LOU Hui 1, HOU Zhaoyin 1, FEI Jinhua 1, LI Yinghui 3, XIAO Haicheng 3, YANG Yuhe 3, ZHENG Xiaoming 1* (1 Institute of Catalysis, Zhejiang University, Hangzhou 310028, Zhejiang, China; 2 School of Chemical Engineering, Harbin Engineering University, Harbin 150001, Heilongjiang, China; 3 Research Institute of Daqing Petrochemical Company, Daqing 163714, Heilongjiang, China)  
The catalytic conversion of methane into higher hydrocarbons in the absence of oxygen using propane as a co-reactant over the xCu-6%Zn/HZSM-5 (x=0~0.9%) catalyst was investigated. It was found that methane could be activated and transferred into higher hydrocarbons and aromatics with a methane conversion of 36% and an aromatics selectivity of 85.7% at 600 ℃ and methane/propane molar ratio of 1.0. The effects of methane/propane molar ratio on the methane and propane conversion and product distribution were studied in details. There was a positive relationship between the methane activation and aromatics production. Incorporation of methane into aromatics was confirmed by mass spectral analysis of aromatics products in the aromatization of isotope-labeled 13 CH 4 in the presence of propane, in which significant 13 C enrichment in C 6H + 6, C 7H + 8 and C 8H + 10 fragments was found.
【Fund】: 国家自然科学基金资助项目 (2 0 3 43 0 0 2 ) ;; 浙江省自然科学基金资助项目 (990 3 )
【CateGory Index】: O643
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