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《Chinese Journal of Catalysis》 2005-03
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Catalytic Performance of Hβ Zeolite Modified with Phosphorus for Isomerization of n-Decane

REN Xingtao 1, CAO Jianqiu 1, WANG Zhenyu 2, LIU Shangyuan 2, XIANG Shouhe 1* (1 Institute of New Catalytic Material Science, College of Chemistry, Nankai University, Tianjin 300071, China; 2 Catalyst Factory, Nankai University, Tianjin 300071, China)  
The effects of phosphorus modification on the surface acidity and the catalytic performance of Pt/P-Hβ were studied by XRD, NH 3-TPD and Py-IR. The isomerization of n-decane over Pt/P-Hβ with different phosphorus contents was investigated. The addition of an adequate amount of phosphorus to Hβ could effectively change the acid amount and acid strength distribution of Hβ zeolite. The total acid amount and strong acid sites decreased after addition of phosphorus, but the weak acid mount and Brnsted acid sites increased. The optimum balance between metal sites and acid sites was obtained. The results of n-decane isomerization over Pt/P-Hβ showed that the n-decane conversion decreased on Hβ with phosphorus addition, however, the iso-decane selectivity increased. The optimum modification result was obtained over the 1.0%Pt/0.75%P-Hβ catalyst.
【Fund】: 国家自然科学基金资助项目 (2 0 2 3 3 0 3 0 )
【CateGory Index】: O643
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